國內産 大理石의 地質工學的 特性

정영욱(Young Wook Cheong),전효택(Hyo Taek Chon) 대한자원환경지질학회 1990 자원환경지질 Vol.23 No.4

Mechanical, physical and petrographic properties of seventeen marble specimens collected from ten marble mines in Korea were investigated. Studied marbles were mainly composed of calcite, dolomite, and various amounts of serpentine, tremolite, olivine, quartz and opaque minerals. Complete and sutured textures were dominant. Compressive strength measured normal to the bedding plane is larger almost two times than that measured parallel to the bedding plane. From the results of Shore hardness test on marbles, water content was an important factor to decrease Shore hardness values. Engineering geological properties, especially, compressive strength, Young’s modulus, wear resistance and water absorption could be controlled by the presence of quartz, and the type of marble texture. Water absorption-porosity, compressive strength-Young’s modulus, and impact strength index-Los Angeles abrasion couples show good correlation. According to the comparative utility as commercial stone, it could be concluded that marbles from the Banglim mine, Songbo mine, Kwangdeok mine and Bongjeong mine were superior to that of other studied marbles.

Acid Mine Drainage and Heavy Metal Contamination of Stream Sediments in the Okdongcheon Stream, Sangdong Area, South Korea

정영욱,Cheong, Young Wook,Thornton, Iain The Korean Society of Economic and Environmental G 1994 자원환경지질 Vol.27 No.1

강원도 상동지역의 옥동천 및 그 지류들을 대상으로 수질 파라메터(Eh-pH, 부유물질)의 측정과 하상퇴적물의 화학분석을 통하여 석탄광 및 금속 광산활동에 의한 옥동천의 수성 환경의 오염정도를 조사하였다. 옥동천의 조사유역을 상부와 하부 옥동천으로 구분할 때 상부 유역은 석탄광의 개발로 인한 황화물의 산화작용으로 인하여 수질은 매우 낮은 pH를 나타내 광산 산성수(Acid Mine Drainage)로 심하게 오염된 것으로 조사되었다. 또한 상부 옥동천에 용존된 철이 지류들의 유입과 하천의 aeration으로 철 산화물(floc)의 발생과 이의 침전으로 하천 바닥은 황갈색의 철산화물이 퇴적되어 있다. 그러나 상부 옥동천의 유속에 의해 일부 철 산화물이 침전되지 못한채 부유되어 옥동천은 매우 탁하게 보인다. 상부 옥동천온 천평천의 유입으로 인하여 낮은 pH의 산성수는 중화되지만 부유물질의 존재로 인하여 하부 옥동천은 계속 탁하여 광산 산성수의 영향이 지속되고 있다. sediment quality criteria와 비교해 볼 때 하부 옥동천의 하상퇴적물, 특히 상동 텅스텐-모리브덴늄 광미 저장댐과 인접된 지점의 하상퇴적물은 Pb, Cu, Zn, Co, Cd, As 및 Bi 등의 유해금속에 의해 농축되어 있어 퇴적물의 질이 상당히 악화되어 있다. 수중 및 저서 생물에 대한 서식처 및 수질을 개선하기 위해서 옥동천 상부에는 산성수를 중화시킬 수 있는 경제성 있는 수처리 장치의 도입과 중금속의 speciation의 연구가 필요할 것으로 사료된다. Geochemical investigations based on measurements of water parameters and sampling of stream sediments have been carried out, in the Okdongcheon stream and its tributaries in the Sangdong area of South Korea. There are two main problems occurring in the Okdongcheon stream: an acid mine drainage in the upper reaches and toxic trace metal contamination of the stream sediments mainly in the lower reaches. Acid mine water originating from coal mining was neutralized at the confluence of the Cheonpyongcheon stream whilst suspended solids due to flocculation of iron in water caused turbidity which was undesirable. Sediments in the Okdongcheon stream have been contaminated by mining activites. Iron was heavily concentrated in sediments in the upper Okdongcheon whilst toxic trace metals including Pb, Cu, Zn, Co, Cd, As and Bi were accumulated in sediments at stations draining metallic mining areas and near the tailings dam. There is now a requrement to neutralise the acid mine drainage and to use site-specific analysis of biological communities to ensure the conservation and preservation of aquatic organisms.

경남 양산 및 밀양지역 납석광상의 지구화학적 연구

정영욱,전효택,Cheong, Young-Wook,Chon, Hyo-Taek 대한자원환경지질학회 1989 자원환경지질 Vol.22 No.4

Mineralogy and geochemistry of five pyrophyllite deposits in Yangsan-Milyang area such as Cheonbulsan, Dumyong, Dongrae, Youkwang, and Sungjin mines were investigated. Pyrophyllite ores consist mainly of pyrophyllite, sericite, and quartz with some amounts of kaolinite and pyrite. Polytype of pyrophyllite is 2M. Sericite has two polytypes of 1M and 2M1. The ${\delta}^{18}O$ values of pyrophyllite from the Cheonbulsan and the Dumyong mines were measured as 0.23-0.60‰ and 3.40‰, respectively, and those of montmorillonite and kaolinite from the Dumyong mine were in the range of 11.90-12.06‰. This low oxygen isotope composition provides conclusive evidence for hydrothermal activity in the studied area. Contents of major elements are more useful than those of trace elements to discriminate altered zones such as pyrophyllite, sericite, argillic, and andalusite zones from the surrounding rocks. Particularly, contents of $K_2O$, $Na_2O$ and CaO are helpful to identify alteration zones from the discriminant and the cluster analysis of multi-element data.

경남(慶南) 및 전남(全南) 일부(一部) 납석광상(蠟石鑛床)의 산소(酸素)-황(黃) 동위원소조성(同位元素組成)과 광상성인(鑛床成因)

전효택,정영욱,김인준,Chon, Hyo Taek,Cheong, Young Wook,Kim, In Joon 대한자원환경지질학회 1991 자원환경지질 Vol.24 No.2

Oxygen and sulfur isotope composition of pyrophyllite and pyrite from six pyrophyllite deposits in the Yangsan-Milyang areas (the Cheonbulsan, Dumyong, Dongrae, Youkwang, Sungjin and Milyang mines), and five deposits in the Whasoon-Dado-Haenam areas (the Byuksong, Songseok, Dado, Bugock and Nowha mines) were measured. Pyrophyllite ores both from the Yangsan-Milyang areas and the Dado-Haenam areas are composed mainly of high alumina minerals such as pyrophyllite, sericite and kaolinite. Most of altered rocks show diagnostic chacteristics of bleaching effect. Major minerals of the Songseok ore deposit in the Whasoon area are pyrophyllite, and diaspore with minor amounts of kaolinite and quartz. The Byuksong ores from the Whasoon area were composed mainly of andalusite, kaolinite, pyrophyllite and mica with small amounts of chloritoid, quartz and carbonaceous matter. The Byuksong and Songseok ores show metamorphic textures such as porphyroblastic, and pressure solution textures, and have low whiteness values, The ${\delta}^{18}O$ values of pyrophyllite from the Cheonbulsan and Dumyong mines in the Yangsan area, and the Dado and Nowha mines in the Dado-Haenam areas were in the range of 0.23~5.36%,. The relatively low 8 180 values provide conclusive evidence for hydrothermal activity in these deposits. The ${\delta}^{18}O$ values of pvrophvllite from the Songseok mine in the Whasoon area were measured as 6.70-8.13%, and these higher ${\delta}^{18}O$ values suggest that the Songseok ore deposit have been probably subjected to metamorphism. ${\delta}^{34}$S(pyrito) values from the Cheonbulsan, Dumyong, Youkwang, Dongrae, Sungjin and Milyang deposits in the Yangsan-Milyang areas, and the Dado pyrophyllite deposits in the Dado area range from -5.8 to 2.7%, which means that the pyrite sulfur could be of igneous origin. ${\delta}^{34}$S(pyrito) from the Nohwa mine in the Haenam area is, however, measured as -12.4%" implying the contamination of sulfur derived from the sedimentary country rocks. All of the studied high alumina deposits in the Yangsan-Milyang areas and the Dado-Haenam areas were hydrothermal in origin, whereas the Byuksong and Songseok ore deposits in the Whasoon area were probably of metamorphic origin.

상동 및 울진지역 주석 화강암질암의 지구화학 자료에 대한 다변량해석

전효택,정영욱,손창일,Chon, Hyo-Taek,Cheong, Young-Wook,Son, Chang-Il 대한자원환경지질학회 1994 자원환경지질 Vol.27 No.3

Tin mineralizations in South Korea have been found only in the Ulchin and Sangdong areas. They appear to be in close spatial association with the Wangpiri granitoid in the UlChin area, and the Nonggeori and Naedeogri granites in the Sangdong area. However, previous works have revealed that there are considerable differences in geological setting, mineralogical and geochemical compositions among these granitoids concerned. The roles of discriminant and multiple regression analysis have been examed to establish geochemical differences among the tin-granitoids and to identify elements relating to tin mineralizations. The data set used in this study consists of 60 observations with 29 elements which are cited from pre-existing publications. A stepwise discriminant analysis determined the group of variables that differentiate between samples from four training sets; Buncheon, Wangpiri, Nonggeori and Naedeogri granitoids. These granitoids were most effectively discriminated on the basis of major elements FeO, CaO and $P_2O_5$ and also by the trace elements Rb and Zr. Results of the multiple regression analysis shows that the level of Sn in granitoids depends positively on ones of MnO, Rb and FeO and negatively $P_2O_5$. Graphical representation of discriminant scores on sampling locations greatly aid recognition of differences in the geochemical characteristics in terms of spatial distribution of granitoids examed. The application of the discriminant analysis provides a potential means of identifying and comparing geochemical characteristics.

부산임기광산 폐석적치장에서의 순간충격시험 적용성 연구

박학윤,주정웅,정영욱,여인욱,Park, Hak-Yun,Ju, Jeong-Woung,Cheong, Young-Wook,Yeo, In-Wook 한국지하수토양환경학회 2007 지하수토양환경 Vol.12 No.3

불포화대 및 포화대에 걸쳐 존재하는 폐석더미의 수리적 특성을 조사하기 위해 물을 주입한 후 수두강하를 측정하는 순간충격시험을 실시하였다. 본 연구지역과 같이 관정이 수리적 특성이 크게 다른 두 지층에 걸쳐 설치된 경우, Bower and Rice해석 방법을 이용하여 두 대수층 각 각의 수리전도도를 산출할 수 있었으며, 하강하는 지하수위의 변곡점을 이용하여 폐석더미의 두께를 추정할 수 있었다. 갈수기 시 관정 내 낮은 지하수위 때문에 인위적인 지하수위를 형성시킨 후 순간충격시험을 실시한 결과, 그 결과는 풍수기 시험 결과와 차이가 크지 않았다. 이와 같은 순간 충격시험은 폐석적치장과 같은 곳의 수리적 특성을 파악할 수 있는 유효한 방법으로 판단된다. The slug test by adding water to well and measuring falling head was conducted to investigate the hydrogeological property of unsaturated or partially saturated mine tailings in the Imgi abandoned mine in Busan. In case that wells were installed with a full screen through two layers with different hydraulic properties, Bouwer and Rice method was useful to estimate the hydraulic conductivity and the depth of mine tailings. In particular, when groundwater dried out in the dry season, the slug test performed by adding water into well to form artificial water table and then conducting falling head test produced the reasonable hydraulic conductivity values. The slug test using falling head test can be an alternative to investigate the hydrogeological property of abandoned mine tailings.

거풍 폐광산 폐기물 적치장 지하수 및 침출수 수질의 시기별 변화

안주성,임길재,정영욱,Ahn, Joo-Sung,Yim, Gil-Jae,Cheong, Young-Wook 대한자원환경지질학회 2009 자원환경지질 Vol.42 No.3

In this study, water quality variation in borehole groundwaters and surface leachate waters were investigated on a seasonal sampling and remote monitoring basis within the waste impoundments at the Geopung mine site where previous rehabilitation measures were unsuccessful to prevent acidic drainage. All groundwaters were typical acidic drainage with acidic pH (3.3${\sim}$4.6) and high TDS (338${\sim}$3330 mg/L) values during the dry season, but increases in metal contents (TDS 414${\sim}$4890 mg/L) and decrease of pH (2.7${\sim}$3.6) were observed during the rainy season. Surface leachate waters showed a similar pattern in water quality variation. Surface runoff waters during rain events had acidic pH (3.0${\sim}$3.4) through direct reactions with waste rocks. Good correlations were found between major and trace elements measured in water samples, but no significant seasonal variation in chemical compositions was shown except relative changes in contents. It can be suggested that dissolution of soluble secondary salts caused by flushing of weathered waste rocks and tailings directly influenced the water quality within the waste impoundments. Increases in acid and metal concentrations and their loadings from mine wastes are anticipated in the rainy season. More appropriate cover systems on waste rocks and tailings necessitate consideration of more extreme conditions in the study mine. 폐광지역 광산폐기물 적치장에서 발생하는 산성 침출수 및 이의 영향을 직접적으로 받는 하부 지하수의 수질변화 양상을 자동계측자료 및 시기별 시료 분석으로 평가하였다. 연구지역은 충북 옥천군의 폐광산인 거풍광산이며 한차례 복토작업이 이루어졌으나 산성배수 발생은 지속되었다. 건기의 지하수 시료는 강산성(pH 3.3${\sim}$4.6) 및 높은 총용존고형물질 함량(338${\sim}$3330 mg/L)으로서 전형적인 산성배수의 특성을 보였으며 우기에 중금속 함량 증가(TDS 414${\sim}$4890 mg/L)와 pH 2.7${\sim}$3.6으로 보다 강한 산성을 나타내었다. 지표침출수 시료도 유사한 수질변화양상을 보이며 강우시 지표 유거수는 폐석과의 직접 반응으로 강산성(pH 3.0${\sim}$3.4)을 나타내었다. 시료내 주성분 및 중금속원소들 간의 상관성이 전반적으로 높게 나타났으며 개별 성분들의 건우기 함량 증감양상 외에 전체 시기별 수질조성의 큰 변화는 보이지 않았다. 연구지역 광산폐기물 표면에는 금속 수화황산염 등의 다양한 2차 염류가 풍부하게 생성되어있으며 이들의 강우에 용해되어 침출수 및 하부 지하수의 수질에 직접적으로 영향을 주는 것으로 판단한다. 향후 보다 심각한 기후조건에서도 우수한 효율을 나타낼 수 있는 복토 및 처리기법이 요구된다.

골재 생산과정에서 발생하는 일부 석분의 평가와 그 활용 연구 동향

이진영(Jin-Young Lee),정영욱(Young Wook Cheong),지상우(Sang-Woo Ji),이동길(Dong-Gil Lee) 대한자원환경지질학회 2021 자원환경지질 Vol.54 No.5

암석을 파쇄해서 골재를 생산할 때 부산물로서 암분을 위주로 한 고상 석분 혹은 슬러지가 발생한다. 이러한 부산물은 폐기물로 분류되어 활용되지 못하고 대부분 매립 처분되고 있다. 이 부산물은 원석의 종류와 생산 과정에 따라서 광물조성, 화학조성 및 물성 등이 다르다. 따라서 부산물의 물리적 혹은 화학적 특성을 잘 활용할 수 있는 기술이 개발 된다면 폐기 처분 대신 경제적 및 환경적 이익을 거둘 수 있을 것이다. 본 연구에서는 국내 골재 생산업체로부터 석분 슬러지를 수집하여 XRD 광물 분석, 입도분석 그리고 주성분 화학 분석을 수행하여 물리적 화학적 특성을 조사하였다. 또한 국내외적으로 진행된 고상 석분 및 슬러지의 활용사례를 통해서 연구 동향을 파악하고 향후 연구 분야 도출에 기초 자료로 활용토록 하였다. When crushing rocks to produce aggregates, solid stone dust or sludge is generated as a by-product. These by-products are classified as waste and are not utilized, and most of them are disposed of landfills. This by-product differs in mineral composition, chemical composition, and physical properties depending on the rock type and aggregate production process. Therefore, if a technology that can make good use of the inherent physical or chemical properties of by-products is developed, economic and environmental benefits can be achieved instead of disposal. In this study, stone dust and sludge were collected from domestic aggregate producers and physical and chemical properties were investigated by performing XRD mineral analysis, particle size analysis, and chemical analysis. In addition, the research trend was identified through a domestic and international research case studies on the use of stone powder and sludge.

慶南 및 全南 一部 蠟石鑛床의 酸素-黃 同位元素組成과 鑛床成因

Hyo TaekChon(全孝澤),Young Wook Cheong(鄭永旭)In Joon Kim(金仁俊) 대한자원환경지질학회 1991 자원환경지질 Vol.24 No.2

Oxygen and sulfur isotope composition of pyrophyllite and pyrite from six pyrophyllite deposits in the Yangsan-Milyang areas (the Cheonbulsan, Dumyong, Dongrae, Youkwang, Sungjin and Milyang mines), and five deposits in the Whasoon-Dado-Haenam areas (the Byuksong, Songseok, Dado, Bugock and Nowha mines) were measured. Pyrophyllite ores both from the Yangsan-Milyang areas and the Dado-Haenam areas are composed mainly of high alumina minerals such as pyrophyllite, sericite and kaolinite. Most of altered rocks show diagnostic chacteristics of bleaching effect. Major minerals of the Songseok ore deposit in the Whasoon area are pyrophyllite, and diaspore with minor amounts of kaolinite and quartz. The Byuksong ores from the Whasoon area were composed mainly of andalusite, kaolinite, pyrophyllite and mica with small amounts of chloritoid, quartz and carbonaceous matter. The Byuksong and Songseok ores show metamorphic textures such as porphyroblastic, and pressure solution textures, and have low whiteness values. The δ¹⁸O values of pyrophyllite from the Cheonbulsan and Dumyong mines in the Yangsan area, and the Dado and Nowha mines in the Dado-Haenam areas were in the range of 0.23~5.36‰. The relatively low δ¹⁸O values provide conclusive evidence for hydrothermal activity in these deposits. The δ¹⁸O values of pvrophvllite from the Songseok mine in the Whasoon area were measured as 6.70-8.13‰ and these higher δ¹⁸O values suggest that the Songseok ore deposit have been probably subjected to metamorphism. δ³⁴Spyrite values from the Cheonbulsan, Dumyong, Youkwang, Dongrae, Sungjin and Milyang deposits in the Yangsan-Milyang areas, and the Dado pyrophyllite deposits in the Dado area range from -5.8 to 2.7%, which means that the pyrite sulfur could be of igneous origin. δ³⁴Spyrite from the Nohwa mine in the Haenam area is, however, measured as -12.4‰, implying the contamination of sulfur derived from the sedimentary country rocks. All of the studied high alumina deposits in the Yangsan-Milyang areas and the Dado-Haenam areas were hydrothermal in origin, whereas the Byuksong and Songseok ore deposits in the Whasoon area were probably of metamorphic origin.

산성광산배수로 오염된 지하수 정화용 투수성 반응벽체 반응매질 선정 기초실험

지상우(Sang Woo Ji),정영욱(Young Wook Cheong) 대한자원환경지질학회 2005 자원환경지질 Vol.38 No.3

The batch tests were performed to evaluate the applicability of the permeable reactive barrier (PRB) to in-situ treatment of groundwater with high concentration of heavy metals. The leachates used in this study were collected from waste rock dump of the Imgy mine, and have a low pH and high metal concentration. The acidity loading was 65 kg as CaCO 3 /day, metal loading of Fe+Al+Mn was 11.6 kg/day. This type of water could be treated with biological-mediated sulfate reduction using the organic carbon mixture as a reactive media. The batch tests were carried out with five mixtures that were composed with different mixing ratios of mushroom compost, pine-tree bark, and limestone cheep. Results indicated that the PRB could reduce the acidity loading CaCO 3 /day to 12.3 kg and reduce the metal loading to 3.3 kg/day. Considering about the low pH and high metal loading, the contaminated water may be ameliorated by passing it through the buffering PRB composed with inorganic carbonate materials and then through the PRB composed with the organic carbon mixture which can induce sulfate reduction. 중금속으로 오염된 산성 지하수의 현장 정화방법으로 투수성반응벽체 기술의 적용 가능성을 평가하기 위하여 반응 매질 선정을 위한 실내실험을 수행하였다. 처리대상 오염지하수로 이용한 임기광산 폐석적치장 침출수는 낮은 pH와 높은 금속농도를 갖는다(산도부하량으로 65 kg CaCO 3 /일, 금속부하량(Fe+Al+Mn)으로 11.6 kg/일). 이러한 특성의 오염지하수는 반응매질로 유기탄소 혼합물을 이용하여 황산염환원 반응에 의한 처리가 가능할 것으로 판단된다. 다섯 가지 서로 다른 배합비를 갖는 버섯퇴비, 소나무 바크, 석회석의 혼합 반응매질을 이용한 배치실험 결과를 통해 보면 투수성반응벽체를 적용할 경우 산도부하량은 12.3 kg CaCO 3 /일, 금속부하량은 3.3 kg/일로 줄일 수 있다. 대상 지하 수의 낮은 pH와 높은 금속부하량을 고려하여 무기탄소를 위주로 한 완충용 반응벽체를 먼저 두고, 이어서 유기탄소 혼합물로 구성되는 반응벽체로 황산염 환원을 유도하는 방법 적용한다면 보다 효과적인 광산배수에 대한 정화를 기대할 수 있을 것이다.