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Soluble Single-Molecule Magnet: Mn12-stearate.
박치동,정둑영,Park, Chi Dong,Jeong, Duk Yeong Korean Chemical Society 2001 Bulletin of the Korean Chemical Society Vol.22 No.6
A new polynuclear complex of manganese stearate has been prepared by substitution of acetate with stearic acid. The stearate ion with long alkyl chain was used to isolate molecular $Mn_{12}$ cluster from each other. The $Mn_{12}$-stearate compound prepared is soluble in most organic solvents and resistant against water catalyzed reduction. The $Mn_{12}$-stearate compound shows similar electrochemical, magnetic properties to the pristine $Mn_{12}$-acetate.