류마티스 관절염에서 발생한 Cerebral Aspergillosis

이태근 ( Tae Kun Lee ),최재훈 ( Jae Hoon Choi ),최철웅 ( Cheul Woong Choi ),이상용 ( Sang Yong Lee ),이준희 ( Jun Hee Lee ),이정욱 ( Joung Wook Lee ),김상수 ( Sang Soo Kim ),김성일 ( Sung Il Kim ) 대한류마티스학회 2003 대한류마티스학회지 Vol.10 No.4

We report a case of aspergillosis of the central nervous system in patient with rheumatoid arthritis (RA). A 46-year-old woman with 20-year history of RA and on treatment with corticosteroid, hydroxychloroquine and methotrexate, was admitted because of drowsiness, dizziness and dysarthria. On admission, physical examination and laboratory data showed, among other findings, disappearance of pupil reflex, positive Babinski and Chaddock reflex. Magnetic resonance imaging (MRI) of brain showed multiple high signal intensity lesion on medulla, pons, midbrain, basal ganglia, internal capsule, thalamus and hypothalmus. Stereotactic brain biopsy was performed and biopsy specimen revealed an invasive Aspergillus.

직충돌 이온산란 분광법을 사용한 MgO(100) 면에 성장된 BaTiO₃막의 구조해석

황연,이태근,Hwang, Yeon,Lee, Tae-Kun 한국세라믹학회 2006 한국세라믹학회지 Vol.43 No.1

Time-of-flight impact-collision ion scattering spectroscopy (TOF-ICISS) using 2 keV $He^+$ ion was applied to study the geometrical structure of the $BaTiO_3$ thin film which was grown on the MgO(100) surface. Hetero-epitaxial $BaTiO_3$ layers were formed on the MgO(100) surface by thermal evaporation of titanium followed first by oxidation at $400^{\circ}C$, subsequently by barium evaporation, and finally by annealing at $800^{\circ}C$. The atomic structure of $BaTiO_3$ layers was investigated by the scattering intensity variation of $He^+$ ions on TOF-ICISS and by the patterns of reflection high energy electron diffraction. The scattered ion intensity was measured along the <001> and <011> azimuth varying the incident angle. Our investigation revealed that perovskite structured $BaTiO_3$ layers were grown with a larger lattice parameter than that of the bulk phase on the MgO(100) surface.

비행시간형 직충돌 이온산란 분광법을 이용한 Si(100) 면의 구조해석

황연,이태근,Hwang, Yeon,Lee, Tae-Kun 한국세라믹학회 2003 한국세라믹학회지 Vol.40 No.8

Time-Of-flight Impact-Collision Ion Scattering Spectroscopy (TOF-ICISS) using 2 keV He$\^$+/ ion was applied to study the geometrical structure of the Si(100) surface. The scattered ion intensity was measured along the [011] azimuth varying the incident angle. The focusing effects were appeared at the incident angles of 20$^{\circ}$, 28$^{\circ}$, 46$^{\circ}$, 63$^{\circ}$, and 80$^{\circ}$. The Si atomic position was simulated by calculating the shadow cone to explain the five focusing effects. The four focusing effects at 28$^{\circ}$, 46$^{\circ}$, 63$^{\circ}$, and 80$^{\circ}$ resulted from the {011} surface where no dimers existed on the outermost surface. On the contrary, the scattering between two Si atoms in a dimer resulted in the focusing peak at 20$^{\circ}$. 2 keV의 저에너지 He$^{+}$ 이온을 사용한 비행시간형 직충돌 이온산란 분광법을 이용하여 Si(100) 표면의 원자구조를 해석하였다. [011] 방위를 따라 이온빔을 입사시키고, 입사 각도에 따른 산란된 이온의 강도를 측정하였다. 20$^{\circ}$, 28$^{\circ}$, 46$^{\circ}$, 63$^{\circ}$, 80$^{\circ}$등의 5가지 입사각도에서 집속 효과가 일어났다. 이 각도를 설명하기 위해 그림자 원뿔을 계산하여 원자의 위치를 모사하였으며, 이 결과는 실험과 잘 일치하였다. 28$^{\circ}$, 46$^{\circ}$, 63$^{\circ}$ 및 80$^{\circ}$에서 일어나는 4개의 집속 효과는 표면 최외층에서 이 합체가 자리하지 않는 {011}면을 따라서 발생한 것이며 벌크 구조가 반영된 결과이다. 그 반면에 이합체를 이루는 원자사이에서 발생한 산란은 20$^{\circ}$에서 집속 효과를 나타내었다.

Recent Advances in the Powder Processing by Mechanical Alloying

황연,이태근,박병규,Hwang, Yeon,Lee, Tae-Kun,Park, Byung-Kyu Korea Crystallographic Association 1999 韓國結晶學會誌 Vol.10 No.2

$V_2O_5$ 첨가가 $Zn_3Nb_2O_8$ 마이크로파 유전체 특성에 미치는 영향

윤호병,이태근,황연,Yun, Ho-Byung,Lee, Tae-Kun,Hwang, Yeon 한국결정학회 2006 韓國結晶學會誌 Vol.17 No.1

[ $Zn_3Nb_2O_8$ ]세라믹스에 액상소결제인 $V_2O_5$를 첨가하여 소결하여 고주파 대역에서의 유전특성의 변화를 조사하였다. $1100^{\circ}C$에서 2시간 하소한 결과 $Zn_3Nb_2O_8$를 합성할 수 있었고, $V_2O_5$를 첨가하여 소결한 $Zn_3Nb_2O_8$에서 $V_2O_5$의 mole%증가와 소결온도의 증가에 따라 상대밀도 95%의 소결특성을 확인 하였다. 유전율 특성은 $V_2O_5$ mole ratio가 $2{\sim}4%$의 시편에서 모두 ${\varepsilon}_r\;21$ 이상으로 증가됨을 확인하였고, 품질계수는 $900^{\circ}C$에서 소결한 $V_2O_5$ 2 mole% 시편에서 $Q{\times}f=40,000$을 나타내었다. 온도계수는 $900^{\circ}C$ 소결하고 $V_2O_5$ 1 mole% 첨가한 경우 0에 제일 가까운 $T_{cf}=-54ppm/^{\circ}C$를 나타내었고, 다른 보건에서는 $T_{cf}=-60{\sim}-80ppm/^{\circ}C$의 값을 나타내었다. The microwave dielectric properties of $Zn_3Nb_2O_8\;with\;V_2O_5$ addition were investigated. The addition of $V_2O_5$ enhanced the sinterability of $Zn_3Nb_2O_8$, which resulted in high density of $Zn_3Nb_2O_8$ ceramic greater than 95% of the theoretical value when sintered at $900^{\circ}C$ for 4 hours. X-ray diffraction analysis of sintered $Zn_3Nb_2O_8$ ceramic showed no second phase with $V_2O_5$ addition. Dielectric permittivity(${\varepsilon}_r$) and quality factor($Q{\times}f$) varied with both density at different sintering temperature and $V_2O_5$ addition. Dielectric permittivity, quality factor and temperature coefficient($T_{cf}$) of the two mole of $V_2O_5\;added\;Zn_3Nb_2O_8$ that was sintered at $900^{\circ}C$ were 21.4, 40,000, $-54ppm/^{\circ}C$, respectively.

비행시간형 직층돌 이온산란 분광법을 사용한 MgO(001) 면에 성장된 TiO막의 구조해석

황연,이태근,박병규,Hwang, Yeon,Lee, Tae-Kun,Park, Byung-Kyu 한국결정학회 2002 韓國結晶學會誌 Vol.13 No.2

Time-of-flight impact-collision ion scattering spectroscopy (TOF-ICISS) was applied to study the geometrical structure of epitaxially grown TiO layers on a MgO(001) surface. The hetero-epitaxial TiO layer was deposited by thermal evaporation of titanium onto the MgO(001) surface and subsequent exposure to oxygen at 400℃. The well-ordered TiO structure was confirmed with the 1×1 RHEED pattern. TOF-ICISS results revealed that the TiO layer was formed at the on-top sites of the MgO(001) substrate and that the lateral lattice constant of TiO layer was the same as that of the MgO substrate. The surface of the deposited epitaxial TiO layer was smooth without the three dimensional islands. MgO(001)면 위에 Ti 금속을 증착시킨 후 400℃에서 산소에 노출시킴으로써 헤테로 에피탁시 TiO 막을 성장시켰다. 성장된 TiO막의 원자구조를 비행시간형 직충돌 이온산란 분광법을 사용하여 해석하였다. MgO(001)면에 성장된 에피탁시 TiO막은 다음과 같은 구조를 갖고 있음이 밝혀졌다. Ti및 O 원자가 MgO 원자의 위에 위치하여 면내방향의 격자상수는 MgO의 격자상수와 일치하고, TiO막의 표면은 3차원적 섬 형상이 없는 평활한 구조를 가지고 있다.

산란 입자를 포함하는 염료감응 태양전지용 $TiO_2$ 전극 제조

이진형,이태근,김철진,Lee, Jin-Hyoung,Lee, Tae-Kun,Kim, Cheol-Jin 한국마이크로전자및패키징학회 2011 마이크로전자 및 패키징학회지 Vol.18 No.2

The energy conversion efficiency of DSSCs (Dye-Sensitized Solar Cells) is dependent on the powder size, the structure, and the morphology of $TiO_2$ electrode. The higher efficiency is obtained with high surface area of the nanoanatase-$TiO_2$ powder adsorbed onto a lot more of the dye. Also, the enhancement of light scattering increases the efficiency with high adsorption of the dye. Powder size, crystalline phase, and shape of $TiO_2$ obtained by hydrothermal method have 15-20 nm, anatase and round. $TiO_2$ electrode has fabricated with the mixture of scattering $TiO_2$ particle with 0.4 ${\mu}m$ in nano-sized powder. Conversion efficiency of series of DSSCs was measured with volume fraction of scattering particle. Photovoltaic characteristics of DSSCs with 10% scattering particles are 3.51 mA for Jsc (short circuit current), 0.79 V for Voc(open circuit potential), filling factor 0.619 and 6.86% for efficiency. Jsc was improved by 11% and enhancement of efficiency by 0.77% compared with that of no scattering particles. The confinement of inserted light by light scattering particles has more increase of the injection of exiton(electron-hole pair) and decrease of moving path in electron. Efficiencies of DSSCs with more than 10% for scattering particles have reduced with increasing the pore in the $TiO_2$ electrode. 염료 감응 태양 전지(Dye-Sensitized Solar Cells: DSSCs)의 에너지 변환효율은 $TiO_2$ 전극의 입자 크기, 구조 및 표면 형태에 의존한다. 높은 비표면적을 갖는 나노 크기의 아나타제 $TiO_2$는 많은 염료를 흡착할 수 있어 변환효율을 증가 시킨다. 또한 전극 내부에서 태양광의 산란을 증가 시키면, 염료가 태양광을 흡수하는 양이 증가하여 효율이 증가할 수 있다. 수열 합성법으로 합성한 $TiO_2$ 분말의 크기는 15-25 nm이고, 결정상은 구형의 anatase 상이다. 0.4 ${\mu}m$의 $TiO_2$ 산란입자를 합성한 나노 크기의 $TiO_2$ 분말에 혼합하여 전극을 제조하고, DSSCs를 제작한 후 변환효율을 측정하였다. 10% 의 산란 입자가 포함된 DSSCs는 단락전류 3.51 mA, 개방전압 0.79 V, 곡선인자 0.619로 6.86%의 변환 효율을 나타 내었다. 산란 입자의 영향으로 단락전류밀도는 11% 증가하였고, 효율은 0.77% 증가하였다. 산란 입자가 포함되지 않은 DSSCs 보다 산란 입자가 전극으로 들어온 태양광을 산란시켜 전자-홀 쌍의 생성을 증가 시키고, 전자가 전극을 따라 이동하는 경로가 감소하여 효율이 증가하였다. 10% 이상의 산란 입자는 전극 내부에 입자 크기의 큰 기공을 증가 시켜 효율이 감소하였다.

용액연소합성법을 이용한 LaFeO₃ 분말 합성 및 탄소 연소 특성

강대식,이태근,황연,배광현,조성백,Rang, Da-Sik,Lee, Tae-Kun,Hwang, Yeon,Bae, Kwang-Hyun,Cho, Sung-Baek 한국재료학회 2007 한국재료학회지 Vol.17 No.7

[ $LaFeO_3$ ] powders were prepared as the oxidation catalyst materials to reduce the emission of particulate matters from diesel engine and their catalytic effects on the oxidation of carbon were investigated. Solution combustion method was employed for the powder synthesis, which uses highly exothermic and selfsustaining reactions. In this study $LaFeO_3$ powders were synthesized at $400^{\circ}C$ as varying the ratio ($\Phi$) of fuel (citric acid) and oxidizer (metal nitrate), and their phase and carbon ignition property were examined. As $\Phi$ decreases, the crystallinity of synthesized $LaFeO_3$ powders enhanced. By calcining at $700^{\circ}C$, all the powders synthesized at various $\Phi$ fully crystallized. The calcined $LaFeO_3$ powders showed carbon ignition temperature as low as $501{\sim}530^{\circ}C$, which implied the decrease of the ignition temperature by $120{\sim}150^{\circ}C$.

Sn-Doped In₂O₃ 나노잉크를 위한 나노로드의 복합화에 따른 용액기반 투명 전도성 산화물의 저온성능

배주원,구본율,이태근,안효진,Bae, Ju-Won,Koo, Bon-Ryul,Lee, Tae-Kun,Ahn, Hyo-Jin 한국재료학회 2017 한국재료학회지 Vol.27 No.3

Transparent conducting oxides (TCOs) were fabricated using solution-based ITO (Sn-doped $In_2O_3$) nanoinks with nanorods at an annealing temperature of $200^{\circ}C$. In order to optimize their transparent conducting performance, ITO nanoinks were composed of ITO nanoparticles alone and the weight ratios of the nanorods to nanoparticles in the ITO nanoinks were adjusted to 0.1, 0.2, and 0.5. As a result, compared to the other TCOs, the ITO TCOs formed by the ITO nanoinks with weight ratio of 0.1 were found to exhibit outstanding transparent conducting performance in terms of sheet resistance (${\sim}102.3{\Omega}/square$) and optical transmittance (~80.2 %) at 550 nm; these excellent properties are due to the enhanced Hall mobility induced by the interconnection of the composite nanorods with the (440) planes of the short lattice distance in the TCOs, in which the presence of the nanorods can serve as a conducting pathway for electrons. Therefore, this resulting material can be proposed as a potential candidate for solution-based TCOs for use in optoelectronic devices requiring large-scale and low-cost processes.

복합재료를 이용한 시트형 차음재 개발

이동훈(Dong-Hoon Lee),이태근(Tae-Kun Lee),정성균(Seong-Kyun Cheong),이희원(Hee-Won Lee),강문(Moon Kang),김영배(Young-Bae Kim) 한국소음진동공학회 2000 한국소음진동공학회 학술대회논문집 Vol.2000 No.11