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Schiff Base Co(II) 착물이 변성된 유리질 탄소전극에서 산소 환원의 전기촉매 효과
성정섭,채희남,최용국,Seong, Jeong-Sub,Chae, Hee-Nam,Choi, Yong-Kook 한국분석과학회 1998 분석과학 Vol.11 No.6
Schiff base ligands such as $SOPDH_2$, $SNDH_2$, $EBNH_2$, and $PBNH_2$ and their Co(II) complexes such as [$Co(II)(SND)(H_2O)_2$], [$Co(II)(SOPD)(H_2O)_2$], [$Co(II)(EBN)(H_2O)$], and [$Co(II)(PBN)(H_2O)$] have been synthesized. The mole ratio of Shiff base ligand to cobalt(II) for the Co(II) complexes was found to be 1:1. Also these complexes have been configurated with hexa-coordination. Reduction of dioxygen was investigated by cyclic voltammetry at glassy carbon electrodes modified with Schiff base Co(II) complexes in 1 M KOH aqueous solution. At modified glassy carbon electrode with Schiff base Co(II) complexes, reduction peak current of oxygen was increased and peak potential was shifted to more positive direction compared to bare glassy carbon electrode. The electrokinetic parameters such as number of electron and exchange rate constant were calculated from the results of cyclic voltammogrms. The reduction of dioxygen at glassy carbon electrode has been $2e^-$ reaction pathway. Exchange rate constant at glassy carbon electrode modified with Co(II) complexes was increased 2~10 times compared to bare electrode. $SOPDH_2$, $SNDH_2$, $EBNH_2$, $PBNH_2$ Schiff base 리간드와 이들의 [$Co(II)(SND)(H_2O)_2$], [$Co(II)(SOPD)(H_2O)_2$], [$Co(II)(EBN)(H_2O)$], [$Co(II)(PBN)(H_2O)$] 착물들을 합성하였다. Co(II) 착물들에서 Schiff base 리간드와 Co(II)의 몰 결합 비는 1:1로 주어졌으며 6배위 결합을 합성하였다. Co(II) 착물이 수식된 유리질 탄소전극을 사용하여 1 M KOH 수용액에서 산소 환원 반응을 순환 전압전류법으로 알아보았다. Schiff base Co(II) 착물이 수식된 전극에서의 산소의 환원 전류는 알몸 유리질 탄소전극에서 보다 더 증가하였고 환원 전위는 양전위 방향으로 더 이동하였다. 산소 환원 반응에 관여한 전자수와 교환 속도 상수 값은 순환 전압전류 곡선으로부터 구하였다. 산소 환원 반응경로는 최종 생성물이 $H_2O_2$로 가는 $2e^-$ 전이 반응을 나타내었으며 촉매가 수식된 전극에서의 교환 속도 상수는 알몸전극의 값에 비해 약 2~10배 정도 증가하였다.
성정섭(Jeong Sub Seong),김재민(Jae Min Kim) 한국안광학회 1998 한국안광학회지 Vol.3 No.1
Lens centration was the fitting variable that was most dependent on base curve radius. Flatter lenses tended to decenter more. A flatter contact lens will likely have to move into the periphery to reach this point of stability. In most cases, the decentration was in the superior and/or temporal direction. It was also found that comfort complains were more common with flatter lenses. The optimal fits was highest with the 8.4mm base curve lens for all three ranges fit eyes decreased as base curve radius was increased. These lenses with steeper radii lead to better centration and therefore to better fit and comfort for more patients than do thin lenses with flatter radii.
올바른 RGP 렌즈의 처방과 관리용품의 사용에 대한 결과 연구
성정섭(Jeong Sub Seong),홍수학(Soo Hak Hong) 한국안광학회 2000 한국안광학회지 Vol.5 No.2
We performed refraction, keratometry, slit lamp biomicroscopy. We selected 58 current spherical RGP lens wearers for this three - month study. All patients exhibits at least 0.75D of corneal astigmatism measured with the keratometer, and 37 patients had corneal astigmatism of 1.50D or greater. At least follow - up visit, we measured Snellen acuity with lenses, and performed over refraction, overkeratometry and slit lamp biomicroscopy. We charted lens position, movement and surface quality. During the three month, biomicroscopy revealed no corneal edema and neo vascularization on any patients. Fluorescein staining were 52 patients case of grade 0. 5 patients case of grade 1, and 1 patient case of grade 2. In evaluating post-fit residual cylinder, on over refraction as a percentage of refractive cylinder. By the initial visit, one - week visit, one - month visit, and two - month visit are 41 %, 34%. 29%, respectively. In this data, we knew no change after one month. The average overrefraction for these eyes in absolute diopters is 0.26D ( initial visit ) , 0.22D ( one - week visit. 0.17D ( one - month visit ) , and 0.16D ( two - month visit ) . The use of a regimen containing a dedicated daily cleaner was more effective in maintaining patient comfort and lens cleanliness than was the use of a regimen containing only a multipurpose solution.
김재민,성정섭,서은선,고은경,이석주,유근창,Kim, Jai-Min,Seong, Jeong-Sub,Seo, Eun-Sun,Kho, Eun-Kyung,Lee, Seok-Ju,Yoo, Geun-Chang 한국안광학회 2004 한국안광학회지 Vol.9 No.1
우리 몸은 연령의 증가에 따라 눈과 시력에 노화가 나타난다. 본 연구에서는 안구의 연령에 따른 변화를 노인들을 대상으로 조사하여 연령의 증가에 따른 전안부와 후안부 대한 해부생리학적 변화를 고찰하고자 한다. 광주지역 50-79세 사이의 노령자 219명을 대상으로 문진, 외안부 검사, 시력검사, 눈꺼풀 틈새의 높이와 넓이, 가시홍채직경, 동공크기 등을 측정하였다. 연령의 증가에 따라 50대 이상에서는 눈꺼풀 결막, 각막, 전안방, 홍채, 수정체, 유리체, 맥락막, 망막 및 신경, 암순옹, 대비감도, 굴절이상 등에서 변화가 나타남을 알 수 있다. 눈꺼풀 틈새의 높이와 넓이는 연령의 증가로 젊은이 보다 좁아 졌으나 각막의 수평직경은 거의 변화가 없는 것으로 조사되었다. 따라서 노인의 안구와 시력에 대한 해부생리학적인 정확한 이해가 있어야 노인환자의 안경처방이나 시력관리를 완벽하게 할 수 있을 것으로 사료된다. The Human body is subject to two patterns of senescence, both of which are represented in the eye and vision. This article discusses the anatomical and physiological changes in anterior and posterior segments which occur with age. The areas covered include the globe, lids, tears, conjunctiva, cornea, sclera, anterior chamber angle, iris, lens, choroid, vitreous and retina. A sample of 219 individuals between the ages of 50 and 79 years was tested with case history, slit lamp examination, palpebral fissure, horizontal visible iris diameter(HVID) and pupil size. The palpebral fissure decreases with age while HVID remains constant in all age classes. This study suggests that an understanding of anatomical and physiological changes which occur with age is helpful to all eye clinicians because the aging process affects all of the ocular tissues.