석회 종류와 배합비 별 문화재 보수용 석회 모르타르의 초기거동특성과 수축특성 연구

남병직,노상균,김은경,안선아,강소영,Nam, Byeong Jik,Noh, Sang Kyun,Kim, Eun Kyung,Ahn, Sun Ah,Kang, So Yeong 한국문화재보존과학회 2020 보존과학회지 Vol.36 No.6

본 연구는 문화재 보수에 사용되는 소괴 소석회, 분말 소석회, 시판 소석회를 대상으로 배합비에 따른 석회 모르타르의 유동성, 응결시간 및 수축율을 비교하였다. 유동성 시험 결과, 문화재 조적용 석회 모르타르의 최적 배합수 비율은 소괴 소석회 8~10%, 분말 소석회 10~18%, 시판 소석회 17~40%의 범위로 나타났다. 응결시간과 수축율 분석 결과, 문화재수리표준품셈에 기술된 전돌벽쌓기(습식) 대비 종결시간비는 시판 소석회(0.4) < 분말 소석회(5.6) < 소괴 소석회(5.7)의 순으로, 수축율비는 소괴 소석회(1.1) < 분말 소석회(1.2) < 시판 소석회(3.0)의 순으로 나타났다. 물리·화학적 특성 분석 결과, 소석회의 입자크기가 커질수록 최적 배합수 함량은 낮아졌고 응결시간은 지연되며 수축율은 감소하였다. 이와 같은 결과는 향후 건축문화재의 수리·복원 현장에 사용되는 석회 모르타르의 초기거동과 수축특성을 예측하는데 기여할 것으로 판단된다. This study investigated the initial behavior (flowability and setting properties) and shrinkage characteristics of lime mortar, based on the mixing ratio of hydrated lime (lump, powder) and commercial lime, which is primarily used for repairing and restoring cultural assets. The flowability showed that the optimum mixing water contents of the masonry lime mortar were 8-10% for the lump hydrated lime, 10-18% for the powdered hydrated lime, and 17-40% for the commercial hydrated lime. The results of the setting and shrinkage analysis showed that the average final setting time ratio compared to the standard of cultural asset repair was in the increasing order of commercial hydrated lime(0.4) < powder hydrated lime(5.6) < lump hydrated lime(5.7). Moreover, the average shrinkage ratio was ordered as lump hydrated lime(1.1) < powder hydrated lime(1.2) < commercial hydrated lime(3.0). The analysis of the physical and chemical characteristics of hydrated lime showed that the optimum mixing water content was reduced as the particle size of the lime increased, thus delaying the setting time and decreasing the length change rate (shrinkage). These results are expected to contribute to the prediction of the initial behavior and shrinkage characteristics of mortars using handmade and commercial lime during repair and restoration work on cultural, heritage buildings.

결합재 종류 및 배합비에 따른 석회 모르타르의 유동 및 응결특성 연구

남병직(Nam, Byeong Jik),강소영(Kang, So Yeong),노상균(Noh, Sang Kyun) 한국콘크리트학회 2019 한국콘크리트학회 학술대회 논문집 Vol.31 No.2

결합재 종류 및 배합비에 따른 석회 모르타르의 탄산화 및 동결융해 특성 연구

남병직(Nam, Byeong Jik),강소영(Kang, So Yeong),노상균(Noh, Sang Kyun) 한국콘크리트학회 2020 한국콘크리트학회 학술대회 논문집 Vol.32 No.2

실내양생 조건에서 문화재 보수용 소괴 소석회를 사용한 석회 모르타르의 압축강도 예측연구

남병직(Nam, Byeong-Jik),강소영(Kang, So-Yeong) 대한건축학회 2023 대한건축학회 학술발표대회 논문집 Vol.43 No.1

도자기 복원에 사용되는 에폭시계 고분자수지의 요구 특성 연구

남병직 ( Byeong Jik Nam ),정세리 ( Se Ri Jeong ),장성윤 ( Sung Yoon Jang ) 한국접착및계면학회 2012 접착 및 계면 Vol.13 No.4

본 연구는 도자기 복원용 에폭시수지 12종을 대상으로 복원제로서의 요구 특성(내구성, 가공성, 광택특성, 수축 · 팽창특성)을 조사한 후, 이를 통해 효과적인 재료 선택의 기준을 제시하고자 하였다. 내구성 분석결과 액상형은 비교적 손상 정도가 적고 재질 강도가 높은 도자기 유물에, 페이스트형은 상대적으로 손상 정도가 심하고 재질 강도가 약한 토기 유물에 적용하는 것이 보다 효과적 이다. 가공성 분석결과 액상형은 페이스트형보다 높은 표면경도를 보였고, 액상형 중에서는 일반경화형이 속경화형보다 표면경도가 높았다. 따라서 높은 표면경도로 재가공이 어려운 액상형은 향후첨가제 혼합을 통한 물성 개선이 필요하다. 광택특성 분석결과 외관상 무색투명한 액상형이 페이스트형보다 높은 광택도를 보였고, 액상형 중에서는 일반경화형이 속경화형보다 광택도가 높았다. 700°C 연질토기는 페이스트형 중 CDK-520A/520B와 Araldite SV 427-2/HV 427-1이, 청자와 백자는 액상형 중 Devcon 5 minute과 EPO-TEK 301-2, 페이스트형 중 Quik Wood가, 분청사기는 페이스트형중 Quik Wood, 액상형 중 EPO-TEK 301-2와 Devcon 5 minute이 대상 도자기의 광택도에 가장 근접 하였다. 수축 · 팽창특성 분석결과 에폭시수지의 대부분은 경화 중 부피 변화가 발생하였으므로, 수축 · 팽창률에 따른 복원면의 증감을 사전에 예측하여 형태복원 범위를 설정하여야 한다. The demand characteristics of the conventional 12 kinds of epoxy resins which have been used for restoration of the ceramic relics were investigated to provide standards of the effective materials in this study. The result of durability analysis showed that a liquid type is more effective in ceramic relics (low damage, high strength), and a paste type is more effective in earthenware relics (high damage, low strength). The result of workability analysis appears that the liquid type is higher than the paste type, and a slow curing type is higher than a fast curing type in surface hardness. Therefore, in the case of the liquid type which is hard to reprocess due to high surface hardness, it is necessary to conduct a study on improving physical properties by adding filler. The result of the gloss analysis on epoxy resins showed that the liquid type (colorless) has higher gloss than the paste type, and the slow curing type has higher gloss than the fast curing type in liquid types. CDK-520A/520B and Araldite SV 427-2/HV 427-1 showed the most similar gloss to 700°C earthenware, Devcon 5 minute, EPO-TEK 301-2, and Quik Wood showed the most similar gloss to celadon and whiteware, Quik Wood, EPO-TEK 301-2, and Devcon 5 minute showed the most similar gloss to buncheongware. It is necessary for conservator to decide the range of the restoration surface by predicting the increase and decrease of the restoration surface because most of the epoxy resins caused the volume change in curing process.

태안 마도 출토 도자기의 염에 의한 손상상태 연구

장성윤,남병직,박대우,강현미,정용화,Jang, Sung-Yoon,Nam, Byeong-Jik,Park, Dae-Woo,Kang, Hyun-Mi,Jung, Yong-Hwa 국립문화재연구소 2009 保存科學硏究 Vol.30 No.-

Ceramics from Taean shipwreck were studied to investigate the deterioration by soluble salts and desalination pattern according to each ceramic characterization. NaCl crystals were found as a crystal growth on the ceramic microstructure and deteriorated to push off the glaze layer of some Puncheong ware sample. As a result of monitoring the desalination pattern of ceramics for 74days, the earthenware sample with big pores and no glaze removed soluble salts so fast, but Puncheong ware and Whiteware samples removed lots of soluble salts slowly and continuously. Generally, it takes long time to remove soluble salts from porcelains, due to small pores and glaze, but the long-term desalination probably can cause the damage on the surface layer such like glaze. As some soluble salts still remains in the ceramic microstructures after desalination, it is very important to control and keep the relative humidity stable through the proper storage. There are various ceramic deterioration patterns by soluble salts. Therefore, it needs to select the desalination method of ceramics from shipwreck, considering the material characteristics and the production techniques.

보존처리용 세척제에 대한 토기의 이온용출 특성연구

박대우,강현미,남병직,장성윤,함철희,Park, Dae-Woo,Kang, Hyun-Mi,Nam, Byeong-Jik,Jang, Sung-Yoon,Ham, Chul-Hee 국립문화재연구소 2010 保存科學硏究 Vol.31 No.-

This study intends to provide quantitative data about the extraction characteristics of major elements of earthenware by executing soaking test of cleaning agents. It aims at providing basic data for the stability assessment when applying the cleaning agents for conserving earthenware. The data will be extracted from the analysis of co-relationship between the physical characteristics and the ion extraction characteristics. XRD analysis displayed that AT-1, AT-2 and AT-3 which did not generate mullite were fired at lower than 1,000 whereas AT-3 and AT-5 that included mullite were higher than 1,000. The degree of absorption was AT-4 > AT-2 > AT-1 > AT-3 > AT-5 in order and the correlation between the degree of absorption and firing temperature of earthenware displayed a positive correlation. Extraction amount of oxalic acid which was used for the removing iron oxide was AT-1 > AT-2 AT-4 > AT-3 > AT-5 in order. and the ion extraction data displayed that there is a positive correlation with absorption level. However AT-1 and AT-2 which were fired at lower temperature showed that there was no correlation between the ion extraction characteristics and absorption level. Ion extraction of citric acid produced little amount compared with the one of oxalic acid, yet it caused less damage to earthenware than oxalic acid when it applied. The result of ion extraction level in the absorption test displayed that Fe had higher level than in Si, Al from the test for both oxalic acid and citric acid. Based on the regression analysis of the data from the previous studies, the physical characteristics of the earthenware and ion extraction level, further studies will be conducted on the predicting technique on the extraction characteristics of major elements of earthenware samples for the conservation in future.

토기의 복원재료로 사용되는 합성수지 제거 연구

김효윤,박대우,남병직,장성윤,Kim, Hyoyun,Park, Daewoo,Nam, Byeongjik,Jang, Sungyoon 국립문화재연구소 2011 保存科學硏究 Vol.32 No.-

국내에서 토기 복원에 주로 사용하는 접착제 3종: Cemedine C, Loctite$^{(R)}$ 401$^{TM}$, Araldite Rapid Type와 메움제 3종: 석고, CDKI 520 A+B, Araldit$^{(R)}$ SV 427-2+HV 427-1의 제거효과에 대해 연구했다. 1차 실험에서 각각의 재료들을 여러 용제에 침적해 연화의 정도(Soften level)를 비교하고, 2차 실험은 연질토기 시료와 경질토기 시료에 재료들로 복원하여 침적법과 증기법의 효과를 비교했다. 1차 실험 결과 Cemedine C와 Loctite는 아세톤에 쉽게 녹았고, Plaster(석고)는 인산나트륨에 효과적으로 제거되었다. Araldite Rapid Type와 CDKI 520과 SV427은 Dichloromethan, Tetrahydrofuran, DMX (Dichloromethan + Methanol + Xylene)에 효과적으로 제거되었다. 2차 연구는 1차 연구를 토대로 제거에 효과적이라 판단되는 용제를 각각 침적법과 증기법으로 제거하였다. 대부분의 시료에 적용된 재료들은 침적법으로 10분 이내에, 증기법으로는 약 24시간 후에 제거되었다. This study examines the removal effects of solvents which were applied on three adhesives and three filling materials for ceramics. The chosen materials are Cemedine C, Loctite$^{(R)}$ 401$^{TM}$, Araldite Rapid Type, plaster of paris, CDKI 520A+B, Araldit$^{(R)}$ SV427-2+HV427-1. For the first examination, each different materials were soaked into different solvents, and then the soften level were compared by compressive pressure. The result of the first exam showed that Cemedine C was dissolved easily in acetone. Furthermore Araldite, CDK and SV427 were soften efficiently by Dichloromethan, Tetrahydrofuran and DMX(Dichloromethan+Methanol+Xylene). However, Loctite and plaster were not able to make sample for the first test. Therefore, the second test carried on only. The second examination, chosen effective solvents from the first test were applied with two different methods; soaking and saturated atmosphere. Almost every sample could removed by soaking method in ten minutes, and saturated atmosphere method needs 24 hours for the safety.

혼화제 첨가에 따른 기경성 석회의 경화 전 특성

강산하(Kang, San-Ha),남병직(Nam, Byeong-Jik),윤은영(Yun, Eun-Young) 대한건축학회 2023 대한건축학회논문집 Vol.39 No.7