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비수용매속에서 Eriochrome Black-T의 폴라로그래피적 거동에 관한 연구
金世奉,金一斗,丁梧鎭 조선대학교 기초과학연구소 1988 自然科學硏究 Vol.11 No.1
The electrochemical reduction mechanism of the E. C. B. T in dimethylsulfoxide and system on the addition of proton donor with water was studied. A single two-electron wave, irreversible step below pH5.5 was observed and also irreversible step above pH 6. 1 to pH10.6 was obtained two one-electron waves, and two two-electron waves, respectively. A probable mechanism of the reduction step of each pH range has been proposed.
混合리간드를 抱合하는 팔라듐(Ⅱ) 錯物의 合成과 結合性質에 關한 硏究
金奉坤,金世奉 慶尙大學校 1984 論文集 Vol.23 No.2
Palladium(Ⅱ) complexes with diamines such as ethylenediamine(en), propylenediamine(pn), cyclohexanediamine(chxn) and trimethylenediamine(tn), and phosphines such as triphenylphosphine, 1,2-bis[(diphenylphosphino) amino] propane that contain phosphines atom as sigma-donor and pi-electron accepter were prepared, and the bond character of ligand for complexes have been investigated by means of infrared and UV-Visible spectroscopy.