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Rui Yong,Xi Fu,Man Huang,Qifeng Liang,Shi-Gui Du 대한토목학회 2018 KSCE JOURNAL OF CIVIL ENGINEERING Vol.22 No.1
An accurate measurement of the Joint Roughness Coefficient (JRC) of large rock joints is essential for understanding the mechanical behavior and permeability characteristics of rock mass. Determining the surface roughness of rock joints in situ, however, is timeconsuming and depends on sophisticated instruments. This study was carried out to develop a systematic method of measuring the JRC values of large joint roughness profiles. The roughness profiles were accurately recorded by a hand profilograph in the field and then digitized with flexibly adjusted sampling intervals by the grayscale image processing method. The digitized profiles were correlated closely with the original roughness profiles. A computerized approach for JRC quantitative evaluation was proposed based on the roughness amplitude/joint length relationship with JRC. The interval effect analysis showed that this method was effective for estimating the JRC values of different sized rock joints. This JRC measurement method has been successfully used in a case study of killas rock joints in Changshan City, P.R. China.
RUIYONG WANG,SHUMIN FAN,RUIQIANG WANG,RUI WANG,HUANJING DOU,LVJING WANG 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2013 NANO Vol.8 No.4
A sensitive and selective colorimetric biosensor for determination of gentamicin, amikacin and tobramycin was proposed with the unmodified gold nanoparticles (GNPs) as the sensing element. Gentamicin, amikacin and tobramycin can rapidly induce the aggregation of gold nanoparticles and is accompanied by a color change from red to blue. The concentration of gentamicin, amikacin and tobramycin can be determined by using UV-Vis spectrometer. The experimental parameters were optimized with regard to pH, incubation time and the concentration of the GNPs. Under optimal experimental conditions, the linear range of the colorimetric sensor for gentamicin/amikacin/tobramycin were 2.67–33.93 ng mL-1, 13.33–66.67 ng mL-1 and 20–180 ng mL-1, respectively. The corresponding limit of detection (3σ) was 0.354 ng mL-1, 0.999 ng mL-1 and 0.579 ng mL-1, respectively. This assay was simple and used to detect aminoglycoside antibiotics in milk and medicine products.
Chang, Zhenjun,Henkensmeier, Dirk,Chen, Ruiyong Wiley (John WileySons) 2017 ChemSusChem Vol.10 No.16
<P>By using a one-step epoxide ring-opening reaction between 4-hydroxy-2,2,6,6-tetramethylpiperidine 1-oxyl (4-hydroxy-TEMPO) and glycidyltrimethylammonium cation (GTMA(+)), we synthesized a cation-grafted TEMPO (g(+)-TEMPO) and studied its electrochemical performance against a Zn2+/Zn anode in a hybrid redox flow battery. To conduct Cl- counter anions, a crosslinked methylated polybenzimidazole (PBI) membrane was prepared and placed between the catholyte and anolyte. Compared to 4-hydroxy-TEMPO, the positively charged g(+)-TEMPO exhibits enhanced reaction kinetics. Moreover, flow battery tests with g(+)-TEMPO show improved Coulombic, voltage, and energy efficiencies and cycling stability over 140 cycles. Crossover of active species through the membrane was not detected.</P>
Kunpeng Liu,Nan Wang,Jianhua Li,Fanglin Du,Baorong Hou,Ruiyong Zhang 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.128 No.-
Electrochemical two-electron water oxidation reaction (2e WOR) to produce H2O2 has been widely concerned. However, four-electron competition reaction causes the large overpotential and low productionrates of 2e WOR, which restrict its’ development and application. Herein, we prepared N-TiO2 derivedfrom NH2-MIL-125 by the hydrothermal combined with calcination method. We found that N-TiO2 asphotoanode exhibited the well properties of photoelectrocatalysis water oxidation, which gave an overpotentialof 630 mV at 1 mA cm2. The overpotentials of N-TiO2 was approximately 130 mV (at1 mA cm2) lower than NH2-MIL-125, and even lower than the previous reported TiO2, which may attributeto the increased oxygen vacancy with the calcination process and N doping. In addition, we investigatedthe degradation performance of the prepared catalysts to degrade methylene blue byphotoelctrocatalysis on-site the preparation of H2O2. It was shown that N-TiO2 performed high degradationefficiency (91%) and excellent stability. The possible mechanism was speculated due to theincreased oxygen vacancy and N doping. This work provides a new idea for photoelectrocatalysis wateroxidation materials and points out a new way for on-site H2O2 production for direct use