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Development of High Strength Glass-ceramic using Slag for Industrial Application
( Dongyoon Shin ),( Mijung Yoon ),( Hyunseo Park ),( Sungmo Seo ),( Jin-ho Yoon ) 한국폐기물자원순환학회(구 한국폐기물학회) 2015 한국폐기물자원순환학회 춘계학술발표논문집 Vol.2015 No.-
In Korean steel making industry is generating 25 billion tons of slag as industrial by-products per year. Uses of these slags to manufacture high functional abrasive material are of greater feasible option for sustainable development of industry as well as effectively solve the pollution issue associated with these waste. Recycling methods of slag have been actively studied for decades, but most of the slag recycling methods studied are related to low cost building materials. Recently, several combinations of by-products have been used in glass-ceramic manufacturing, mostly the abrasive materials are basalt based glassceramic. Using these industrial by-products instead of natural basalt ores, high functional product can be manufactured. This piece of investigation focused on the feasibility study for producing the basalt based glass-ceramic from recycled industrial by-products only, without any natural materials as raw materials. By controlling various process parameters like, mixture ratios of materials, heat treatment for casting, and soaking basalt based glass-ceramic were prepared. The prepared materials were characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscope (SEM), thermo-gravimetry and differential thermal analysis (TG-DTA). Excellent material properties were observed.
Development of High Strength Glass-ceramic using Slag for Industrial Application
Dongyoon Shin,Jin-Ho Yoon,Mijung, Yoon,Hyunseo Park,Sungmo Seo 한국폐기물자원순환학회 2015 한국폐기물자원순환학회 학술대회 Vol.2015 No.05
In Korean steel making industry is generating 25 billion tons of slag as industrial by-products per year. Uses of these slags to manufacture high functional abrasive material are of greater feasible option for sustainable development of industry as well as effectively solve the pollution issue associated with these waste. Recycling methods of slag have been actively studied for decades, but most of the slag recycling methods studied are related to low cost building materials. Recently, several combinations of by-products have been used in glass-ceramic manufacturing, mostly the abrasive materials are basalt based glass-ceramic. Using these industrial by-products instead of natural basalt ores, high functional product can be manufactured. This piece of investigation focused on the feasibility study for producing the basalt based glass-ceramic from recycled industrial by-products only, without any natural materials as raw materials. By controlling various process parameters like, mixture ratios of materials, heat treatment for casting, and soaking basalt based glass-ceramic were prepared. The prepared materials were characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscope (SEM), thermo-gravimetry and differential thermal analysis (TG-DTA). Excellent material properties were observed.
Shin, Young Min,Kim, Taek Gyoung,Park, Jong-Seok,Gwon, Hui-Jeong,Jeong, Sung In,Shin, Heungsoo,Kim, Kyung-Soo,Kim, Dongyoon,Yoon, Myung-Han,Lim, Youn-Mook The Royal Society of Chemistry 2015 Journal of Materials Chemistry B Vol.3 No.13
<P>The alginate hydrogel has been used as an attractive scaffold for tissue regeneration. In particular, its simple cross-linking, high water absorption, and biocompatibility have facilitated its utility in regulating the interaction with cells or organs. However, three-dimensional (3D) networks of the alginate hydrogel do not provide fibrous anchorage sites such as the collagen fibres in the natural extracellular matrix (ECM). This has partially limited the survival of anchorage-dependent cells in the 3D hydrogel environment. In this report, we established a hybrid hydrogel containing fibrous particles (FP) that closely mimics the ECM. The RGD peptide-coupled FP (R-FP) has a wide range of distribution and was homogeneously dispersed in the hydrogel. The encapsulated human mesenchymal stem cells in the hydrogel could bind to the R-FP presenting remarkable spreading morphology, augmented viability and differentiation. These findings may elicit the significance of a physical interaction in which the R-FP provides structural and biological cues to the cells. This strategy can be widely applicable to a variety of hydrogel systems.</P>
Dongyoon Shin,Richard I. Foster,Wonseok Yang,Shuang Liu,Woohyun Lim,Sungyeol Choi 한국방사성폐기물학회 2023 한국방사성폐기물학회 학술논문요약집 Vol.21 No.1
Aluminum’s exceptional properties, such as its high strength-to-weight ratio, excellent thermal conductivity, corrosion resistance, and low neutron absorption cross-section, make it an ideal material for diverse nuclear industry applications, including aluminum plating for the building envelope of nuclear power plants. However, plating aluminum presents challenges due to its high reactivity with oxygen and moisture, thus, complicating the process in the absence of controlled environments. Plating under an inert atmosphere is often used as an alternative. However, maintaining an inert atmosphere can be expensive and presents an economic challenge. To address these challenges, an innovative approach is introduced by using deep eutectic solvents (DES) as a substitute for traditional aqueous electrolytes due to the high solubility of metal salts, and wide electrochemical window. In addition, DESs offer the benefits of low toxicity, low flammability, and environmentally friendly, which makes DESs candidates for industrial-scale applications. In this study, we employed an AlCl3-Urea DES as the electrolyte and investigated its potential for producing aluminum coatings on copper substrates under controlled conditions, for example, current density, deposition duration, and temperature. A decane protective layer, non-polar molecular, has been used to shield the AlCl3-Urea electrolyte from the air during the electrodeposition process. The electrodeposition was successful after being left in the air for two weeks. This study presents a promising and innovative approach to optimizing aluminum electrodeposition using deep eutectic solvents, with potential applications in various areas of the nuclear industry, including fuel cladding, waste encapsulation, and radiation shielding.
On the Origin of Electrocatalytic Oxygen Reduction Reaction on Electrospun Nitrogen–Carbon Species
Shin, Dongyoon,Jeong, Beomgyun,Mun, Bongjin Simon,Jeon, Hongrae,Shin, Hyun-Joon,Baik, Jaiyoon,Lee, Jaeyoung American Chemical Society 2013 JOURNAL OF PHYSICAL CHEMISTRY C - Vol.117 No.22
<P>Nitrogen–carbon (N–C) species is a potential electrocatalyst for oxygen reduction reaction (ORR) in electrochemical energy conversion cells, but its mechanistic origin of ORR on the N–C surface is still unclear. We show our facile approach to the synthesis of highly active Co-modified N–C catalyst and investigated the origin of ORR activity of electrospun N–C species by removing the metal with hydroxide carbon etching and acid metal leaching. Through the detailed investigation on the origin of ORR electrocatalysis for electrospun N–C nanofibers, we revealed that pyrrolic-N and highly graphitized carbon structure are mainly responsible for the enhanced ORR activity of metal-free N–C nanofiber and embedded Co metal got involved in the creation of the pyrrolic N site.</P><P><B>Graphic Abstract</B> <IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/jpccck/2013/jpccck.2013.117.issue-22/jp401186a/production/images/medium/jp-2013-01186a_0007.gif'></P><P><A href='http://pubs.acs.org/doi/suppl/10.1021/jp401186a'>ACS Electronic Supporting Info</A></P>
사진측량용 UAV 시스템을 이용한 정사영상 제작 및 활용성 평가
신동윤 ( Dongyoon Shin ),한지혜 ( Jihye Han ),진유진 ( Yujin Jin ),박재영 ( Jaeyoung Park ),정호현 ( Hohyun Jeong ) 대한원격탐사학회 2016 大韓遠隔探査學會誌 Vol.32 No.3
본 연구는 스마트 카메라를 탑재한 무인항공기를 통해 얻은 영상을 이용하여 카메라 검정 유무에 따른 정사영상의 정확도를 분석하였다. 사진측량용 무인항공 시스템이 개발되었고, 스마트 카메라영상은 image triangulation을 거쳐, 정사영상으로 생성되었다. Image triangulation은 카메라 검정에서 결정된 Interior Orientation (IO) 파라미터의 고려 유무에 따라 수행되었다. 카메라 검정 결과, RMS error가 0.57 pixel로 나타났고, 이것은 비측량용 카메라를 이용한 기존의 연구와 비교했을 때, 우수한 정확도이다. Field experiment에서 IO 파라미터를 고려한 경우, triangulation 결과는 0.1 pixel (RMSE) 이내로 나타났고, 이 것은 IO 파라미터를 고려하지 않은 경우에 비해 최소 2배 이상 향상된 결과였다. 정사영상을 제작한 결과, 카메라 검정 자료를 고려한 결과는 고려하지 않은 결과에 비해 정확도가 89 % 향상되었다. UAV 시스템을 위한 탑재체로써 스마트 카메라의 활용 가능성이 높으며, 직접 또는 간접적인 기능을 충분히 담당할 수 있을 것으로 기대된다. This study analyzes the accuracy of ortho imagery based on whether camera calibration performed or not, using an unmanned aerial vehicle which equipped smart camera. Photgrammetric UAV system application was developed and smart camera performed image triangulation, and then created image as ortho imagery. Image triangulation was performed depending on whether interior orientation (IO) parameters were considered or not, which determined at the camera calibration phase. As a result of the camera calibration, RMS error appeared 0.57 pixel, which is more accurate compared to the result of the previous study using non-metric camera. When IO parameters were considered in static experiment, the triangulation resulted in 2 pixel or less (RMSE), which is at least 200 % higher than when IO parameters were not considered. After generate ortho imagery, the accuracy is 89% higher when camera calibration are considered than when they are not considered. Therefore, smart camera has high potential to use as a payload for UAV system and is expected to be equipped on the current UAV system to function directly or indirectly.