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Hao Wang,Jiangyue Dai,Huilun Chen,Fei Wang,Yangchen Zhu,Jia Liu,Beihai Zhou,Rongfang Yuan 대한환경공학회 2023 Environmental Engineering Research Vol.28 No.2
In this study, Mg/Fe-doped biochar (MFDB) was prepared using the impregnation pyrolysis method, and its preparation was optimized using response surface methodology (RSM). The competitive adsorption between dissolved organic matter (DOM) and phosphorus was also investigated. The best adsorption capacity was obtained with an ㎎ impregnation ratio of 3.17:1 (Mg: biomass, g:g), Fe impregnation ratio of 1.3:1 (Fe: biomass, g:g), and pyrolysis temperature of 491℃. The adsorption capacity of MFDB for phosphorus was 179.21 ㎎/g at 40℃, an initial phosphate concentration of 50 ㎎/g and pH 4. The phosphate adsorption by MFDB conformed to a pseudo-primary and secondary adsorption kinetic model, proving the coexistence of physical and chemical adsorption. The adsorption mechanisms, including ligand exchange, electrostatic interaction, and complexation reaction were revealed. As the pH increased, it weakened the electrostatic interaction of phosphate by MFDB and the ligand exchange between phosphate and OH⁻. When the pH was less than 3, the metal oxide dissolved. For pH values exceeding, OH⁻ competed with phosphate for adsorptio, which also weakened the complexation of phosphate and MFDB. The DOM in domestic wastewater had a slight effect on the phosphorus adsorption. The phosphorus removal rates were closely related to lignin-like humic acid and tryptophan.
Hu Boran,Gao Jin,Xu Shaochen,Zhu Jiangyu,Fan Xuemei,Zhou Xiaoyan 한국응용생명화학회 2020 Applied Biological Chemistry (Appl Biol Chem) Vol.63 No.3
The metabolites that provide the aroma and flavor to wine are the products of several influences, such as grape cultivar, geographic location and associated environmental features, viticultural practices, and vinification techniques, which are central to production protocols, quality evaluation and development of wine regions. Accordingly, we initiated the requisite studies to investigate the differences in the dry red wine metabolites of different grape varieties. The proton-nuclear magnetic resonance technique (1H-NMR) combined with multivariate statistical analysis was used to investigate the changes of metabolite levels in Cabernet Sauvignon, Merlot and Cabernet Gernischt dry red wines vinified in Changli, Hebei province, China, in 2017. The results showed that the types of metabolites in different varieties of dry red wines were similar, but the content was significantly different. The main contributors to the differences in Cabernet Sauvignon, Merlot and Cabernet Gernischt dry red wines were ethyl acetate, lactic acid, alanine, succinic acid, proline, malic acid, and gallic acid, indicating 1H-NMR method combined with multivariate statistical analysis can distinguish these three types of dry red wines from each other. It provides a benchmark for further comparative study on wine quality and the verification of wine authenticity.
New Hanger Design Approach of Tied-Arch Bridge to Enhance Its Robustness
Wenqing Wu,Hao Wang,Yan-Jie Zhu,Jiangyu Yu,Hao Zhao,Hui Zhang 대한토목학회 2018 KSCE JOURNAL OF CIVIL ENGINEERING Vol.22 No.11
As the crucial components among the tied-arch bridge, the local failure of hangers may trigger a progressive collapse through the entire tied-arch bridge. However, the current design guidance as regards hangers still lacks consideration of structure robustness under an extreme hazard. To improve the structural robustness of tied-arch bridge under extreme conditions, a new hanger design method is proposed, which is termed as asymmetric parallel double-hanger system. Based on Miner’s linear cumulative damage law, an analysis on the fatigue life of the double-hanger system was conducted to verify the feasibility of the proposal, and then a dynamic time-history analysis was employed to simulate the transitory fracture impact due to one or more hangers fracturing. According to the simulation results, the structural robustness is greatly enhanced with asymmetric parallel-double hanger system design, when compared with single hanger system design. When one or more hangers reveal local damage, it will not trigger a progress failure to the whole structure in particular. Several practical suggestions of bridge system’s load-carrying capacity are also put forward for the future arch bridge design at the end of this paper.