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Xiaoming Zhu,Xiaoyu Jiang,Haiyan Lu,Xinping Ai,Hanxi Yang,Yuliang Cao 한국물리학회 2014 Current Applied Physics Vol.14 No.4
Stacked-nanoflake Li4Ti5O12 spinel was synthesized via the pyrolysis of a LieTi copolymeric precursor formed by in situ polymerization of LiOH and [Ti(OC4H9)4] and acrylic acid. XRD and SEM characterization shows that the powders calcined at 700 C for 3 h was well-crystallized particles with submicron diameter. Chargeedischarge measurement showed the Li4Ti5O12 electrode had displayed excellent rate capability and delivered reversible capacity of 171, 158, 148, 138 and 99 mAh g1 at rates of 0.1C, 0.5C, 1C, 2C and 4C, respectively. The test electrode also showed excellent cyclability as the capacity retains 96.1% after 60 cycles between 0.5 and 2.5 V.
Yifu Zhang,Min Zhou,Meijuan Fan,Chi Huang,Chongxue Chen,Yuliang Cao,Houbin Li,Xinghai Liu 한국물리학회 2011 Current Applied Physics Vol.11 No.5
V_3O_7ㆍH_2O@C core-shell structured composites have been successfully synthesized using V_3O_7ㆍH_2O nanobelts as the cores and glucose as the source of carbon in the presence of sodium lauryl sulfate (SDS). The as-obtained V_3O_7ㆍH_2O@C core-shell materials were characterized by X-ray powder diffraction (XRD),transmission electron microscopy (TEM), elemental analysis (EA), Fourier transform infrared spectroscopy (FT-IR) and Raman spectrum. The thickness of the carbon shell can be controlled by the hydrothermal reaction time and the quantity of glucose. The surfactants have great influence on fabricating V_3O_7ㆍH_2O@C core-shell composites, which have been discussed in detail. V_3O_7@C composites were subsequently obtained through thermal treatment with V_3O_7ㆍH_2O@C. The electrochemical properties of V_3O_7@C core-shell composites were studied, indicating that the discharge capacity is still 151.2 mAh/g after 45 cycles, which is better than that of pure V_3O_7ㆍH_2O nanobelts.
Yifu Zhang,Chongxue Chen,Juecheng Zhang,Ling Hu,Weibing Wu,Yalan Zhong,Yuliang Cao,Xinghai Liu,Chi Huang 한국물리학회 2013 Current Applied Physics Vol.13 No.1
VO2(M) nanobelts encapsulated into carbon coreeshell structured composite (VO2(M)@C) was successfully synthesized by the thermal treatment with the precursor V3O7$H2O@C composite under the inert atmosphere. The as-obtained sample was characterized by XRD, EDS, EA, FT-IR, Raman, SEM and TEM measurements. The core exhibited monoclinic phase VO2(M) and the carbon coated on the surface of VO2(M) was amorphous. The average thickness of carbon was about 18.5 nm. The possible formation mechanism of VO2(M)@C was proposed as that the reaction underwent the solid state reaction by the interface reaction between V3O7 core and carbon shell. Furthermore, VO2(M) and VO2(M)@C composite were explored as the cathode materials to apply in lithium-ion batteries, indicating that the VO2(M)@C composite electrode exhibited the better electrochemical properties than that of pure VO2(M), achieving the aim of improving the electrochemical properties of VO2(M).
Nanophase ZnV2O4 as stable and high capacity Li insertion electrode for Li-ion battery
Xiaoming Zhu,Xiaoyu Jiang,Lifen Xiao,Xinping Ai,Hanxi Yang,Yuliang Cao 한국물리학회 2015 Current Applied Physics Vol.15 No.4
Spinel ZnV2O4 nanoparticles are synthesized by a hydrothermal method and its properties are characterized using XRD, SEM, TEM, and electrochemical test. The structural and morphological characterizations show that ZnV2O4 sample has high purity and well crystallization with crystal size less than 20 nm. The as prepared electrode shows stable capacity over 660 mAh g-1 in the voltage range of 0.01-3.0 V at 50 mA g-1. The reaction mechanism with lithium ion is also investigated through ex-XRD and -TEM. It shows that the pristine ZnV2O4 is transformed to isostructural spinel LixV2O4 (x close to 7.6) and metal Zn phase during the first lithiation process. Then the spinel LixV2O4 seems to perform a topotactic intercalation reaction mechanism and that the in-situ formed LixV2O4 can still keep its spinel matrix while allowing more than 5.7 lithium reversibly into/out over 50 cycles.