Properties of Citric Acid-bonded Composite Board from Elephant Dung Fibers

( Ragil Widyorini ),( Greitta Kusuma Dewi ),( Widyanto Dwi Nugroho ),( Tibertius Agus Prayitno ),( Agus Sudibyo Jati ),( Muhammad Nanang Tejolaksono ) 한국목재공학회 2018 목재공학 Vol.46 No.2

An elephant digests only around 30~45% of what it consumes; therefore the undigested material mainly passes as intact fibres. Elephant food is usually composed of grass, leaves, twigs, bark, fruit and seed pods. This research aimed to utilize the elephant dung fibers as material for composite board and citric acid as a bonding agent. Citric acid contents in this research were set at 0 wt% (binderless composite board), 10 wt%, 20 wt%, and 30 wt% based on dry weight particles, while the target density was set at 0.8 g/cm³. Pressing temperatures were set at 180℃ and 200℃ with the pressing time was 10 minutes. Physical and mechanical properties tests were then performed according to Japanese Industrial Standard A 5905. The result showed that elephant dung fibers could be used as potential materials for composite board. Addition of citric acid and pressing temperature significantly increased the quality of composite board. Infrared analysis indicated that the presence of ester linkages much higher with the increasing of citric acid content and pressing temperature. The optimum properties of composite board made from elephant dung fibers could be achieved at pressing temperature of 200℃ and a citric acid content of 20 wt%.

Bonding Performance of Maltodextrin and Citric Acid for Particleboard Made From Nipa Fronds¹

Mahdi Santoso,Ragil Widyorini,Tibertius Agus Prayitno,Joko Sulistyo 한국목재공학회 2017 목재공학 Vol.45 No.4

Maltodextrin and citric acid are two types of natural materials with the potential as an eco-friendly binder. Maltodextrin is a natural substance rich in hydroxyl groups and can form hydrogen bonds with lignoselulosic material, while citric acid is a polycarboxylic acid which can form an ester bond with a hydroxyl group at lignoselulosic material. The combination of maltodextrin and citric acid as a natural binder materials supposed to be increase the ester bonds formed within the particleboard. This research determined to investigate the bond-ing properties of a new adhesive composed of maltodextrin/citric acid for nipa frond particleboard. Maltodextrin and citric acid were dissolved in distillated water at the ratios of 100/0, 87.5/12.5, 75/25 and 0/100, and the concentration of the solution was adjusted to 50% for maltodextrin and 60% citric acid (wt%). This adhesive solution was sprayed onto the particles at 20% resin content based on the weight of oven dried particles. Particleboards with a size of 25 × 25 × 1 cm, a target density 800 kg/m³ were prepared by hot-pressing at press temperatures of 180℃ or 200℃, a press time of 10 minute and board pressure 3.6 MPa. Physical and mechanical properties of particleboard were tested by a standard method (JIS A 5908). The results showed that added citric acid level in maltodextrin/citric acid composition and hot-pressing temperature had affected to the properties of particleboard. The optimum properties of the board were achieved at a pressing temperature of 180℃ and the addition of only 20% citric acid. The results also indicated that the peak intensity of C=O group increased and OH group decreased with the addition of citric acid and an increase in the pressing temperature, suggesting an interreaction between the hydroxyl groups from the lignocellulosic materials and carboxyl groups from citric acid to form the ester groups.

Properties of a New Adhesive Composed of Gambir-Sucrose

( Tito Sucipto ),( Ragil Widyorini ),( Tibertius Agus Prayitno ),( Ganis Lukmandaru ) 한국목재공학회 2020 목재공학 Vol.48 No.3

Gambir is a non-wood forest product with a potential of being used as wood adhesive, due to about 33% catechin in it. Meanwhile, catechins and sucrose have not been studied as adhesives. Therefore, basic characteristics of gambir-sucrose adhesives were investigated. In this research, adhesives were prepared by dissolving gambir and sucrose in distilled water, at different blending ratios of the gambir/sucrose such as 100/0, 75/25, 50/50, and 25/75 wt%. Furthermore, gas chromatography-mass spectrometry (GC-MS) was employed to determine the gambir chemical compositions, and Fourier transform-infrared (FTIR) spectroscopy was carried out to identify chemical bonds. Particleboards with a target density of 0.8 g/cm3 were then manufactured by hot-pressing for 10 min at 200℃. The internal bond (IB) strength of particleboard was subsequently measured. Based on the GC-MS analysis, 31.11% of catechin was identified. In addition, the viscosity, density, solid content, and gelation time of the adhesives, and insoluble matter content (IMC) in boiling water were 7.30~33.24 mPa.s, 1.2~1.3 g/cm3, 25.56~28.44%, 73~420 min, and 29.75~62.10%, respectively. Adding sucrose to the adhesive was observed to raise the IMC from 49.05 to 62.10%, at 180℃ and 200℃. FT-IR analysis showed that the gambir absorption peaks occurred at approximately 1620 cm-1, assigned to the C=O stretching of 5-hydroxymethylfurfural, which tended to increase with the addition of sucrose. The reaction between gambir and sucrose was observed in the form of the dimethylene ether bridge. The 25/75 wt% gambir-sucrose adhesives and 200℃ hot-pressed temperature resulted in the highest IB strength (0.89 MPa), and met the requirement of JIS A5908-2003 type 18. Consequently, the gambir-sucrose adhesive could be used as a particleboard adhesive.

Effect of Different Conditions of Sodium Chloride Treatment on the Characteristics of Kenaf Fiber-Epoxy Composite Board

Tamaryska SETYAYUNITA,Ragil Widyorini,Sri Nugroho Marsoem,Denny Irawati 한국목재공학회 2022 목재공학 Vol.50 No.2

Currently, biofibers are used as a reinforcement in polymer composites for structural elements and construction materials instead of the synthetic fibers which cause environmental problems and are expensive. One of the chemicals with a pH close to neutral that can be potentially used as a modified fiber material is sodium chloride (NaCl). Therefore, this study aims to investigate the characteristics of a composite board made from NaCl-treated kenaf fiber. A completely randomized design method was used with consideration of two factors: the content of NaCl in the treatment solution (1 wt%, 3 wt%, and 5 wt%) and the duration of immersion of fibers in the solution (1 h, 2 h, and 3 h). The NaCl treatment was conducted by soaking the fibers in the solution for different durations. The fibers were then rinsed with water until the pH of the water reached 7 and subsequently dried inside an oven at 80℃for 6 h. Kenaf fiber and epoxy were mixed manually with the total loading of 20 wt% based on the dry weight of the fiber. Physical and mechanical properties of the fibers were then evaluated based on JIS A 5908 particleboard standards. The results showed that increasing NaCl content in the fiber treatment solution can increase the physical and mechanical properties of the composite board. The properties of fibers treated with 5 wt% NaCl for 3 h were superior with a modulus of elasticity of 2.085 GPa, modulus of rupture of 19.77 MPa, internal bonding of 1.8 MPa, thickness swelling of 3%, and water absorption of 10.9%. The contact angle of untreated kenaf fibers was 104°, which increased to 80° and 73° on treatment with 1 wt% and 5 wt% NaCl for 3 h, respectively.

Effect of Different Conditions of Sodium Chloride Treatment on the Characteristics of Kenaf Fiber Bundles

Tamaryska SETYAYUNITA,Ragil Widyorini,Sri Nugroho Marsoem,Denny Irawati 한국목재공학회 2022 목재공학 Vol.50 No.6

Currently, composite board manufacturing using natural fibers has the potential to expand owing to environmental awareness. To produce a composite board, treatment is required to improve the mechanical and physical properties of the natural fibers. In this study, sodium chloride (NaCl) was used for the chemical treatment. However, studies on chemical treatments using NaCl are limited. This study aimed to investigate the characteristics of kenaf fibers after NaCl treatment. The NaCl treatment concentrations were 1, 3, and 14 5 wt.% at room temperature, with soaking durations of 1, 2, and 3 h. The tensile strength, strain, and Young’s modulus were measured to evaluate the mechanical properties of the fibers. The fiber bundle diameter, weight change owing to treatment, and contact angle were determined to analyze the effect of NaCl treatment. The kenaf fiber bundle treated with 5 wt.% NaCl for 3 h exhibited the highest tensile strength, Young’s modulus, reduction in fiber bundle diameter, weight change, and decrease in contact angle compared to those of untreated fiber bundles. The tensile properties of the fiber bundle exhibited a tendency to decrease with increasing fiber bundle diameter. Increasing the soaking duration from 1 to 2 h did not result in a significant decrease in the fiber bundle diameter or an increase in tensile strength. However, a further increase in the soaking duration from 2 to 3 h resulted in a considerable decrease in the fiber bundle diameter and an increase in the tensile strength.

Selected Properties of Particleboard Made from Sugar Palm (Arenga pinnata) Dregs

Faza AISYADEA,Greitta Kusuma Dewi,Ragil Widyorini 한국목재공학회 2023 목재공학 Vol.51 No.5

Dregs from the sugar palm (Arenga pinnata) starch industry are considered a waste product of the agricultural industry and have not yet been optimally utilized. Therefore, this study aimed to manufacture particleboards from dregs using different amounts of adhesive and particle size ratios. Sugar palm dregs, which had been separated into fibers and powder/fine particles, were used as raw material for making particleboards. The fiber had an average length of 6.84 ± 3.23 cm, while the fine particles were of a size that passed through size 10 mesh and remained in size 60 mesh. Three ratios of fiber to fine particles (100:0, 75:25, and 50:50 wt%) with three different amounts of sucrose-citric acid adhesive (10, 15, and 20 wt%) were used in this study. Increasing the amount of fine particles and the resin content can improve the physical properties and the internal bond strength of boards made from sugar palm dregs. The fine particles possibly filled the gap between the fibers in the particleboard, while the fibers exhibited a high bending strength. As a result, a high-performance particleboard can be attained by combining the composition ratio of fiber/fine particles and resin content. In this study, particleboards made from fiber/fine particles (75:25 wt%) and adhesive content of 15 wt% and 20 wt% had the mechanical properties that met the requirements of Japanese Industrial Standard (JIS) A 5908 type 18. Sugar palm dregs have the potential to be used as raw materials to create value-added particleboards.