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      • KCI등재

        Properties of a New Adhesive Composed of Gambir-Sucrose

        ( Tito Sucipto ),( Ragil Widyorini ),( Tibertius Agus Prayitno ),( Ganis Lukmandaru ) 한국목재공학회 2020 목재공학 Vol.48 No.3

        Gambir is a non-wood forest product with a potential of being used as wood adhesive, due to about 33% catechin in it. Meanwhile, catechins and sucrose have not been studied as adhesives. Therefore, basic characteristics of gambir-sucrose adhesives were investigated. In this research, adhesives were prepared by dissolving gambir and sucrose in distilled water, at different blending ratios of the gambir/sucrose such as 100/0, 75/25, 50/50, and 25/75 wt%. Furthermore, gas chromatography-mass spectrometry (GC-MS) was employed to determine the gambir chemical compositions, and Fourier transform-infrared (FTIR) spectroscopy was carried out to identify chemical bonds. Particleboards with a target density of 0.8 g/cm3 were then manufactured by hot-pressing for 10 min at 200℃. The internal bond (IB) strength of particleboard was subsequently measured. Based on the GC-MS analysis, 31.11% of catechin was identified. In addition, the viscosity, density, solid content, and gelation time of the adhesives, and insoluble matter content (IMC) in boiling water were 7.30~33.24 mPa.s, 1.2~1.3 g/cm3, 25.56~28.44%, 73~420 min, and 29.75~62.10%, respectively. Adding sucrose to the adhesive was observed to raise the IMC from 49.05 to 62.10%, at 180℃ and 200℃. FT-IR analysis showed that the gambir absorption peaks occurred at approximately 1620 cm-1, assigned to the C=O stretching of 5-hydroxymethylfurfural, which tended to increase with the addition of sucrose. The reaction between gambir and sucrose was observed in the form of the dimethylene ether bridge. The 25/75 wt% gambir-sucrose adhesives and 200℃ hot-pressed temperature resulted in the highest IB strength (0.89 MPa), and met the requirement of JIS A5908-2003 type 18. Consequently, the gambir-sucrose adhesive could be used as a particleboard adhesive.

      • SCOPUSKCI등재

        Dynamic Modulus of Three-Layer Boards with Different Furnish and Shelling Ratio

        Muhammad Navis Rofii,Tibertius Agus Prayitno,Shigehiko Suzuki 한국목재공학회 2016 목재공학 Vol.44 No.2

        This aims of this study were to investigate the relationship between non-destructive evaluation (NDE) and actual bending properties of particleboard, and to predict the bending properties of three-layer particleboard. Three kinds of raw materials, i.e. Hinoki (Chamaecyparis obtusa Endl.) strand, knife-milled Douglas-fir (Pseudotsuga manziesii (Mirb) Franco), and hammer-milled matoa (Pometia spp.) obtained from wooden industry, were utilized as furnish for experimental panel with methylene diphenyl diisocyanate (MDI) resin as binder. The NDE test was conducted by hit sounds using an FFT analyzer according to the spectrum peak of wave frequency, while the static bending test was conducted according to JIS A-5908. The results reveal that the dynamic Young’s modulus as an NDE test has a potential for being used to predict the elastic bending of particleboards by a specific equation for adjusting its proper values. The values of NDE and static test are significantly different with a deviation range at 3-20%. The bending stiffness of three-layer particleboards manufactured from different wood species is predictable by observing the bending stiffness of two elements based on the thickness of its layers. The predicted values of bending stiffness and static test are significantly different with a deviation range at 5-24%.

      • SCOPUSKCI등재

        Bonding Performance of Maltodextrin and Citric Acid for Particleboard Made From Nipa Fronds<sup>1</sup>

        Mahdi Santoso,Ragil Widyorini,Tibertius Agus Prayitno,Joko Sulistyo 한국목재공학회 2017 목재공학 Vol.45 No.4

        Maltodextrin and citric acid are two types of natural materials with the potential as an eco-friendly binder. Maltodextrin is a natural substance rich in hydroxyl groups and can form hydrogen bonds with lignoselulosic material, while citric acid is a polycarboxylic acid which can form an ester bond with a hydroxyl group at lignoselulosic material. The combination of maltodextrin and citric acid as a natural binder materials supposed to be increase the ester bonds formed within the particleboard. This research determined to investigate the bond-ing properties of a new adhesive composed of maltodextrin/citric acid for nipa frond particleboard. Maltodextrin and citric acid were dissolved in distillated water at the ratios of 100/0, 87.5/12.5, 75/25 and 0/100, and the concentration of the solution was adjusted to 50% for maltodextrin and 60% citric acid (wt%). This adhesive solution was sprayed onto the particles at 20% resin content based on the weight of oven dried particles. Particleboards with a size of 25 × 25 × 1 cm, a target density 800 kg/m<sup>3</sup> were prepared by hot-pressing at press temperatures of 180℃ or 200℃, a press time of 10 minute and board pressure 3.6 MPa. Physical and mechanical properties of particleboard were tested by a standard method (JIS A 5908). The results showed that added citric acid level in maltodextrin/citric acid composition and hot-pressing temperature had affected to the properties of particleboard. The optimum properties of the board were achieved at a pressing temperature of 180℃ and the addition of only 20% citric acid. The results also indicated that the peak intensity of C=O group increased and OH group decreased with the addition of citric acid and an increase in the pressing temperature, suggesting an interreaction between the hydroxyl groups from the lignocellulosic materials and carboxyl groups from citric acid to form the ester groups.

      • KCI등재

        Properties of Citric Acid-bonded Composite Board from Elephant Dung Fibers

        ( Ragil Widyorini ),( Greitta Kusuma Dewi ),( Widyanto Dwi Nugroho ),( Tibertius Agus Prayitno ),( Agus Sudibyo Jati ),( Muhammad Nanang Tejolaksono ) 한국목재공학회 2018 목재공학 Vol.46 No.2

        An elephant digests only around 30~45% of what it consumes; therefore the undigested material mainly passes as intact fibres. Elephant food is usually composed of grass, leaves, twigs, bark, fruit and seed pods. This research aimed to utilize the elephant dung fibers as material for composite board and citric acid as a bonding agent. Citric acid contents in this research were set at 0 wt% (binderless composite board), 10 wt%, 20 wt%, and 30 wt% based on dry weight particles, while the target density was set at 0.8 g/cm<sup>3</sup>. Pressing temperatures were set at 180℃ and 200℃ with the pressing time was 10 minutes. Physical and mechanical properties tests were then performed according to Japanese Industrial Standard A 5905. The result showed that elephant dung fibers could be used as potential materials for composite board. Addition of citric acid and pressing temperature significantly increased the quality of composite board. Infrared analysis indicated that the presence of ester linkages much higher with the increasing of citric acid content and pressing temperature. The optimum properties of composite board made from elephant dung fibers could be achieved at pressing temperature of 200℃ and a citric acid content of 20 wt%.

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