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Mondal, S.,Lin, C. C.,Chen, W. P.,Zhang, Z.-W.,Alcock, C.,Axelrod, T.,Bianco, F. B.,Byun, Y.-I.,Coehlo, N. K.,Cook, K. H.,Dave, R.,Kim, D.-W.,King, S.-K.,Lee, T.,Lehner, M. J.,Lin, H.-C.,Marshall, S. American Institute of Physics 2010 The Astronomical journal Vol.139 No.5
<P>The Taiwanese-American Occultation Survey (TAOS) project has collected more than a billion photometric measurements since 2005 January. These sky survey data—covering timescales from a fraction of a second to a few hundred days—are a useful source to study stellar variability. A total of 167 star fields, mostly along the ecliptic plane, have been selected for photometric monitoring with the TAOS telescopes. This paper presents our initial analysis of a search for periodic variable stars from the time-series TAOS data on one particular TAOS field, No. 151 (R.A. = 17<SUP>h</SUP>30<SUP>m</SUP>6<img entity='fs' SRC='http://ej.iop.org/icons/Entities/fs.gif' ALT='fs' ALIGN='BASELINE' />7, decl. = 27°17'30'', J2000), which had been observed over 47 epochs in 2005. A total of 81 candidate variables are identified in the 3 deg<SUP>2</SUP> field, with magnitudes in the range 8 < R < 16. On the basis of the periodicity and shape of the light curves, 29 variables, 15 of which were previously unknown, are classified as RR Lyrae, Cepheid, δ Scuti, SX Phonencis, semi-regular, and eclipsing binaries.</P>
Improving the Gumbel analysis by using M-th highest extremes
Cook, Nicholas J. Techno-Press 1998 Wind and Structures, An International Journal (WAS Vol.1 No.1
Improvements to the Gumbel method of extreme value analysis of wind data made over the last two decades are reviewed and illustrated using sample data for Jersey. A new procedure for extending the Gumbel method to include M-th highest annual extremes is shown to be less effective than the standard method, but leads to a method for calibrating peak-over-threshold methods against the standard Gumbel approach. Peak-over-threshold methods that include at least the 3rd highest annual extremes, specifically the modified Jensen and Franck method and the "Method of independent storms" are shown to give the best estimates of extremes from observations.
Biomedical and Biochemical Applications of Self-Assembled Metallacycles and Metallacages
Cook, Timothy R.,Vajpayee, Vaishali,Lee, Min Hyung,Stang, Peter J.,Chi, Ki-Whan American Chemical Society 2013 Accounts of chemical research Vol.46 No.11
<P>Metal ions and metal complexes with organic molecules are ubiquitous in nature. Bulk metal ions of Na, K, Mg, and Ca constitute as much as 1% of human body weight. The remaining trace ions, most commonly of Fe, Ni, Cu, Mn, Zn, Co, Mo, and V, make up ∼0.01% by weight, but their importance in biological processes cannot be overstated.</P><P>Although nature is limited to the use of bioavailable metal ions, many rarer transition metals can elicit novel biological responses when they interact with biomolecules. For this reason, metal–biomolecule complexes are of interest in medicinal applications. A well-known example is cisplatin, which contains Pt, rare in nature, but highly effective in this context as an anticancer drug in the form of cis-Pt(NH<SUB>3</SUB>)<SUB>2</SUB>Cl<SUB>2</SUB> and analogous Pt(II) complexes. This and other examples have led to strong interest in discovering new metalloanticancer drugs.</P><P>In this Account, we describe recent developments in this area, particularly, using coordination-driven self-assembly to form tunable supramolecular coordination complexes (SCCs) with biomedical applications. Coordination-driven self-assembly describes the spontaneous formation of metal–ligand bonds in solution, transforming molecular building blocks into single, 2D metallacycles, or 3D metallacages depending on the directionality of the precursors used. Such SCCs have well-defined internal cavities and simple pre- or post-self-assembly functionalizations. They are highly tunable both spatially and electronically.</P><P>Metal ions are necessary structural elements for the directional bonding approach, which can be exploited to provide biological activity to an SCC, particularly for Pt- and Ru-based structures. Since these two metals are not only among the most commonly used for coordination-driven self-assembly but are also the basis for a number of small molecule anticancer agents, researchers have evaluated a growing number of SCCs for their antitumor properties.</P><P>The biological application of SCCs is still an emergent field of study, but the examples discussed in this Account confirm that supramolecular scaffolds have relevance to a wide variety of biochemical and biomedical targets. SCCs can serve as anticancer agents, act as selective sensors for biologically important analytes, or interact with DNA and proteins. The myriad of possible SCCs and their almost limitless modularity and tunability without significant synthetic penalty suggests that the biological applications of such species will continue along this already promising path.</P><P><B>Graphic Abstract</B> <IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/achre4/2013/achre4.2013.46.issue-11/ar400010v/production/images/medium/ar-2013-00010v_0016.gif'></P>
A photophysical study of PCBM thin films
Cook, S.,Ohkita, H.,Kim, Y.,Benson-Smith, J.J.,Bradley, D.D.C.,Durrant, J.R. North Holland ; Elsevier Science Ltd 2007 Chemical physics letters Vol.445 No.4
Jablonski diagram comparing the energy of the intramolecular and the more delocalised charge transfer states in thin films of PCBM.