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        Precipitating tunable-emission CsPb(Cl/Br)3 QDs in boro-germanate glass for wide-color-gamut liquid crystal displays

        Xiaoliang Pang,Xuejie Zhang,Bingfu Lei,Haoran Zhang 한국정보디스플레이학회 2019 Journal of information display Vol.20 No.4

        Embedding CsPbX3 (X = Cl, Br, I) perovskites QDs in inorganic glass matrix via in-situ crystallization has been regarded as a feasible strategy to improve their stability against water, heat, and light irradiation. However, the tunable-emission range of these CsPbX3-nanocrystals-embedded glasses is still narrow, insufficient to cover a wide color gamut. Herein, a simple synthetic method was developed in this study to obtain the tunable-emission CsPb(Cl/Br)3 quantum dots (QDs) in boro-germanate glass (CsPb(Cl/Br)3 QDs@glass) by controlling the molar ratio of PbBr2/PbCl2. With the increase of the PbBr2 concentration from 1.6 to 3.2 mol%, the emission wavelength of CsPb(Cl/Br)3 QDs@glasses can be shifted from 448 to 485 nm, and the corresponding photoluminescence quantum yield (PLQY) increases from 0.61 to 24.43%. In addition, the CsPb(Cl/Br)3 QDs@glass exhibits impressing promotion of thermal stability, photostability, and water resistance due to the excellent protective function of the glass matrix. As a proof-of-concept experiment, a LED device was fabricated by employing the optimal CsPb(Cl/Br)3 QDs@glass with a commercial 375nmUVchip, yielding an intense cyan light. All the results indicate that the investigated CsPb(Cl/Br)3 QDs@glasses may find promising applications as color convertors in wide-color-gamut liquid crystal displays (LCDs).

      • KCI등재

        Effect of supplemental blue light intensity on the growth and quality of Chinese kale

        Yamin Li,Yinjian Zheng,Houcheng Liu,Yiting Zhang,Yanwei Hao,Shiwei Song,Bingfu Lei 한국원예학회 2019 Horticulture, Environment, and Biotechnology Vol.60 No.1

        The infl uence of blue light on the growth and quality of vegetables is controversial, since both positive and negative eff ectshave been observed on diff erent varieties of vegetables and most research has been conducted with a combination of lightspectrums. In this work, we investigated the eff ects of supplemental blue light intensity on growth, nutritional quality, andhealth-promoting compounds of Chinese kale ( Brassica alboglabra Bailey) using only blue (460 nm) light-emitting diodes10 days before harvest in a greenhouse under ambient light conditions. Four blue-light treatments were conducted (0, 50,100, and 150 μmol m −2 s −1 , named T0, T50, T100, and T150, respectively) with 12 h (6:00–18:00) of light treatment perday. The growth of Chinese kale plants was improved by supplemental blue light. The fresh and dry weights of Chinesekale plants were signifi cantly higher under T50 and T100 than those in the other treatments. The content of chlorophyll band total chlorophyll increased signifi cantly under T50, and the content of carotenoids increased signifi cantly under T150. The contents of soluble sugars and free amino acids were signifi cantly increased under the blue light treatments. The nitratecontent decreased with increasing blue light intensity, while the anthocyanin content increased. The contents of vitamin Cin T50 and total phenolic compounds in T150 were signifi cantly higher than in T0. The fl avonoid contents were signifi canthigher in T50 and T150, and signifi cantly lower in T100. Our results show that blue light can infl uence the growth and qualityof Chinese kale and 50 μmol m −2 s −1 of supplemental blue light might be the most feasible light intensity for Chinesekale production.

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        Toward efficient broad-spectrum UV absorption of carbon dots: Facile preparation, performance characterization and its application as UV absorbers

        Jiemin Qiu,Weihao Ye,Congcong Chen,Zhiqiang Xu,Chaofan Hu,Jianle Zhuang,Hanwu Dong,Bingfu Lei,Guangqi Hu,Yingliang Liu 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.117 No.-

        UV absorbers are sustainable substances that inhibit the ultraviolet (UV) radiative degradation of polymers. In previous reports, the as-prepared carbon dots (CDs) possess only an absorption band at UVA(320–400 nm). To achieve broad-spectrum UV absorption (200–400 nm), increasing the concentrationof the CDs solution becomes common. However, a high concentration solution seriously affects the lighttransmittance due to its heavy yellow color. Furthermore, the promising organic UV absorbers cannotachieve broad-spectrum UV absorption. In this work, we initially synthesized three-component watersolublecarbon dots (OP–CDs), which delivers an excellent UV absorption (98 % UVA and 100 % UVB atthe concentration of 1.7 102 mg/mL; 99 % transmittance in visible light). Moreover, OP–CDs exhibitoutstanding stability at high temperatures and different pH. With the corporation of OP–CDs and polyvinylalcohol (PVA), a high-performance UV-shielding film was formed, leading to enhanced broadspectrumUV shielding performance and improved mechanical properties, resistance of photocatalyticactivity and anti-UV aging ability compared with pure PVA film. Notably, the PVA film remains hightransparency with the addition of OP–CDs. The study suggests that the corporation of OP–CDs and polymersis effective in anti-UV degradation.

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