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RISS 인기검색어
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- 저자 : Arif Ullah Khan (검색결과 3 건)
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Fathi Etaher Elbakoush,Qudrat Ullah Khan,Mati Ullah,Arif Ullah,Afaq Ullah Khan,Javed Khan,Asra Iftikhar 한국전기전자재료학회 2021 Transactions on Electrical and Electronic Material Vol.22 No.6
The carbonization performance of the iron-containing carbon film resulting from polyimide was examined, Polyimide/Fe composite films were prepared from Iron (III) 2,4-pentanedionate (Fe(acac)) and poly(amic acid) (PAA) based on ODA and PMDA via a solution process in DMAC, followed by carbonization the polyimide film at a temperature range of 600–1600 °C. The organized polyimide/Fe combined fi lms were characterized using a scanning electron microscope (SEM), and thermogravimetric analysis (TGA), X-ray diffraction (XRD), and Raman. The formation of Fe particles and the synthesis of polyimide (PMDA/ODA) in the polyimide matrix is confirmed by FTIR results. Meantime, in the polyimide matrix, Fe particles were well spread which were showed by the SEM images. Kinetic parameters and thermal stability of the degradation methods for the organized polyimide/Fe combined films were examined in N 2 environment by TGA. The results have shown that the values of the calculated activation energies and thermal stability increased of the (Fe (acac)) the activation energy and loading also different with the weight-loss rate for all compositions.
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Ionic liquids based fluorination of organic compounds using electrochemical method
Zia Ul Haq Khan,Yongmei Chen,Dondan Kong,Nawshad Muhammad,Arif Ullah Khan,Faheem Ullah Khan,Kamran Tahir,Aftab Ahmad,Lei Wang,Pingyu Wan 한국공업화학회 2015 Journal of Industrial and Engineering Chemistry Vol.31 No.-
Ionic liquids due to their advantageous properties gain importance in many fields. This study aims tooverview the use of ionic liquids in the selective partial fluorination of organic compounds throughelectrochemical method. In addition to ionic liquid based fluorination, the earlier approaches offluorination through an electrochemical process have also been highlighted. The factors such aselectrode materials (Pt, Ni, and C), types of solvents (CH3CN, DMC, THF, DME, Sulfone, etc.) and type ofelectrolytes (Et3N 3HF, Et3NF 3HF, py HF, etc.) which affect the electrochemical fluorination of organiccompounds have been reviewed. For electrode preparation, the carbon, platinum and nickel wereconsidered suitable materials to be used as an electrode. In CH3CN media, Et3N 3HF and Et4NF 3HFshowed better efficiency during fluorination of organic compounds. Solvent play an important role inelectrochemical fluorination of organic compounds, with the change of solvent the percentage yield ishighly affected. Py-HF is a convenient solvent-supporting electrolyte medium with a reasonably goodconductivity. The electrolyte containing solvents have some side effects on electrochemical fluorinationof organic compounds as observed in cyclic voltammetric analysis. Therefore electrochemicalfluorination to organic compounds without the use of solvent gained more importance. The ionicliquids have been reported for its dual properties, as solvent as well as a fluorinating agent for organiccompounds in electrochemical processes. It has been concluded that solvents free electrochemicalfluorination of organic compounds gives good results as compare to solvent based. Ionic liquids due tomore oxidative stability were noted to have considerable effect on the yield and selectivity of organiccompound fluorination.
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Laser Polarization Effects on the Photodetachment Cross Section of H− Near a Reflecting Surface
Suneela Arif,Muhammad Haneef,Jehan Akbar,Saleh Mohammad,Imran Ullah,Hameed Khan,Nasrullah Shah,Muhammad Zahir,Abdur Rab 한국물리학회 2012 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.61 No.5
The influence of laser polarization angle on the photodetachment of H<sup>−</sup> near a reflecting surface is investigated based on a theoretical imaging technique. An analytical expression for the photodetachment cross section is derived. The photodetachment cross section of H<sup>−</sup> near a reflecting surface is found to be not only related to the inter-ion-surface distance and the photon energy but also the laser polarization angle <i>θ<sub>L</sub></i>. A strong oscillating structure is noted for <i>θ<sub>L</sub></i> = 0°. As the angle continues to increase, the oscillating structure diminishes, and for <i>θ<sub>L</sub></i> = 90°, the oscillating structure in the cross section reduces to a non-oscillating structure.
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