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      • SCOPUSKCI등재

        아세톤 - 물계의 과잉열역학적 성질에 관하여

        김기창,임진남 한국화학공학회 1977 Korean Chemical Engineering Research(HWAHAK KONGHA Vol.15 No.1

        아세톤-물계에 대하여 15,25,35 및 45℃에서 몰분율에 따른 混合熱을 측정하였다. 측정된 混合熱 데이타로부터 NRTL式을 사용하여 아세톤-물 분자간의 interaction energy을 계산하였고 interaction energy가 混合熱에 미치는 영향을 검토하였다. 한편 混合熱 실험치로부터 ΔG^E와 ΔS^E을 계산하였으며 계산된 ΔG^E로부터 등온기액평형치를 얻었다. 이를 문헌치와 비교한 결과 좋은 일치를 얻었다. Heats of mixing were measured for the acetone-water system at 15, 25, 35 and 45℃, respectively. Interaction energies between the water and acetone molecules were calculated by the NRTL equation, and the effects of the interaction energy on heats of mixing were discussed. The excess Gibbis free energy and the excess entropy were calculatd from the experimental data for the heat of mixing and isothermal vapor-liquid equilibria were predicted from the calculated values of excess Gibbs free energy. The results turned out to be in good agreement with literature values.

      • KCI등재후보

        북한이탈주민의 지역사회적응 경험에 관한 연구: 여성을 중심으로

        김기창 한국사회복지질적연구학회 2015 한국사회복지질적연구 Vol.9 No.1

        This study conducted an in-depth interview against 10 female North Korean defectors in Korea with a goal of offering suggestions to their adaptation process and support policies through analysis on their adaptations to a local community. The study results found the followings: First, most North Korean defectors are psychologically shaky after escaping from North Korea. Second, their ultimate goal was to arrive at the Republic of Korea with an unfocused expectation that Korean government would take care of them, not targeting self-sufficiency. Third, it turned out that life goal and motivation would be the critical factors to cover their post-traumatic stress syndrome and embodiment. Fourth, in terms of psychological aspects and adaptation to family life, the experience of adapting themselves to all variables such as psychological, social, cultural, economic, institutional and policy family lives had an effect on their self-sufficiency. Lastly, a success model for female North Korean defectors started with a selection of spouse, which reveals a direction for their self-sufficiency. Based on these results, this study suggested policy and support plans on North Korean defectors. 본 연구는 북한이탈주민의 지역사회 적응 경험 분석을 통해, 적응과정 및 지원 정책에 시사점을 제시하고자 국내 거주 북한이탈주민 여성 10명을 대상으로 심층 인터뷰를 실시하였다. 본 연구결과를 요약하면 다음과 같다. 첫째, 탈북과정에서 상당한 심리적 위축 경험을 갖고 있는 것으로 나타났다. 둘째, 이들의 탈북에 대한 동기부여가 대한민국에 도착하는 것까지이며 그 다음 삶에 대한 목표가 자립이 아닌 대한민국이 알아서 해주기를 바라는 막연한 기대 때문인 것으로 나타났다. 셋째, 입국 즉후부터 삶에 대한 목표 및 동기 부여가 초기 외상 후 스트레스 증후군이나 신체화현상 등의 기대를 채울 수 있는 중요한 요인으로 나타났다. 넷째, 심리적 측면과 가족생활의 적응경험에서 심리적, 사회적, 문화적, 경제적, 제도적 및 정책적 가족생활 등의 모든 변수의 적응경험이 자립에 영향을 미쳤다. 마지막으로 북한이탈주민 여성의 성공모델이 가족에서 배우자 선택이 제시되었다는 것은 자립방향의 방향성을 제시하고 있다. 이러한 연구결과를 토대로 북한이탈주민에 대한 정책 및 지원방안을 제언하였다.

      • 격자유체이론을 이용한 초임계유체내에서의 상평형

        김기창 江原大學校 産業技術硏究所 1991 産業技術硏究 Vol.11 No.-

        The lattice-fluid theory are adopted modeling the phese equilibria in supercritical fluids, In order ot investigate effects of the nonrandom distribution of holes in mixtures on the phase equilibria, the equation of state and the chemical potential of the bunary miture are formnulated with taking into account nonrandomness of holes distributions in the fluid mixture. The relations of phase equilibria formultated in this work are tested through predictions of solubility of heavy solids in supercritical fluids and predictions of high pressure phase equilibria of binary mixtures. Results obtained exhibit that the lattice fluid model with assumptions of nonrandomness of hole distributions is successful in quantatively mideling the phase equilibria of mixtures of molecules of dissimilar of dissimilar sizes, specifically solidssupercritical fluid mixtures.

      • KCI등재

        물권행위무용론

        김기창 한국민사법학회 2010 民事法學 Vol.52 No.-

        Transactions such as sale or gift have traditionally been regarded as a ‘causa’ which would lead to transfer of title if the thing was delivered or registration of title was done on the basis of such a causa. Friedrich Savigny, however, altered this traditional view by dividing the causa into two categories: ‘contract which gives rise to obligations (to transfer title)’ and ‘contract which has immediate effect of transferring title’. He then proposed that only the latter (real contract; Dingliches Vertrag) must be viewed as causa of title transfer. Korean commentators largely accept this theory and the notion of real contract has been central to an explanation of title transfer. This paper examines whether the concept of real contract indeed provides a satisfactory tool of analysis. Spontaneous gift done without any obligation to give has often been explained to contain a real contract which is deemed to be concluded between the donor and the recipient at the moment the object of gift is delivered. However, this paper discusses circumstances where the title passes even in the absence of an agreement between the donor and the recipient of a gift. As it is possible that a title passes even in the absence of a real contract, the usefulness of the notion of real contract is hard to explain. Where the grounds for passing the title of movables or immovable are fully satisfied (ie., balance has been fully paid, due date has arrived or the defence of simultaneous performance was waived or not available, etc.),there is no need for any further ‘agreement’ to pass the title at the moment of delivery or title registration. Even if the delivery was done against the wishes of the transferor through enforcement proceedings or even if the title registration was completed using forged/stolen documents or fraudulent means, the title passes validly as long as the delivery (in the case of movables) or the title registration (in the case of immovable) was done. If the delivery was done in a stealthy or violent manner, then recovery of possession only (rather than the title) may be at issue (possessory interdict). On the other hand, if the grounds for passing the title of immovable have not (yet) been satisfied, Korean court does not distinguish whether the title registration was done through forged/stolen documents or documents secured by fraudulent means or handed over by mistake. The registration is treated as null and void (rather than voidable). If the notion of ‘real contract’ is to be invoked in connection with registration of title, one would have to conclude that title registration which was done by fraudulent means or documents handed over by mistake should nevertheless be valid but voidable only. This, however, is not the position adopted by Korean courts. Whether the conveyancing was done as performance of an obligation to convey or done as spontaneous gift, the notion of ‘real contract’ is either inadequate or comes into conflict with Korean courts’ position. A more satisfactory approach would be to examine (i) whether the grounds for passing the title have been satisfied and (ii) whether the delivery/title registration was done. There is no need to envisage ‘real contract’ as distinct from the ‘intent’with which the underlying transactions (sale, gift, etc.) are carried out. Nor is it tenable to conceive ‘real agreement’ as distinct from the mental aspect (‘animus’) which is required in obtaining possession. If ‘real contract’ is invoked with regard to delivery (change of possession), then one would inevitably have to conclude that where the ‘real contract’ was vitiated by mistake or f raud, the t ransferor who parted with the possession i s entitled t o rescind the ‘real contract’ and claim the thing back (because the passing of the title is retroactively voided). Such a conclusion would be wholly incompatible with the possessory interdictal proceedings.

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