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Synthesis of furan compounds from HMF and fructose catalyzed by aluminum-exchanged K-10 clay
Bing Liu,Zizhen Gou,Anqiu Liu,Zehui Zhang 한국공업화학회 2015 Journal of Industrial and Engineering Chemistry Vol.21 No.1
K-10 clay-Al was found to be effective for the synthesis of 5-ethoxymethylfurfural (EMF) from 5-hydroxymethylfurfural (HMF) with a yield of 89.5%. Further synthesis of EMF from the one-potconversion of fructose in ethanol was failed, but ethyl fructoside was produced. When the conversion offructose was carried out in DMSO, HMF was obtained in a high yield of 93.2%.