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        One-step synthesis of Pt-Pd catalyst nanoparticles supported on few-layer graphene for methanol oxidation

        Hongxia Wang,Leimei Sheng,Xinluo Zhaoa,Kang An,Zhongmin Ou,Yanghao Fang 한국물리학회 2018 Current Applied Physics Vol.18 No.8

        In this study, Pt-Pd nanoparticles (NPs) supported on few-layer graphene (FLG) have been firstly prepared by one-step arc discharge evaporation of carbon electrodes containing both Pt and Pd elements. The few-layer graphene and Pt-Pd nanoparticles were achieved simultaneously through the evaporation process. After a hightemperature hydrogen treatment, the Pt-Pd/graphene was applied in the study of methanol oxidation in direct methanol fuel cell. The total weight of electrocatalyst keeps 2 wt% of the electrode. The sample with a mass ratio of Pt:Pd=3:1 (H-Pt3Pd1/G) exhibits better electrocatalytic activity (198 mA mg-1 pt) and better tolerance to carbon monoxide(CO) poisoning (If/Ib=1.26). It is noteworthy that the value of If/Ib can reach to 1.55 for the sample with the mass ratio of Pt:Pd=2:1 (H-Pt2Pd1/G),which implies its excellent ability of CO tolerance. The introduction of Pd element may open a new strategy to improve the CO tolerance by arc discharge evaporation.

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