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        Adsorption, Kinetic and Regeneration Studies of n-Hexane on MIL-101(Cr)/AC

        Wenpu Zhao,Wei-Qiu Huang,Manlin Li,Zhoulan Huang 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2019 NANO Vol.14 No.8

        MIL-101(Cr)/AC was synthesized by in situ incorporation of activated carbon powder via hydrothermal method. The water stability, n-hexane adsorption and regeneration of the MIL-101(Cr)/AC were experimentally measured. The results showed that the MIL-101(Cr)/AC exhibited the larger surface area (3319.3 m2/g) than that of MIL-101(Cr) and AC, respectively. The addition of activated carbon was beneficial to improve the yield of MIL-101(Cr)/AC. The pore structure parameter and XRD of the MIL-101(Cr)/AC changed little after in water for 24 h. Furthermore, the adsorption capacity of MIL-101(Cr)/AC for n-hexane was 786 mg/g, which increased to 23.0% and 27.7% compared with MIL-101(Cr) and AC, respectively. Kinetic fitting of data indicated that the pseudo-first order model can more accurately describe the adsorption process of n-hexane on MIL-101(Cr)/AC and the intraparticle diffusion was not the sole rate-controlling step. Besides, the regeneration efficiency of MIL-101(Cr)/AC was over 92% after 10 consecutive n-hexane adsorption/desorption cycles.

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        Fabrication of Hierarchical N-doped Carbon Nanotubes for CO2 Adsorption

        Hongning Wang,Chao Xu,Yongsheng Zhou,Wenpu Zhao,Jing Zhong,Wei-Qiu Huang,Ruo-Yu Chen 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2019 NANO Vol.14 No.6

        Hierarchical N-doped carbon nanotubes (NCTs) with controllable aspect ratios were developed for CO2 adsorption. In this work, NCTs were synthesized by coating different amounts of 3-aminophenol/formaldehyde resin (APF) on the outer layer of silica nanotubes, carbonizing in N2 at 700 ℃ and removing the silica and Ni template by hydrofluoric acid etching. The obtained NCTs were activated by K2CO3. After activation, micropores on the activated N-doped carbon nanotubes (ANCTs) were enriched, the micro-surface area and pore volume of ANCT-1.0 reached 1195 m2 g-1 and 0.45 cm3 g-1, respectively, and the corresponding adsorption capacity increased by 50% (4.50 mmol g -1 at 0 ℃ and 1 bar). Moreover, ANCT-1.0 maintained a high stability throughout consecutive adsorption–desorption cycles. The advantages of hierarchical N-doped carbon nanotubes, including their meso–microporous structures, high geometric aspect ratio and good stability, make them valuable and promising materials to capture carbon dioxide.

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