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        Reinforcement of Waterborne Polyurethane Films with Poly(acrylic acid)-Modified Palygorskite Fibers

        Yu Mao,Lingli Ni,Changyou Yang,Peng Cai,Weigang Du,Xiaoyan Gao 한국섬유공학회 2020 Fibers and polymers Vol.21 No.9

        Palygorskite (PAL) is a natural fibrous clay mineral which attracted tremendous attention as reinforcing agent topolymers. In this paper, a facile and environmental friendly modification process of PAL by poly acrylic acid (PAA) via insitupolymerization in PAL/water gel has been reported. The effects of PAA modified PAL (PAA-PAL) on the mechanical andthermal properties of waterborne polyurethane (WPU) nanocomposites have been investigated. Scanning electronmicroscopy (SEM) demonstrated that the dispersion of PAL has improved dramatically after PAA modification. Tensile testsshowed that PAA-PAL has a significant reinforcement effect on WPU matrix. Addition of 10 wt% PAA-PAL, the tensilestrength and the Young’s modulus of WPU composites increased 235 % and 388 %, respectively. Furthermore, the thermalstability of WPU also has been distinctly improved via addition of PAA-PAL.

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