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1
Mimicking synaptic plasticity and learning behaviours in solution processed SnO2 memristor

Pan, Ying,Wan, Tao,Du, Haiwei,Qu, Bo,Wang, Danyang,Ha, Tae-Jun,Chu, Dewei Elsevier 2018 JOURNAL OF ALLOYS AND COMPOUNDS Vol.757 No.-
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Abstract In this study, a transparent memristor with a configuration of Au/SnO2/FTO is fabricated by a simple solution process at low temperature and further utilized to mimic biological synapses. A series of significant synaptic functions, including nonlinear transmission characteristics, spike-rate-dependent plasticity (SRDP), short-term plasticity (STP) and long-term plasticity (LTP) are emulated. The transition from short-term to long-term plasticity is also investigated in the device by repeated stimulation. The nonlinear rectification characteristic in the current memristor is attributed to the Schottky barrier at the Au/SnO2 interface. By controlling the oxygen vacancy migration induced under electrical input, the barrier at the interface can be modified, giving rise to the different synaptic functions. These results suggest that the proposed Au/SnO2/FTO memristor in this study is a promising synaptic device for artificial neural network applications. Highlights <UL> <LI> Synaptic electronic based on Au/SnO2/FTO memristor was fabricated through a simple solution process at low temperature. </LI> <LI> Synaptic plasticity including SRDP, STP, LTP and STP-to-LTP transition were demonstrated in the synaptic device. </LI> <LI> Different synaptic functions were realised by controlling oxygen vacancy migration induced by electrical input. </LI> </UL> Graphical abstract [DISPLAY OMISSION]
2
Oxidative degradation of Rhodamine B solution with nZVI persulfate activation

Yong-Tao Li,Xin-Yue Liu,Xi Li,Hao Liu,Wan-Ying Du,Jing-Lin Chen 대한환경공학회 2024 Environmental Engineering Research Vol.29 No.4
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In this study, the researchers evaluated the use of nano-zero-valent iron (nZVI) activated persulfate (PS) for the degradation of Rhodamine B (RhB). The effects of various operating parameters such as initial pH, and dosages of PS, nZVI and citric acid (CA) on the removal rate of RhB were investigated. The results demonstrated that at a PS dosage of 5 mmol·L-1, nZVI dosage of 0.3 g·L-1, 0.1 mmol·L-1 CA, and pH of 5, the degradation rate of RhB was 94.970%. The degradation and kinetic analysis of RhB using micron-scale zero-valent iron (mZVI) and nZVI revealed that nZVI exhibited higher activity with PS due to its smaller particle size. The activation of PS by nZVI is higher compared to mZVI, and the ineffective consumption is half that of the mZVI/PS system, the TOC removal rate increased by 18.65%. Kinetic analysis indicated that under the mentioned reaction conditions, the degradation process followed a pseudo-second-order reaction model, with the highest apparent reaction rate constant (kobs). The researchers also identified active radical species in the nZVI/PS system. Additionally, Gas Chromatography-Mass Spectrometry (GC-MS) analysis was used to detect reaction intermediates and propose a possible degradation pathway for RhB.