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A self-complexing and self-assembling pillar[5]arene
Strutt, Nathan L.,Zhang, Huacheng,Giesener, Marc A.,Lei, Juying,Stoddart, J. Fraser The Royal Society of Chemistry 2012 Chemical communications Vol.48 No.11
<P>A monofunctionalised pillar[5]arene derivative carrying a viologen side chain which exhibits self-complexation in dilute dichloromethane solutions forms supramolecular daisy chain polymers and eventually organogels as its concentration is increased three-fold over the range from 0.1 to 100 mM.</P> <P>Graphic Abstract</P><P>A viologen-functionalized pillar[5]arene exhibits self-complexation in dilute solutions and forms supramolecular daisy chain polymers and organogels at high concentrations. <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c2cc16030g'> </P>
Dynamic clicked surfaces based on functionalised pillar[5]arene
Zhang, Huacheng,Strutt, Nathan L.,Stoll, Ragnar S.,Li, Hao,Zhu, Zhixue,Stoddart, J. Fraser Royal Society of Chemistry 2011 Chemical communications Vol.47 No.41
<P>A dynamic smart surface which was constructed by the self-assembly of an azobenzene-functionalised pillar[5]arene exhibits reversibly responsive morphologies towards UV and visible light as observed by TEM, SEM and AFM.</P> <P>Graphic Abstract</P><P>Pillar[5]arene monofunctionalized with azobenzene was used to prepare a photoresponsive surface which can switch between vesicles and solid particles. <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c1cc14934b'> </P>
The Chameleonic Nature of Diazaperopyrenium Recognition Processes
Basuray, Ashish N.,Jacquot ,de ,Rouville, Henri‐,Pierre,Hartlieb, Karel J.,Kikuchi, Takashi,Strutt, Nathan L.,Bruns, Carson J.,Ambrogio, Michael W.,Avestro, Alyssa‐,Jennifer,Sc WILEY‐VCH Verlag 2012 Angewandte Chemie Vol.124 No.47
<P><B>Zwei zum Preis von einem</B>: Das Diazaperopyrenium‐Dikation verhält sich sowohl homo‐ als auch heterophil, indem es mit seinesgleichen sowie mit vielfältigen π‐elektronenreichen Donoren Komplexe bildet. In Kombination mit den elektronischen Eigenschaften führt dieses dichotome Verhalten zur Bildung selbstorganisierter Nanodrähte im Festkörper sowie zu einer Templatwirkung bei der Bildung eines [3]‐ und zweier [2]Rotaxane mit aromatischen Kronenethern (siehe Bild).</P>