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RISS 인기검색어
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- 저자 : S.A.A. Hosseinzadeh (검색결과 3 건)
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Pourjavadi A.,Amini-Fazi M. S.,Hosseinzadeh H. The Polymer Society of Korea 2005 Macromolecular Research Vol.13 No.1
In this study, a series of highly swelling hydrogels based on sodium alginate (NaAlg) and polymethacrylamide (PMAM) was prepared through free radical polymerization. The graft copolymerization reaction was performed in a homogeneous medium and in the presence of ammonium persulfate (APS) as an initiator and N,N'-methylenebisacrylamide (MBA) as a crosslinker. The crosslinked graft copolymer, alginate-graft-polymethacrylamide (Alg-gPMAM), was then partially hydrolyzed by NaOH solution to yield a hydrogel, hydrolyzed alginate-graft-polymethacrylamide (H-Alg-g-PMAM). During alkaline hydrolysis, the carboxamide groups of Alg-g-PMAM were converted into hydrophilic carboxylate anions. Either the Alg-g-PMAM or the H-Alg-g-PMAM was characterized by FTIR spectroscopy. The effects of the grafting variables (i.e., concentration of MBA, MAM, and APS) and the alkaline hydrolysis conditions (i.e., NaOH concentration, hydrolysis time, and temperature) were optimized systematically to achieve a hydrogel having the maximum swelling capacity. Measurements of the absorbency in various aqueous salt solutions indicated that the swelling capacity decreased upon increasing the ionic strength of the swelling medium. This behavior could be attributed to a charge screening effect for monovalent cations, as well as ionic cross-linking for multivalent cations. Because of the high swelling capacity in salt solutions, however, the hydrogels might be considered as anti-salt superabsorbents. The swelling behavior of the superabsorbing hydrogels was also measured in solutions having values of pH ranging from 1 to 13. Furthermore, the pH reversibility and on/off switching behavior, measured at pH 2.0 and 8.0, suggested that the synthesized hydrogels were excellent candidates for the controlled delivery of bioactive agents. Finally, we performed preliminary investigations of the swelling kinetics of the synthesized hydrogels at various particle sizes.
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Behavior of FRP-reinforced steel plate shear walls with various reinforcement designs
Mehdi Seddighi,Mohammad A. Barkhordari,S.A.A. Hosseinzadeh 국제구조공학회 2019 Steel and Composite Structures, An International J Vol.33 No.5
The nonlinear behavior of single- and multi-story steel plate shear walls (SPSWs) strengthened with three different patterns of fiber reinforced polymer (FRP) laminates (including single-strip, multi-strip and fully FRP-strengthened models) is studied using the finite element analysis. In the research, the effects of orientation, width, thickness and type (glass or carbon) of FRP sheets as well as the system aspect ratio and height are investigated. Results show that, despite an increase in the system strength using FRP sheets, ductility of reinforced SPSWs is decreased due to the delay in the initiation of yielding in the infill wall, while their initial stiffness does not change significantly. The content/type/reinforcement pattern of FRPs does affect the nonlinear behavior characteristics and also the mode and pattern of failure. In the case of multi-strip and fully FRP-strengthened models, the use of FPR sheets almost along the direction of the infill wall tension fields can maximize the effectiveness of reinforcement. In the case of single-strip pattern, the effectiveness of reinforcement is decreased for larger aspect ratios. Moreover, a relatively simplified and approximate theoretical procedure for estimating the strength of SPSWs reinforced with different patterns of FRP laminates is presented and compared with the analytical results.
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