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        Effect of Ce Addition on the Tribological Behavior of ZK60 Mg-Alloy

        S. M. Banijamali,Y. Palizdar,S. Najafi,A. Sheikhani,M. Soltan Ali Nezhad,P. Valizadeh Moghaddam,H. Torkamani 대한금속·재료학회 2021 METALS AND MATERIALS International Vol.27 No.8

        The present work aims to study the tribological behavior of an extruded ZK60 alloy in the presence of Ce; in a previous study, among ZK60 alloys with diferent Ce addition rates, an alloy with 3 wt% of Ce was found to exhibit the mostpromising mechanical (e.g., hardness and strengths) properties, while its wear behavior remained unknown. The results ofmicrostructural examinations by optical and electron microscopes show that Ce addition reduces the grain size from 6.1 to2.0 μm. Besides, in addition to the precipitates already distributed in the base alloy (Mg7Zn3), Ce could promote the formation of a new precipitate (MgZn2Ce), increasing the total fraction of the precipitates. These microstructural evolutionsenhance the strengths of the studied ZK60 alloy, as the yield and tensile strengths increase from 212 to 308 MPa and from297 to 354 MPa, respectively. A pin on disc tribometer was employed to study the wear behavior of the developed alloyunder diferent normal loads (5, 20, 40, and 60 N). The results show that the base and Ce-added alloys exhibit almost asimilar frictional behavior, while the wear resistance of the Ce-added alloy is higher within the load ranges applied: (i) inlow load conditions (5 and 20 N), where the abrasive wear is the active mechanism, the precipitates in the Ce-added alloycould enhance the wear resistance. (ii) Under the load of 40 N, oxidative wear is also an operative wear mechanism, leadingto a sharp increase in the wear rate of the alloys. In this condition, Ce could provide a protective oxide layer, which couldimprove the wear resistance of the alloy. (iii) At a load of 60 N, both studied alloys exhibit a similar wear rate due to a severeoxidation condition. Therefore, beyond this loading condition, the microstructural evolutions (e.g., change in precipitationbehavior) caused by Ce addition can no longer contribute to the enhancement of wear resistance.

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