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- 저자 : P. W. Khirade (검색결과 5 건)
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Kamble, Siddharth P.,Sudake, Y.S.,Patil, S.S.,Khirade, P.W.,Mehrotra, S.C. Korean Chemical Society 2011 대한화학회지 Vol.55 No.3
The present paper reports the study of binary mixtures and their properties over the entire range of composition at temperatures 288, 298, 308 and 318 K. Excess dielectric constant, excess molar volume, excess refractive index, molar refraction and excess molar refraction at different temperatures have been computed from the experimentally measured values of the aforesaid parameters and fitted to the Redlich-Kister equation. Excess dielectric constant, excess molar volume excess molar polarizations are negative whereas excess refractive indices are positive over entire mole fraction of methyl acetate for all temperatures. The results are discussed in light of intermolecular interactions occurring in the binary mixture. Estimated coefficients of the Redlich-Kister polynomials and the standard error along the coefficients are also reported. 본 논문은288, 298, 308, 318 K에서 구성 요소의 전체 영역에서 이성분 혼합물과 그 특징을 발표하였다. 각각의 다른 온도에서 초과유전상수, 초과 몰 부피, 초과 굴절률, 몰 굴절, 초과 몰 굴절은 실험적으로 측정된 이전의 파라미터 값으로부터 계산되었고 Redlich-Kister 식으로 확인했다. 초과 유전상수, 초과 몰 부피, 초과 몰 편광은 음수인 반면에 초과 굴절률은 모든 온도에 대해 메틸 아세테이드의 전체 몰 분율에서 양수이다. 본 결과는 이성분 혼합물에서 발생하는 분자 사이의 상호작용을 고려하여 논의 되었다. Redlich-Kister 다항식의 예측된 계수와 계수에 따른 표준오차 또한 보고되었다.
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Undre, P.B.,Khirade, P.W.,Rajenimbalkar, V.S.,Helambe, S.N.,Mehrotra, S.C. Korean Chemical Society 2012 대한화학회지 Vol.56 No.4
Using time domain reflectometry, the complex dielectric spectra between 10 MHz to 20 GHz has been measured in the whole composition range at 10, 20, 30 and $40^{\circ}C$ for the binary mixtures of ethylene glycol and dimethyl sulfoxide. For all the mixtures, only one dielectric loss peak was observed in this frequency range. The relaxation in these mixtures can be described by a single relaxation time using the Debye model. A systematic variation is observed in dielectric constant (${\varepsilon}_0$) and relaxation time (${\tau}$). The excess permittivity (${\varepsilon}^E$), excess inverse relaxation time $(1/{\tau})^E$, Kirkwood correlation factor (g) and thermodynamic parameters viz. enthalpy of activation (${\Delta}H$) and Gibbs free energy of activation (${\Delta}G$) have been determined, to confirm the formation of hydrogen bonded homogeneous and heterogeneous cooperative domains, the dynamics of solute - solute interaction and the hindrance to molecular rotation in the hydrogen bonded glass forming ethylene glycol - dimethyl sulphoxide system.
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Study of Dynamics of Allyl Chloride-2-Butanone Binary System Using Time Domain Reflectometry
Sudake, Y.S.,Kamble, S.P.,Patil, S.S.,Khirade, P.W.,Mehrotra, S.C. Korean Chemical Society 2012 대한화학회지 Vol.56 No.1
Complex permittivity spectra of Allyl Chloride (AC), 2-Butanone (2-BU) and their binary mixtures over the entire range of concentration were obtained using the Time Domain Reflectometry (TDR) technique in microwave frequency range at various temperatures. Static dielectric constant and relaxation time are obtained from complex permittivity spectra. Density ($\rho$) and refractive index ($n_D$) are also measured. These parameters are used to determine excess dielectric constant, excess inverse relaxation time, excess molar volume, excess molar refraction, polarity, Bruggeman factor and thermodynamic parameters viz. enthalpy of activation and entropy of activation. The values of static dielectric constant and relaxation time increases while density and refractive index decreases with the percentage of 2-Butanone in Allyl Chloride increases. Excess parameters were fitted to a Redlich-Kister equation.
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Dielectric Study of Methyl Acrylate-Alcohol Mixtures Using Time Domain Reflectometry
K. Dharmalingam*,K. Ramachandran,P. Sivagurunathan,B. Prabhakar Undre,P. W. Khirade,S. C. Mehrotra 대한화학회 2006 Bulletin of the Korean Chemical Society Vol.27 No.12
Dielectric studies of methyl acrylate with 1-propanol, 1-butanol, 1-heptanol and 1-octanol binary mixtures have been carried out over the frequency range from 10 MHz to 10 GHz at temperatures of 283, 293, 303 and 313 K using Time Domain Reflectometry (TDR) for various concentrations. The Kirkwood correlation factor and excess inverse relaxation time were determined and discussed to yield information on the molecular structure and dynamics of the mixture. The values of the static dielectric constant, relaxation time and the Kirkwood correlation factor decrease with increased concentration of methyl acrylate in alcohol. The Bruggman plot shows a non-linearity of the curves for all the systems studied indicates the heterointeraction which may be due to hydrogen bonding of the OH group of alcohol with C=O of the methyl acrylate. The excess inverse relaxation time values are negative for all the systems at all the temperatures indicates that the solute-solvent interaction hinders the rotation of the dipoles of the system.
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Dielectric Study of Methyl Acrylate-Alcohol Mixtures Using Time Domain Reflectometry
Dharmalingam, K.,Ramachandran, K.,Sivagurunathan, P.,Prabhakar , B.,Khirade, P.W.,Mehrotra, S.C. Korean Chemical Society 2006 Bulletin of the Korean Chemical Society Vol.27 No.12
Dielectric studies of methyl acrylate with 1-propanol, 1-butanol, 1-heptanol and 1-octanol binary mixtures have been carried out over the frequency range from 10 MHz to 10 GHz at temperatures of 283, 293, 303 and 313 K using Time Domain Reflectometry (TDR) for various concentrations. The Kirkwood correlation factor and excess inverse relaxation time were determined and discussed to yield information on the molecular structure and dynamics of the mixture. The values of the static dielectric constant, relaxation time and the Kirkwood correlation factor decrease with increased concentration of methyl acrylate in alcohol. The Bruggman plot shows a non-linearity of the curves for all the systems studied indicates the heterointeraction which may be due to hydrogen bonding of the OH group of alcohol with C=O of the methyl acrylate. The excess inverse relaxation time values are negative for all the systems at all the temperatures indicates that the solute-solvent interaction hinders the rotation of the dipoles of the system.
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