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Bull, Mathew M.,Chung, Woo Jin,Anderson, Sarah R.,Kim, Su-jeong,Shim, In-Bo,Paik, Hyun-jong,Pyun, Jeffrey Royal Society of Chemistry 2010 Journal of materials chemistry Vol.20 No.29
<P>The synthesis of ferromagnetic cobalt nanoparticles with polymeric ligands with tunable particle size is reported on multi-gram scales. End-functional polystyrene ligands were prepared <I>via</I> atom transfer radical polymerization. Mechanistic studies on this system were conducted as well as direct comparisons of polymer <I>vs.</I> small molecule ligand effects on nanoparticle formation.</P> <P>Graphic Abstract</P><P>The manuscript describes a facile method to prepare ferromagnetic cobalt nanoparticles with unprecedented control of particle size over a range of 18 to 43 nm in multi-gram quantities per batch. <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c0jm01042a'> </P>