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Photo-crosslinking of polyethylene by mono- and diacetophenone derivatives and their precursors
Lukac, Ivan,Kosa, Csaba,Weiss, Richard G. Korean Society of Photoscience 2009 Photochemical & photobiological sciences Vol.8 No.10
The efficiency of photochemical crosslinking of low-density polyethylene (PE) films by molecules containing one or two acetophenone groups and their precursors have been correlated with the relative rates of carbonyl group depletion under equivalent irradiation conditions. The acetophenone derivatives are found to be equally or more efficient than benzophenone as crosslinkers of PE. Because some additives are not thermodynamically equilibrated in the PE matrices and crystallize on standing at $30^{\circ}C$, doped films were irradiated usually as soon as possible after their preparation. However, others were aged to determine the influence of equilibration on the efficiency of crosslinking. Thus, the effect of crystallization of some of the crosslinker additives in the PE matrices and the competition between photochemical addition of the carbonyl groups to C-H or C=C bonds of the polymer were investigated. GC-MS and FTIR analyses of photoproducts from irradiation of alkanophenones bearing a $\gamma$-hydrogen atom in PE films showed that (intramolecular) Norrish Type II splitting and Yang cyclization processes proceed efficiently, and are more rapid than subsequent intermolecular hydrogen abstraction reactions by the acetophenone photoproducts.
BENEFITS AND CHALLENGES OF CONTROLLING A LED AFS (ADAPTIVE FRONT-LIGHTING SYSTEM) USING FUZZY LOGIC
L. LUKACS,M. DASSANAYAKE,R. MAGALHAES,C. FONTES,M. EMBIRUCU,I. M. PEPE 한국자동차공학회 2011 International journal of automotive technology Vol.12 No.4
The vehicular illumination system has undergone considerable technological advances in recent decades such as the use of a Light Emitting Diode (LED) Adaptive Front-lighting System (AFS), which represents an industry breakthrough in lighting technology and is rapidly becoming one of the most important innovative technologies around the world in the lighting community. This paper presents AFS control alternatives using fuzzy logic (types 1 and 2) to determine its operating parameters taking into consideration the road conditions in the state of São Paulo (Brazil). Fuzzy logic is a well-known extension of the conventional (Boolean) logic that enables the treatment of uncertainty present in the information through the definition of intermediary membership values between the “completely true” and the “completely false”. This technique or modeling strategy is particularly important when a multi-parameter decision must be taken or the decisions are based on the human knowledge. The results show the potential of the methodology proposed and its suitability for light control providing safer nighttime driving.