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      • KCI등재

        Variability in Tropical Cyclone Climatology over North Indian Ocean during the Period 1891 to 2015

        Kasturi Singh,Jagabandhu Panda,Monalisa Sahoo,M. Mohapatra 한국기상학회 2019 Asia-Pacific Journal of Atmospheric Sciences Vol.55 No.2

        Tropical cyclone (TC) prediction and impact of warming environment on cyclonic activity are one of the most popular research topics. Based on sea surface temperature (SST) anomaly variation, the period 1880–2015 is divided into pre-warming (PWP; during 1880–1946) and current warming (CWP; during 1947–2015) with negative and positive anomalies respectively. Based on data availability, the period 1891–2015 is emphasized for the analysis of variability in TC climatology. The Mann-Kendall test and Sen’s slope estimation indicates a clear decreasing trend in annual TS (total storms) and CS + SCS (cyclones and severe cyclones) frequency during CWP for NIO region and particularly Bay of Bengal (BOB) at 95% confidence level. However, the TS and CS + SCS frequencies were increasing during the PWP. TC activity over southern and northern BOB is decreasing sharply during CWP. Southern sector of BOB hosts mostly severe systems and middle sector most TCs. TC activity over the eastern sector of Arabian Sea shows considerable enhancement duringCWP. An increasing SST, surface wind, mid-tropospheric relative humidity and potential evaporation factor (PEF) are helpful in the formation of intensified storms during CWP. The activities during PWP were reverse compared to that of CWP. A large temperature anomaly difference between atmosphere and Ocean also perceived to play a key role in modulating the enhanced intensity of TCs during CWP. The SST range of 27.5 °C to 29.5 °C and supportive flow field is helping to enhance the middle and upper tropospheric moisture content; eventually, resulting in increased SST, PEF and relative humidity through a possible feedback mechanism.

      • KCI등재

        A novel Sm3+-activated Li3BaSrLn3(MO4)8 [Ln = La, Gd, and Y; M = Mo andW] deep red-emitting phosphors for plant cultivation and white LEDs

        Marikumar Rajendran,Kasturi Singh,Sivakumar Vaidyanathan 한국정보디스플레이학회 2021 Journal of information display Vol.22 No.2

        Deep red phosphor-based LEDs play a crucial role in plant growth applications, where the LED emission covers the phytochrome (Pr) absorption. In this context, a series of Sm3+-activated Li3BaSrLn3(MO4)8:Sm3+ [Ln = La Gd and Y; M = Mo and W] deep red phosphors were synthesized using the solid-state method. The outcome of the PXRD patterns suggests that the synthesized phosphors were crystallized in a monoclinic structure with the space group C2/c. SEM analysis was executed to study the morphology of the phosphors, and an FT-IR study was performed to study the stretching frequency of the MO/W-O bond in the (Mo/W)O4 groups. All the Sm3+-activated phosphors showed intense emission at 646 nm due to their 4G5/2→6H9/2 transition and exhibited excellent thermal stability (> 72% at 423K). The selected phosphors showed internal quantum efficiency at around 30%. The pc-LEDs were fabricated with the combination of near-UV LED and the synthesized deep-red phosphors. Besides, the emission spectrum of the fabricated LED was compared with the phytochrome Pr absorption spectrum for de plant growth application. These results suggest that the synthesized phosphor can be useful in the white LED fabrication to improve the CRI and can also be beneficial in the plant growth field.

      • KCI등재

        New europium complexes and their use in red light-emitting diodes and vapoluminescent sensors

        Devi Rachna,Boddula Rajamouli,Singh Kasturi,Kumar Satendra,Vaidyanathan Sivakumar 한국정보디스플레이학회 2021 Journal of information display Vol.22 No.3

        Three novel trivalent europium [Eu(III)] complexes – Eu(DBM)3Phen-Ph-Ph, Eu(DBM)3Phen-mCF3-Ph, and Eu(DBM)3Phen-pCF3-Ph – were designed, synthesized, and characterized using various spectroscopic methods. Then their photophysical characteristics were investigated. The Eu complexes in the solid phase showed a pure red emission (due to the electric dipole transitions of the Eu3+ ion). In a solution, they had multiple emissions due to their ligand contribution. The solvatochromism studies revealed that the Eu(III) complexes in the methanol and DMSO solutions had both metal ion and ligand emissions with similar intensities, which yielded a white emission. Of all the Eu(III) complexes, Eu(DBM)3Phen-mCF3-Ph showed the best quantum yield. In addition, the fluorinated mCF3 ligand had an unusually high lifetime value. Its remarkable linear decrease in luminescence intensity with increasing temperature opens a new window for its use as a sensitive temperature sensor at the 30–80°C range. The CIE color coordinates of the fabricated red LEDs (InGaN) are very close to the standard NTSC CIE color coordinates for bright red emissions, and the color purity as well as the LER values of the fabricated red LEDs are also very good. The Eu(III) complexes exhibited on-off photoluminescence switching via the vapoluminescent process and responded best to the acid-base (HCl-NH3) vapors. All these features suggest that the synthesized Eu(III) complexes are efficient candidates for red-emitting LEDs and vapoluminescent sensors. Organic chromophores, which are phenanthro-imidazole ligands based on fluorinated moieties coordinated with Eu(III) metal ions, very efficiently facilitate energy transfer from the ligand to the Eu(III) ion. The CIE color coordinates of the complexes showed a bright pure red emission, with x = 0.66 and y = 0.33 (612 nm). The fabricated light-emitting diode (LED) showed superior color quality and the complexes showed on-off-on luminescence behavior after exposure to the acid-base vapors.

      • SCOPUSKCI등재

        Multi-objective optimization for biomass and lipid production by oleaginous bacteria using vegetable waste as feedstock

        Suryakanta Patnaik,Sarveshwaran Saravanabhupathy,Sangeeta Singh,Achlesh Daverey,Kasturi Dutta 대한환경공학회 2022 Environmental Engineering Research Vol.27 No.3

        In this study, pretreated organic wastes such as waste paper cups, cardboard waste, and vegetable waste were screened for the growth and lipid production of oleaginous bacteria DS-7 (isolated from the dairy effluent scum). The pretreated vegetable waste was found to be the best feedstock for biomass and lipid production by the DS-7. Further, process parameters such as inoculation time, substrate concentration (w/v) (amount of pretreated vegetable waste), pH, and inoculum size were optimized using a multi-objective optimization technique to enhance the biomass and lipid productions. The optimization study successfully enhanced the biomass concentration (g/L) and lipid content (%) by 47.9% and 15.84%, respectively in comparison with the unoptimized state. The biomass and lipid productivities were 42% (1.449 g/L/d) and 51% (1.267 g/L/d) greater than unoptimized conditions. The characteristics of the biodiesel obtained from the valorization of vegetable waste were comparable to the standard. Thus, the vegetable waste can be utilized as a potential feedstock for microbial biodiesel production.

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