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      저자 : Jiasheng Fang (검색결과 2 건)
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        Effect of Different Nanofillers on Non-Isothermal Crystallization Kinetics and Electric Conductivity of Dynamically-Vulcanized PP-EPDM Blends

        Bin Yang,Lei Hu,Ru Xia,Fang Chen,Shu-Chun Zhao,Yan-Li Deng,Ming Cao,Jiasheng Qian,Peng Chen 한국고분자학회 2016 Macromolecular Research Vol.24 No.1

        In this study, nanofillers composed of hydroxylated carbon nanotubes (h-CNT), carbon nanotubes (CNT) and graphene (GR) were separately added into the dynamically-vulcanized polypropylene (PP)/ethylene-propylenediene monomer (EPDM) blend. Differential scanning calorimetry (DSC), wide-angle X-ray diffraction (WAXD) and electrical resistivity measurements were employed to study the effect of nanofillers on the melt behavior, non-isothermal crystallization behavior and electrical conductivity of the prepared composites. WAXD results showed that h-CNT had a better induction effect of β-PP in the nanocomposites. The sequence of the activity in inducing the formation of β-PP was h-CNT>GR>CNT. However, the total crystallinity of the nanocomposites nearly remained constant. Non-isothermal crystallization kinetic analysis indicated that the presence of nanofillers improved the crystallization rate of the nanocomposites. The consequence of nucleation activity was as follows: CNT>GR>h-CNT. Although EPDM hindered the macromolecular motion of PP, interestingly it could increase the crystallization rate to an extent. Besides, the influence of nanofillers on enhancing the conductive property of the nanocomposites can be ranked as follow: CNT>GR>h-CNT.

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        In situ fabrication dynamic carbon fabrics membrane with tunable wettability for selective oil–water separation

        Xuejie Yue,Tao Zhang,Dongya Yang,Fengxian Qiu,Yao zhu,Jiasheng Fang 한국공업화학회 2018 Journal of Industrial and Engineering Chemistry Vol.61 No.-

        Achieving reversible wetting properties of separation membrane for on-demand separate oil/water mixture remains challenging, especially for the oil/water mixtures with complex impurities. Herein, hierarchical porous dynamic separation membranes involving primary fiber membrane and secondary nanostructures are fabricated by in situ growth ZnO nanowires on the surface of carbon fibers. Based on the effect of oxygen-related defects of ZnO nanowires coating, the as-fabricated dynamic separation membrane is capable of switching wetting property between high-hydrophobicity and superhydrophilicity via simply annealing alternatively under vacuum and air environment, achieving the switching between oil-removing mode and water-removing mode according to the type of oil/water mixtures. Moreover, the dynamic separation membrane can be extended to separate the oil/water mixtures containing suspended solids using the reconstruction of ZnO dynamic coating. Through removing the ZnO dynamic coating via soaking the clogged membrane in the hydrochloric acid–ethanol and refabricating the ZnO-dynamic coating, the membrane blocked by impurities could be readily re-formed, which effectively expand its scope of application and enhance its anti-fouling property. This work not only provides a simple and on-demand solution for pure oily wastewater, but also extends the separation membrane to separate oil/water mixtures containing suspended solids.

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