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Aimin Zhang,Guoqun Zhao,Jialong Chai,Junji Hou,Chunxia Yang,Guilong Wang 한국섬유공학회 2020 Fibers and polymers Vol.21 No.12
The crystalline behavior and mechanical properties of PP/GF (glass fibers) composites molded by rapid heat cyclemolding (RHCM) and conventional injection molding (CIM) were compared. SEM, DSC and XRD were utilized to studycrystallization behavior of PP and PP/GF composites. Furthermore, universal testing machine was employed to investigatethe mechanical properties. Results proved that higher degree of crystallinity and larger crystal size can be obtained in RHCMin comparison to CIM. GF can induce more crystal nuclei and then reduce the crystal size due to shear stress which isgenerated in polymer matrix around fibers. Nucleating agent (NA) has a positive effect on refine grains. The average crystaldiameter of PP/NA/30 %GF is about 1.7 μm which is one-tenth of PP/30 %GF (14 μm) in RHCM. XRD tests illustrated thatα-form crystal is the main crystal type for PP and PP/GF composites in RHCM and CIM. However, there is a little β-formcrystal in RHCM for PP/GF composites without NA. NA accelerates the formation of α-form crystal and restrains theemergence of β-form crystal. The plastic parts obtained in RHCM exhibited higher strength and modulus compared with thatobtained in CIM for both tensile and flexural tests.