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- 저자 : Haosheng Mi (검색결과 1 건)
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Meng Zhang,Lili Liu,Jianan Li,Rui Zhan,Zhiping Wang,Haosheng Mi,Yunxiao Zhang 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.127 No.-
The catalytic mechanism of CoFe2O4 nanoparticles (NPs) was investigated in the system of electrochemicalenhanced heterogeneous activation of peroxymonosulfate (EC/CoFe2O4/PMS) with moxifloxacin(MOX) as target contaminant. The removal efficiencies of MOX in PMS, CoFe2O4, EC, CoFe2O4/PMS, andEC/CoFe2O4/PMS system were 18.3%, 36.1%, 43.7%, 96.9%, and 98.3%, respectively. Although there wasno synergy effect between EC and heterogeneous catalytic oxidation reaction (HCOR) on MOX removal,the value of apparent rate constant (karc) was much higher in EC/CoFe2O4/PMS system (0.24 min1) comparedwith CoFe2O4/PMS system (0.13 min1). Therefore, EC not only kept the structure of CoFe2O4 NPsstable, but also significantly accelerated the reaction rate of HCOR. Meanwhile, according to electrochemicalimpedance spectra of catalysts synthesized based on ion-substitution strategy and the EC-HCORexperimental results, the decisive role of „Co in PMS activation and the electron transfer between„Co and „Fe were confirmed. The TOC removal efficiency was reached 74.4% as the ratio of PMS toCoFe2O4 NPs being 0.8 mM to 50 mg/L (30 min), and further improved to 87.6% with batch addition(0.25 mM per 30 min) of PMS (120 min, CoFe2O4 = 100 mg/L). The research results could improve theunderstanding of catalytic mechanism of spinel oxide in electrochemical system.
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