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Lijun Tang,Raju Nandhakumar,Gongfan Wei,Zhilong Guo 대한화학회 2011 Bulletin of the Korean Chemical Society Vol.32 No.9
An easy and convenient synthetic route to (S)-2-hydroxy-2'-(3-phenyluryl-benzyl)-1,1'-binaphthyl-3-carboxaldehyde (1), capable of recognizing tryptophan by fluorescence has been developed. The binol carboxaldehyde 1 exhibited a high selectivity to L-tryptophan over other examined L-α-amino acids such as alanine,phenylalanine, glutamine, arginine, lysine, serine, threonine, aspartat, valine, histidine and cysteine, with a fluorescence “turn-on” signal. In addition, 1 displayed chiral discrimination with good enantioselectivity toward L-tryptophan over D-tryptophan through different fluorescence enhancement factors.
Lijun Yang,Haijun Guo,Kaiting Huang 대한전기학회 2019 Journal of Electrical Engineering & Technology Vol.14 No.2
Because buildings have certain heat capacity, when the thermal power changes, the indoor temperature has a relative lag of change, while the feeling to comfortable temperature of the human body lies within a certain range. Based on the energy storage characteristics of buildings, this paper structures the optimal dispatch model of a combined cooling, heating, and power system (CCHP) and the virtual energy storage system (VESS) is integrated into the model of optimizing schedule on microgrid. This will achieve the charge and discharge management of microgrid virtual energy storage system, with the optimization objectives of minimizing the economic, environmental and energy indexes through determining the weight coeffi cient of each index by analytic hierarchy process (AHP) and through the adjustment of the indoor temperature of the building within the range of human comfort. Finally, taking the summer refrigeration scenario as an example and comparing two microgrids of two types of buildings with or without virtual energy storage, this paper concludes that compared with traditional optimization dispatching methods, the combined cooling, heating, and power optimization dispatching method adopting virtual energy storage fully excavates the potential of the buildings’ virtual storage and every aspect has been improved in terms of economy, environment and energy.
Lijun Tang,Jiaojiao Guo,Zhenlong Huang 대한화학회 2013 Bulletin of the Korean Chemical Society Vol.34 No.4
A known Hg2+ selective rhodamine B derivatised probe 1 was reinvestigated as a colorimetric and fluorescent probe for Cu2+ through changing the applied solvent media. Probe 1 exhibited good selectivity and sensitivity to Cu2+ in CH3CN-H2O (7:3, v/v, HEPES 10 mM, pH 7.0) solution with a detection limit of 9.74 × 10−7 M. The Cu2+ sensing event was proved to be irreversible through hydrolysis of 1 to release rhodamine B.
Tang, Lijun,Guo, Jiaojiao,Wang, Nannan Korean Chemical Society 2013 Bulletin of the Korean Chemical Society Vol.34 No.1
A new Rhodamine B hydrazide hydrazone 1 has been synthesized and investigated as a colorimetric and fluorescent "off-on" sensor for the recognition of $Cu^{2+}$ in $CH_3CN/H_2O$ (1:1, v/v, HEPES 10 mM, pH = 7.0) solution. Sensor 1 displayed highly selective, sensitive and rapid recognition behavior toward $Cu^{2+}$ among a range of biologically and environmentally important metal ions. Sensor 1 bind $Cu^{2+}$ via a 1:1 stoichiometry with an association constant of $1.92{\times}10^6\;M^{-1}$, and the detection limit is evaluated to be $7.96{\times}10^{-8}\;M$. The $Cu^{2+}$ recognition event is reversible and is barely interfered by other coexisting metal ions.
Colorimetric and Fluorescent Recognition of Fluoride by a Binaphthol Thioureido Derivative
Tang, Lijun,Wang, Nannan,Guo, Jiaojiao Korean Chemical Society 2012 Bulletin of the Korean Chemical Society Vol.33 No.7
A new thiourea based receptor (1) was synthesized and applied to fluoride ion recognition in acetonitrile solution. Receptor 1 displayed dual changes in absorption and fluorescence emission intensities selectively for fluoride ions. The interaction of 1 with fluoride undergoes a deprotonation process that is confirmed by $^1H$ NMR titration.
Tang, Lijun,Wei, Gongfan,Nandhakumar, Raju,Guo, Zhilong Korean Chemical Society 2011 Bulletin of the Korean Chemical Society Vol.32 No.9
An easy and convenient synthetic route to (S)-2-hydroxy-2'-(3-phenyluryl-benzyl)-1,1'-binaphthyl-3-carboxaldehyde (1), capable of recognizing tryptophan by fluorescence has been developed. The binol carboxaldehyde 1 exhibited a high selectivity to L-tryptophan over other examined L-${\alpha}$-amino acids such as alanine, phenylalanine, glutamine, arginine, lysine, serine, threonine, aspartat, valine, histidine and cysteine, with a fluorescence "turn-on" signal. In addition, 1 displayed chiral discrimination with good enantioselectivity toward L-tryptophan over D-tryptophan through different fluorescence enhancement factors.
Tang, Lijun,Guo, Jiaojiao,Huang, Zhenlong Korean Chemical Society 2013 Bulletin of the Korean Chemical Society Vol.34 No.4
A known $Hg^{2+}$ selective rhodamine B derivatised probe 1 was reinvestigated as a colorimetric and fluorescent probe for $Cu^{2+}$ through changing the applied solvent media. Probe 1 exhibited good selectivity and sensitivity to $Cu^{2+}$ in $CH_3CN-H_2O$ (7:3, v/v, HEPES 10 mM, pH 7.0) solution with a detection limit of $9.74{\times}10^{-7}$ M. The $Cu^{2+}$ sensing event was proved to be irreversible through hydrolysis of 1 to release rhodamine B.
Study on the Excited Energy Transfer in Light-harvesting Complex (LH2) of Rhodobacter sphaeroides
Liu, Yuan,Guo, Lijun,Qian, Shixiong,Xu, Chunhe Korean Society of Photoscience 2002 Journal of Photosciences Vol.9 No.2
A green mutant of Rhodobacter sphaeroides 60I was acquired by chemical induction. The blue-shifted of the carotenoid absorption was found in the Light-harvesting complex II (LH2) of the mutant. With the excitation at different wavelength, we observed that the evolution of excited-state dynamics in LH2 of Rhodobacter sphaeroides 60I. The dynamical traces demonstrate a dominant absorption followed concomitantly by an ultrafast transmission increase and decay with 818nm excitation.