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        Environmentally Friendly Waterproof and Breathable Nanofiber Membranes with Thermal Regulation Performance by One-Step Electrospinning

        Pan Zhang,Gaihuan Ren,Lulu Tian,Bo Li,Zhanzhao Li,Hongqin Yu,Rongwu Wang,Jianxin He 한국섬유공학회 2022 Fibers and polymers Vol.23 No.8

        The waterproof and moisture permeable fabric with thermal regulation not only has the protective function forhuman body, but also meets the comfort of human clothing, which is a challenging and innovative research. Herein, we reportan environmentally friendly, simple, and high-efficiency strategy to fabricate waterproof and breathable nanofibermembranes with outstanding thermal regulation ability by introducing stearic acid (SA) into the hydrophobic siliceouspolyurethane (SIPU) solution by a facile one-step electrospinning. Owing to the addition of SA, the waterproofness of SIPU/SA nanofiber membranes is greatly improved, meanwhile, the addition of SA acted as a phase change material to imparttemperature regulation performance in appropriate temperature range to the SIPU/SA nanofiber membranes. By adjusting theaddition amount of the SA, eco-friendly and multifunctional SIPU/SA nanofiber membranes are systemically optimized withgood waterproofness (79 kPa), moisture breathability (8.0 kg m-2 d-1), and outstanding temperature regulation performance(latent heat up to 40 J/g), satisfied tensile strength (6.2 MPa) and excellent breaking elongation of 182 %. The obtained SIPU/SA nanofiber membranes can be suitable for the design of multifunctional wearable textiles for various applications,especially in outdoor protective clothing, medical clothing, intelligent clothing and military products.

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        Electrospun PS/PAN Nanofiber Membranes Formed from Doped Carbon Nanotubes with a Fluffy and Multi-scale Construction for Air-Filtration Materials

        Weili Shao,Wanli Yue,Gaihuan Ren,Chen Cui,Junpeng Xiong,Ling Wang,Tong Lu,Wanjun Bu,Fan Liu,Jianxin He 한국섬유공학회 2022 Fibers and polymers Vol.23 No.5

        Electrospun nanofibers are widely used in air-filtration materials because of their fine fiber diameter, small poresize, and high porosity. However, nanofiber membranes exhibit a dense structure, such that they present a large resistance toany air flow. In this study, we set out to design and develop composite nanofiber materials with fluffy structures, as well asblended structures of coarse and fine fibers, through electrospinning technology. These materials could be used in airfiltration applications, given that they offer high efficiency and low resistance. The results show that, compared with purePAN nanofibers, the diameter of PAN nanofibers doped with CNT decreased from 192.36 to 124.37 nm; when the spinningratio of PS coarse fiber (1053 nm) and PAN/CNT fine fiber is 3:1, the resulting nanofiber membrane materials has an obviousthree-dimensional structure, with a specific surface area of 103.16 m2/g, a pore size of 2.25 μm, and a quality factor of0.0947 Pa-1. Under test conditions featuring an air flow of 32 L/min, and 0.3 μm NaCl aerosol particles, the filtrationefficiency was 99.37 % and the resistance was 35 Pa. Furthermore, the dust-holding capacity of the nanofiber air-filter paperwas found to be almost the same as that of melt-blown air-filter papers. Even after being water-soaked 50 times, the filteringefficiency of the nanofiber air-filter paper was still higher. Interestingly, the nanofiber membrane materials doped with CNTalso exhibited excellent sound-absorption abilities. Thus, the composite nanofiber material could potentially be applied toareas with serious air pollution and high noise pollution.

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