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- 저자 : Banglei Liang (검색결과 1 건)
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Banglei Liang,Yaqi Zhao,Xinxin Guo,Zhenxin Zhao,Qiao Feng,Jingyi Guo,Xiaoyuan Zhang,Jinyu Tian 한국섬유공학회 2020 Fibers and polymers Vol.21 No.8
An efficient approach was presented to prepare polyaniline/polypyrrole (PANi/PPy) composite nanofibers bygrowing PPy layers on the surface of PANi nanofibrous seeds as electrode materials for supercapacitors in neutral electrolyte. Core layer of PANi nanofiber was firstly synthesized by the chemical oxidative polymerization of aniline monomers underfree melting condition of reaction solutions in fully aqueous system without the assistance of any templates or organicsolvents. Then the shell layer of PPy was fabricated by in-situ chemical oxidative polymerization of pyrrole monomers withthe above-mentioned PANi nanofiber as a seed, and the PPy shell layer thicknesses were tuned by changing the molar ratio ofaniline to pyrrole. The resulting PANi/PPy composites were investigated by field-emission scanning electron microscopy,ultraviolet-visible spectroscopy, Fourier transform infrared and Raman spectrometry. Furthermore, electrochemical behaviorsin Na2SO4 electrolyte were tested by cyclic voltammetry, galvanostatic charge-discharge techniques and electrochemicalimpedance spectroscopy. It turned out that low molar ratio of aniline to pyrrole is helpful to increase the PPy shell layerthicknesses, yield and conductivity of PANi/PPy composite nanofibers. A great improvement on the capacitive propertiescould be achieved by choosing appropriate PPy shell layer thickness. The results showed that benefiting from strong synergyeffect and π-π interaction between PANi core and PPy shell layer as well as low electrochemical impedance, PANi/PPycomposite nanofibers prepared with the molar ratio of 1:1 (PPy shell layer thickness of about 12.5 nm) displayed the highestspecific capacitance of 1550.2 F g-1 at scan rate of 5 mV s-1 and 758.8 F g-1 at the current density of 1 A g-1 with the bestcycling stability of 70.3 % after 500 cycles in 0.5 M Na2SO4 electrolyte, which exhibited a great potential in the developmentof high-performance electrode materials operated in environmentally friendly electrolyte.
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