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KNiFe(CN)<sub>6</sub> 전기화학적 이온교환체를 이용한 세슘 양이온의 분리에 관한 연구
황영기,Hwang, Young Gi 한국전기화학회 2012 한국전기화학회지 Vol.15 No.4
본 연구에서는 전기화학적 이온교환체 중의 하나인 nickel hexacyanoferrate($KNiFe(CN)_6$) 막 전극을 사용하여 세슘 양이온을 분리하는 실험을 수행하였다. 1.0M $NaNO_3$와 1.0M $CsNO_3$의 단일성분계 및 이성분계 수용액에서 순환전위곡선을 측정하여 전극전위, 전류, 전기량의 변화 거동을 조사하였으며, 실험 전과 후에 $KNiFe(CN)_6$ 막의 구조 형태와 원자조성의 변화를 각각 SEM과 EDS 분석을 통하여 조사하였다. 또한 나트륨과 세슘 용액에서 교대로 이온교환 반응을 수행하여 측정한 순환전위곡선과 원자조성으로부터 $KNiFe(CN)_6$의 이온 선택성을 조사하였다. 본 연구의 실험 결과에 의하면, 전기를 인가한 $KNiFe(CN)_6$ 이온교환체는 화학적 유 무기물 이온교환체에 비해 약 40배 이상의 우수한 내구성을 가짐을 알 수 있었다. 또한 $KNiFe(CN)_6$ 이온교환체는 나트륨보다 세슘에 대해 보다 높은 선택도를 가짐을 확인할 수 있었다. This study was performed to investigate the separation of cesium cations by using an electrochemical ion exchanger of nickel hexacyanoferrate($KNiFe(CN)_6$) film electrode. Potential, current, and charge passing through the cyclic voltammograms were measured in singular and binary solutions of 1.0M $NaNO_3$ and 1.0M $CsNO_3$. Before and after each experiment, the structural morphology and atomic composition of $KNiFe(CN)_6$ were analyzed by SEM and EDS, respectively. The ion selectivity of $KNiFe(CN)_6$ was also observed by the voltammograms and atomic compositions measured in the solution alternated between sodium and cesium. As the result of this study, it was found that the electrically switched $KNiFe(CN)_6$ ion exchanger had the significant advantage of 40 times or longer durability than conventional organic or inorganic ion exchanger. It was also shown that the $KNiFe(CN)_6$ ion exchanger had high selectivity for cesium over sodium.
Nickel Hexacyanoferrate 이온교환체의 전기화학적 특성에 관한 연구
황영기(Young-Gi Hwang) 한국산업융합학회 2016 한국산업융합학회 논문집 Vol.19 No.4
For the study on the ion exchange of nickel hexacyanoferrate(NiHCNFe) electrode with the several cations, the film of hexacyanoferrate was prepared on the bare nickel surface by the electrochemical and chemical methods in the solution composed with 5mM K3Fe(CN)6 and 100mM KNO3. To compare the capability of the ion exchange of NiHCNFe film electrode, the repeated cyclic voltammograms were measured in the 0.5M cation nitrate solutions at 25℃ and pH7. It was found that the capacity of the electrochemically derivatized NiHCNFe reduced in the rate of 0.5~0.7%/cycle and was nearly exhausted at the 150th potential cycle. Better result was obtained from that the capacity loss of the chemically assembled NiHCNFe was less than 0.02%/cycle for 5,000cycles. Furthermore, the residual capacity was more than 30% at the 5,000th cycle.
원자력 폐수의 양이온 처리를 위한 전기화학적 이온교환체의 특성
황영기(Young-Gi Hwang) 한국산업융합학회 2016 한국산업융합학회 논문집 Vol.19 No.4
Electrochemical ion exchange method is expected to be one of the most acceptable techniques for the separation of radioactive cations from nuclear wastewater. In this study a thin film of hexacyanoferrate on nickel surface was derivatized chemically in an aqueous potassium-ferricyanide solution. Electrochemical redox behavior of the nickel hexacyanoferrate(NiHCNFe) film electrode was investigated with the use of cyclic voltammetry potentiostated from -100 to 800 mV versus SCE. The electro-reduction characteristics of the NiHCNFe film were examined in the cobalt solutions. The NiHCNFe ion exchanger was more useful at lower concentration, lower temperature, and pH7 of the cobalt solution. The capacity loss of NiHCNFe was 0.018%/cycle that was less than the average loss of 2~3%/cycle of the convective organic exchanger. The 45~55% of the initial cobalt ions was electro-deposited on the NiHCNFe by using continuous recirculating reactor system. As a result, it was found that the electroactive NiHCNFe films showed better performance than the organic resins for the separation of cobalt ion from the aqueous solutions.
단상 계통연계형 인버터의 SRF-PLL 옵셋 오차로 인한 전류 맥동 저감에 관한 연구
황선환(Seon-Hwan Hwang),황영기(Young-Gi Hwang),권순걸(Soon-Kurl Kwon) 한국조명·전기설비학회 2014 조명·전기설비학회논문지 Vol.28 No.11
This paper presents an offset error compensation algorithm for the accurate phase angle of the grid voltage in single-phase grid-connected inverters. The offset error generated from the grid voltage measurement process cause the fundamental harmonic component with grid frequency in the synchronous reference frame phase lock loop (PLL). As a result, the grid angle is distorted and the power quality in power systems is degraded. In addition, the dq-axis currents in the synchronous reference frame and phase current have the dc component, first and second order ripples compared with the grid frequency under the distorted grid angle. In this paper, the effects of the offset and scaling errors are analyzed based on the synchronous reference frame PLL. Particularly, the offset error can be estimated from the integrator output of the synchronous reference frame PLL and compensated by using proportional-integral controller. Moreover, the RMS (Root Mean Square) function is proposed to detect the offset error component. The effectiveness of the proposed algorithm is verified through simulation and experiment results.
연구논문 - 생물공학분과 / 에너지 , 환경분과 / 유지 , 계면활성제분과 : 국내 상업용 알루미늄의 용해속도에 미치는 억제제의 영향
심은기,황영기 ( Eun Gi Shim,Young Gi Hwang ) 한국공업화학회 1997 한국공업화학회 연구논문 초록집 Vol.1990 No.3
N/A Dissolution rate of the domestic commercial aluminium was measured in KOH solution in order to confirm its applicability as an electrode in an aluminium-air cell. This was also performed to control the dissolution rate by means of the addition of ZnO, ZnCO₃, or ZnAc as an inhibitor.
심은기,황영기,전혜수,Shim Eun-Gi,Hwang Young-Gi,Chun Hai-Soo 한국전기화학회 1999 한국전기화학회지 Vol.2 No.3
This study investigated the corrosion rate of aluminum in alkaline solution. It was performed to observe the effects of alloy element, alkalinity (KOH concentration), solution temperature, and inhibitor and its concentration in the solution. Among species of aluminum, AA-1050 showed the lowest corrosion rate due to its high purity $(>199\%)$, whereas alloys containing Mg anuor Mn were highly corroded, relatively. The corrosion rate could be reduced over than $50\%$ by saturating the solution with ZnO, while ZnAc did not work as an inhibitor. The inhibition effect of ZnO increased with increasing the alkalinity and solution temperature. It was found that the corrosion rate linearly increased with the concentration of KOH in first order and exponentially decreased with the inverse of the solution temperature. An analysis of the corroded material covered the surface of aluminum was made by SEM and EDS. According to the analytical results by using XRD, it was confirmed that $Al(OH)_3$ was produced from the corrosion of aluminum in KOH solution. 본 연구에서는 알칼리 용액에서 알루미늄의 부식속도를 측정하면서, 합금원소, 알칼리도(KOH농도),용액온도, 그리고 용액에 첨가하는 부식 억제제의 종류와 그 농도 등이 미치는 영향에 대해 조사하였다. 알루미늄 제품에 따라서는 순도 $99\%$ 이상인 AA-1050의 부식속도가 가장 낮은 반면에 Mg나 Mn이 포함된 합금은 상대적으로 높게 측정되었다. KOH 수용액에 ZnO를 포화농도로 첨가하면 부식속도가 $50\%$ 이상 억제되는 효과가 나타났지만. ZnAc는 부식 억제제로서 역할하지 못하였다. 알칼리도와 용액온도가 높을수록 ZnO의 부식 억제효과는 상승하였다 부식속도는 KOH농도에 대해 1차 선형 증가함수 그리고 온도 역수에 대해 지수형 감소함수로 나타났다. SEM과 EDS를 사용하여 부식 표면에 부착된 물질의 성분을 분석하였으며, XRD의 기기분석을 통하여 KOH 용액에서의 알루미늄의 부식 생성물이 $Al(OH)_3$임을 확인하였다.