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        수소화물에 의한 Zr 합금의 고온산화 가속효과

        정윤목(Yunmock Jung),하성우(Sungwoo Ha),박광헌(Kwangheon Park) 한국표면공학회 2016 한국표면공학회지 Vol.49 No.4

        The operation method of nuclear power plants is currently changing to high burn-up and long period that can enhance economics and efficiency of the plant. Since nuclear plant operation environment has been becoming severe, the amount of absorbed hydrogen also has increased. Absorbed hydrogen can be fatal securing safety of nuclear fuel cladding in case of Loss of Coolant Accidents(LOCA). In order to examine the impact of hydride on high-temperature oxidation, high-temperature oxidation experiment was performed on normal Zry-4 cladding and on Zry-4 cladding where hydrogen is charged in air pressure·steam atmosphere under the 950℃ and 1000℃. According to the results, while oxidation acceleration due to charged hydrogen was not observed prior to breakaway oxidation creation, oxidation began to accelerate in cladding where hydrogens charged as soon as the breakaway oxidation started. If so much hydrogen are charged in the cladding, equiaxial monoclinic phase to unstable of stress is formed and it is presumed that oxidation is accelerated because nearby stress caused a crack in equiaxial phase, and that makes corrosion resistance decline sharply.

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        고압 수증기하 산화에서 핵연료 피복관내 수소효과 연구

        정윤목(Yunmock Jung),정성기(Seonggi Jeong),박광헌(Kwangheon Park),노선호(Seonho Noh) 한국표면공학회 2014 한국표면공학회지 Vol.47 No.1

        The characteristics of oxidation for the Zry-4 was measured in the 800℃ and high steam pressure (50 bar, 75 bar, 100 bar) conditions, using an apparatus for high pressure steam oxidation. The effect of accelerated oxidation by high-pressure steam was increased more than 60% in hydrogen-charged cladding than normal cladding. This difference between hydrogen charged claddings and normal claddings tends to be larger as the higher pressure. The accelerated oxidation effect of hydrogen charging cladding is regarded as the hydrogen on the metal layer affects the formation of the protective oxide layer. The creation of the sound monoclinic phase in Zry-4 oxidation influences reinforcement of corrosion-resistance of the oxide layer. The oxidation is estimated to be accelerated due to the creation of equiaxial type oxide film with lower corrosion resistance than that of columnar type oxide film. When tetragonal oxide film transformed into the monoclinic oxide film, surface energy of the new monoclinic phase reduced by hydrogen in the metal layer.

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