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활성화된 nickel 금속과 halobenzene의 dehalogenative coupling 반응에 관한 연구
맹주양,맹용민 순천향대학교 기초과학연구소 2001 순천향자연과학연구 논문집 Vol.7 No.2
Activated Methallic nickel powder, prepared by the reduction of nickel halides with lithium and with naphthalene as an eletron carrier, is a simple and a convenient reagent for the dehalogenative coupling of iodobenzenes and bromobenzenes under mild conditions. The intermediates, ArNiX and Ar2Ni species (Ar = C_6F_5). were isolated as the phosphine complexes.