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Zhonghao Jin,Dao Li,Rui Ma,Xutao Peng,Guanzhong Lu,Xingyi Wang 한국공업화학회 2009 Journal of Industrial and Engineering Chemistry Vol.15 No.3
2-Chloro-4,6-dinitroresorcinol was converted catalytically in one-pot operation to the corresponding Nalkyl secondary aminophenol, 4,6-bis(isopropylamino)resorcinol, in high yield by using acetone as alkyl source and hydrogen as reducing reagent over 10 wt.% Pd/C catalyst. The effects of reaction conditions, such as the amount of acetic acid, concentration of acetone, catalyst amount, and reaction time on the selectivity of 4,6-bis(isopropylamino)resorcinol were investigated.
Wang, Zhonghao,Hu, Xun,Wang, Lina,Jin, Bingjun,Zou, Guojun,Huang, Zhiwei,Liu, Qing,Hu, Guangzhi,Zhang, Kan,Park, Jong Hyeok Elsevier 2019 ELECTROCHIMICA ACTA Vol.299 No.-
<P><B>Abstract</B></P> <P>Herein, electrochemically sluggish polymeric carbon nitride (PCN) is successfully introduced into NiCo<SUB>2</SUB>O<SUB>4</SUB> to form hybrids of NiCo<SUB>2</SUB>O<SUB>4</SUB> and PCN, in which PCN nanosheets are regarded as a substrate to promote the nucleation and subsequent in-situ growth of NiCo<SUB>2</SUB>O<SUB>4</SUB> nanosheets. The surface of as-prepared hybrids are rich in Ni and Co ions in low and high valence state, respectively. In addition, the hybrids exhibit more hydrophilic compared with that of pristine NiCo<SUB>2</SUB>O<SUB>4</SUB> due to its higher amounts of hydroxyl group. It has been found that the nitrogen species originated from PCN nanosheets tend to bond with the metal ions and electrolyte used, resulting in tuning the electronic structural states and coupling effects with NiCo<SUB>2</SUB>O<SUB>4</SUB> nanosheets. Owing to these structural characteristics, the electrochemical performance as faradaic electrode materials and long-term stability of optimized hybrid is much superior to the bare NiCo<SUB>2</SUB>O<SUB>4</SUB> nanosheets.</P> <P><B>Highlights</B></P> <P> <UL> <LI> NiCo<SUB>2</SUB>O<SUB>4</SUB>-PCN samples were prepared via a facile and scalable strategy. </LI> <LI> The NiCo<SUB>2</SUB>O<SUB>4</SUB>-PCN-40 exhibited much higher supercapacitor performance than that of pure NiCo<SUB>2</SUB>O<SUB>4</SUB>. </LI> <LI> The PCN nanosheets can promote the nucleation and subsequent in-situ growth of NiCo<SUB>2</SUB>O<SUB>4</SUB> nanosheets in oriented way. </LI> <LI> The presence of PCN can tune the electronic structural states and coupling effects with NiCo<SUB>2</SUB>O<SUB>4</SUB> nanosheets. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>The vertically growth of NiCo<SUB>2</SUB>O<SUB>4</SUB> on PCN nanosheets substrate with 3D open frameworks synthesized here is beneficial for facilitating electrolyte ions transport and electron trapping, thus boosting the supercapacitor performance of NiCo<SUB>2</SUB>O<SUB>4</SUB>.</P> <P>[DISPLAY OMISSION]</P>