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Zhan-Long Yu,Fa Cheng,Shao-Jing Zhao,Jian-Wei Zhang,Zu-Cheng Cai,Yu Chen 한국고분자학회 2011 Macromolecular Research Vol.19 No.2
Conventional surfactant dodecylbenzenesulfonic acid (DBSA) and its corresponding Gemini surfactant acid (GSA) were simply mixed with a solution of hyperbranched polyethylenimine (HPEI) in chloroform. This resulted in the novel supramolecular complexes, HPEI-DBSA and HPEI-GSA, through a neutralization reaction between the amino groups of HPEI and the sulfonic-acid groups of DBSA and GSA. The formed supramolecular complexes and their precursors were characterized by FTIR, 1H NMR, and dynamic light scattering. HPEI-DBSA and HPEI-GSA exhibited inverted-micelle properties that could accommodate the water-soluble guest molecules in an apolar solvent. With the anionic dye methyl orange (MO) as the model guest, both HPEI-DBSA and HPEI-GSA showed superior guest-encapsulation performance than the supramolecular nanocarrier derived from the assembly of aliphatic acid onto HPEI. For example, HPEI-DBSA and HPEI-GSA nanocarriers could encapsulate more MO molecules, and a much smaller amount of the surfactant molecules was required to achieve the maximum MO encapsulation. These results highlight the importance of strong-acid groups of the surfactants in raising the guest-encapsulation efficiency of this type of supramolecular nanocarrier. HPEI-DBSA and HPEI-GSA had different guestencapsulation mechanisms. This indicates that HPEI-GSA can encapsulate basic guests more than HPEI-DBSA,such as MO and fluorescein sodium (FS), but fewer relatively acidic guests, such as Alizarin Yellow R sodium salt and bromophenol blue.
Yu He,Xiwen Li,Jiecai Long,Baojun Shen,Zhibin Sun,Yili Yang,Xiaobin Zhan 한국화학공학회 2021 Korean Journal of Chemical Engineering Vol.38 No.3
The twin cam mixer (TCM), as a general-purpose mixer, shares many attributes in common with 3D industrial mixers, like the internal mixer. We investigated the mixing process in a 2D TCM with two identical isosceles triangular cams rotating at 0.5 rpm. A 2D numerical model coupled with the species transport model was employed to study the influence of cam height-base ratio and eccentricity qualitatively and quantitatively, and both were found to have a significant effect on the mixing behavior of the mixer. Furthermore, a dimensionless parameter, named the modified pressurization coefficient, is put forward to quantify the geometry of the mixer. The logarithmic relationship between the modified pressurization coefficient and the mixing quality was discovered and expected to provide new ideas for establishing the relationship between the geometric parameters of a mixer and its mixing performance.
Analysis of the extrusion pressure of a cylindrical extruder for extruding highly viscous fluids
Zhibin Sun,Baojun Shen,Yu He,Jiecai Long,Xiaobin Zhan,Yujin Li,Xiwen Li 한국화학공학회 2022 Korean Journal of Chemical Engineering Vol.39 No.10
Extrusion pressure is crucial for the security and performance of a cylindrical extruder during the extrusion process. In this study, a validated CFD model was adopted to evaluate the relationship between the extrusion velocity, fluid viscosity, and the extrusion pressure of a cylindrical extruder while extruding highly viscous fluids. The simulated and experimental results of the extrusion pressure and velocity profiles show good agreement. This study reveals that extrusion pressure evolution can be divided into two stages during the extrusion process. At stage I, the distance between the ram and the bottom of the vessel (liquid height) is greater than the critical height and the extrusion pressure remains almost constant. At stage II, the distance is less than the critical height and the extrusion pressure increases exponentially. The results indicate that an increase in extrusion velocity and fluid viscosity leads to a linear increase in the extrusion pressure at stage I. Furthermore, by introducing a pressure number, Np, and a pressurerelated Reynolds number, Rep, a novel correlation of the extrusion pressure with the extrusion velocity, viscosity of highly viscous fluids and liquid height has been developed.
Baojun Shen,Xiaobin Zhan,Yu He,Zhibin Sun,Jiecai Long,Yili Yang,Xiwen Li 한국화학공학회 2021 Korean Journal of Chemical Engineering Vol.38 No.7
Planetary centrifugal bioreactors are promising candidates for cell culture platforms since there is no pollution caused by stirring blades. In this work, the fluid structure in a planetary centrifugal bioreactor was investigated using the computational fluid dynamics (CFD) method. The effects of operating conditions on the oxygen transfer rate (OTR), mixing efficiency and shear environment of the bioreactor were studied with the revolution speed (N) ranging from 60 to 160 rpm and the rotation-to-revolution speed ratio (i) from 2 to 1. The results show that the volumetric mass transfer coefficient (kLa), turbulence intensity, volumetric power consumption, and shear stress increase along with the increase of the revolution and rotation speeds. Furthermore, the rotation in the opposite direction to the revolution is beneficial to the performance of the bioreactor. The planetary centrifugal bioreactor has a higher kLa of 50- 200/h and a lower average shear stress of 0.01-0.05 Pa in comparison with conventional stirred tank bioreactors, which makes it suitable for biological culture of oxygen-consuming cells and shear-sensitive cells.
Huan-Huan Yang,Hui Zhou,Wan-Zhan Zhu,Cai-Long Chen,Guo-Chong Chen,Lu-Gang Yu,Li-qiang Qin 한국식품영양과학회 2020 Journal of medicinal food Vol.23 No.10
Dietary factors play a crucial role in the management of type 2 diabetes mellitus (T2DM) by reducing cardiovascular disease (CVD) risk. Therefore, we aimed to examine the associations between habitual green tea consumption and risk factors of CVD among T2DM patients. A total of 1013 patients with T2DM were included in a community-based cross-sectional study. Data on dietary habits, including tea consumption, were collected using a food frequency questionnaire. A multivariable logistic regression model was used to analyze the associations. In men, as compared with nongreen tea drinkers, odds ratios (ORs) (95% confidence interval [CI]) of nonalcoholic fatty liver disease (NAFLD) were 2.06 (95% CI, 1.20–3.55) for those with green tea consumption of once per day and 2.45 (95% CI, 1.31–4.58) for more than or equal to twice per day (P-trend = .004); ORs (95% CI) of general obesity were 2.19 (95% CI, 1.02–4.68) and 2.70 (95% CI, 1.18–6.21), respectively (P-trend = .021); whereas no such association was found in women. Sensitivity analysis according to self-awareness of their T2DM status revealed that the positive association between green tea consumption and general obesity was not reliable. Higher intake of green tea was still positively associated with NAFLD, but it only persisted in participants aged ≥52 years or the lower dietary quality subgroup in further analyses. Our findings suggest that tea consumption was associated with an increased risk of NAFLD among male T2DM patients aged 52 years or older, and those with lower dietary quality, which needs to be confirmed in future prospective studies.