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Kun Rong,Xueping Li,Qian Yang,Ruimin Li,Zaiwang Zhang,Meiling Zou,Huanqiang Zheng,Juanjuan Liu 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.120 No.-
Iron nanoparticles supported on corn straw biochar (PE-FeNPs@BC) were used to remove V(V). This materialwas prepared by using Yali pear peel extract-supported iron nanoparticles (PE-FeNPs) as the functionalbody and corn straw biochar (BC) as the support. The synthesis conditions such as Fe/C massratio and synthesis temperature were optimized. The material was characterized by SEM-EDS, FTIR,XRD, and XPS. The results showed that particle agglomeration was reduced, and the dispersion wasimproved after PE-FeNPs were supported on BC. The removal effect was better in the pH range of 2–6,and the removal efficiency was the highest at pH 3.7. At 25 ℃ and pH 3.7, the maximum adsorptioncapacity qm of V(V) was 362.7 mg/g, and 95.1 % of 90 mg/L V(V) was removed. The coexisting NaCl orNaNO3 had a weaker effect on the removal of V(V). The adsorption reactions followed the pseudosecond-order model and Langmuir model, and chemical adsorption was the dominant process. The mainreaction mechanism of PE-FeNPs@BC with V(V) was as follows: adsorbed V5+ was reduced to V4+ by Fe0and Fe2+ and then removed by co-precipitation in the forms of xFe2O3yV2O5zH2O and VO2H2O. Thisstudy promotes the reuse of waste pear peel and can provide an environmentally friendly method forremoving V(V) pollution.