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Sufang Chen,Yanju Qiu,Xixi Xing,Cunwen Wang,Chengchao Liu,Yuhua Zhang,Jingping Hong,Jinlin Li,Daohong Zhang 한국고분자학회 2020 Macromolecular Research Vol.28 No.3
Among the Fischer-Tropsch synthesis (FTS) catalysts, Cobalt catalysts are currently attracting a lot of research interests due to their high activity and high selectivity. But the dispersion and reducibility of cobalt catalysts with moderate interaction between cobalt and support are still a challenge. A novel amino-ended hyperbranched polyamide (AEHPA) was used to modify SBA-15 and then was applied as support for obtaining cobalt catalyst (15Co/SBA-15-N). The catalysts were characterized by XRD, TEM, XPS and H2-TPR techniques. The results showed that AEHPA doped mesoporous SBA-15 caused the generation of N species in the SBA-15 pore channels. The N-Co bonds resulted in the formation of highly-dispersed cobalt nanoparticles with uniform sizes inside the ordered mesopores of support. AEHPA doping was an effective way to modify the surface properties of the SBA-15 for immobilizing cobalt nanoparticles. Compared with the conventional 15Co/SBA-15 catalyst without doping AEHPA, the AEHPA doped 15Co/SBA-15-N catalyst showed improved cobalt dispersion and stabilized cobalt location, which led to much better reaction stability as well as C5+ selectivity.
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A Novel Recombined Potato virus Y Isolate in China
Shuxin Han,Yanling Gao,Guoquan Fan,Wei Zhang,Cailing Qiu,Shu Zhang,Yanju Bai,Junhua Zhang,Carl Spetz 한국식물병리학회 2017 Plant Pathology Journal Vol.33 No.4
This study reports the findings of a distinct Potato virus Y (PVY) isolate found in Northeast China. One hundred and ten samples (leaves and tubers) were collected from potato plants showing mosaic symptoms around the city of Harbin in Heilongjiang province of China. The collected tubers were planted and let to grow in a greenhouse. New potato plants generated from these tubers showed similar symptoms, except for one plant. Subsequent serological analyses revealed PVY as the causing agent of the disease. A novel PVY isolate (referred to as HLJ-C-44 in this study) was isolated from this sample showing unique mild mosaic and crisped leaf margin symptoms. The complete genome of this isolate was analyzed and determined. The results showed that HLJ-C-44 is a typical PVY isolate. Phylogenetic analysis indicated that this isolate belongs to the N-Wi strain group of PVY recombinants (PVYN-Wi) and also shared the highest overall sequence identity (nucleotide and amino acid) with other members of this strain group. However, recombination analysis of isolate HLJ-C-44 revealed a recombination pattern that differed from that of other PVYN-Wi isolates. Moreover, biological assays in four different potato cultivars and in Nicotiana tabacum also revealed a different phenotypic response than that of a typical PVYN-Wi isolate. This data, combined, suggest that HLJ-C-44 is a novel PVY recombinant with distinct biological properties.
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