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        Vibratory characteristics of cracked non-uniform beams with different boundary conditions

        Han-bing Liu,Zhigang Wei,Guojin Tan,Yangyang Han,Ziyu Liu 대한기계학회 2019 JOURNAL OF MECHANICAL SCIENCE AND TECHNOLOGY Vol.33 No.1

        Non-uniform beams with bending moment of inertia and mass per unit length varying as I(x) = α 1 (1+βx) λ+4 and m(x) = α 2 (1+βx) λ are widely used in various engineering fields, such as the civil and mechanical engineering etc. This paper presents an exact method to investigate the free vibration of cracked non-uniform beams with different conditions. Firstly, the closed form solution for the mode shape functions of the non-uniform beam is obtained based on the Euler-Bernoulli beam theory. Secondly, the beam is divided into several segments according to the different variable form, and each segment is further divided into many sub-segments by cracks. Four undetermined coefficients could represent the mode shape function of each sub-segment by simulating crack with the massless rotational spring. The undetermined transfer relationship in the same segment is obtained based on the principle of the transfer matrix method. The fourorder undetermined coefficient matrix is obtained by using continuity and equilibrium conditions between adjacent segments, and then the characteristic equation of the entire cracked beam is obtained after that. Finally, the results obtained from the finite element method and published papers are used to validate the correctness and reliability of the proposed method. The influences of crack depth, location and boundary conditions on natural frequencies of cracked non-uniform beams are discussed.

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        Emission properties of sequentially deposited ultrathin CH3NH3PbI3/MoS2 heterostructures

        Shao Ziyi,Xiao Junting,Guo Xiao,You Siwen,Zhang Yangyang,Li Mingjun,Song Fei,Zhou Conghua,Xie Haipeng,Gao Yongli,Sun Jiatao,Huang Han 한국물리학회 2022 Current Applied Physics Vol.36 No.-

        Hybrid organic-inorganic perovskite materials have obtained considerable attention due to their exotic optoelectronic properties and extraordinarily high performance in photovoltaic devices. Herein, we successively converted the ultrathin PbI2/MoS2 into the CH3NH3PbI3/MoS2 heterostructures via CH3NH3I vapor processing. Atomic force microscopy (AFM)、Scanning electron microscopy (SEM) and X-ray photoemission spectroscopy (XPS) measurements prove the high-quality of the converted CH3NH3PbI3/MoS2. Both MoS2 and CH3NH3PbI3 related photoluminescence (PL) intensity quenching in CH3NH3PbI3/MoS2 implies a Type-II energy level alignment at the interface. Temperature-dependent PL measurements show that the emission peak position shifting trend of CH3NH3PbI3 is opposite to that of MoS2 (traditional semiconductors) due to the thermal expansion and electron-phonon coupling effects. The CH3NH3PbI3/TMDC heterostructures are useful in fabricating innovative devices for wider optoelectronic applications.

      • Porous WO<sub>3</sub> monolith-based photoanodes for high-efficient photoelectrochemical water splitting

        Wang, Yina,Zhang, Fangfang,Zhao, Guoyan,Zhao, Yingao,Ren, Yangyang,Zhang, Huijun,Zhang, Linyu,Du, Jimin,Han, Yumin,Kang, Dae Joon Elsevier 2019 CERAMICS INTERNATIONAL Vol.45 No.6

        <P><B>Abstract</B></P> <P>We report a successful fabrication of low-cost, high-efficient, structurally-rigid, porous WO<SUB>3</SUB> photoelectrochemical (PEC) catalysts using polystyrene as the template by a sol-gel method and a high-temperature annealing treatment. The scanning electron microscopy and Brunauer-Emmett-Teller surface analysis results indicate that such WO<SUB>3</SUB> monoliths possess a porous structure and a large specific surface area, which can supply lots of photogenerated charge transfer pathways as well as more surface PEC active sites. Compared with a commercially available WO<SUB>3</SUB>, our highly porous WO<SUB>3</SUB> PEC catalysts show an excellent PEC water splitting activity. Particularly, the porous WO<SUB>3</SUB> photoanodes calcinated in the presence of oxygen atmosphere at 450 °C for 7 h show the best PEC performance exhibiting the photocurrent density of 0.97 mA/cm<SUP>2</SUP> at 1.23 V versus reversible the hydrogen electrode and the incident photon-to-current conversion efficiency up to 48.9% at 420 nm in 0.5 M Na<SUB>2</SUB>SO<SUB>4</SUB> electrolyte under AM 1.5 G irradiation. Such excellent PEC performance is due to the high porosity of the WO<SUB>3</SUB>, promoting the fast transfer and the separation rate of photogenerated carriers during the PEC water splitting process.</P>

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