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        Belt-like VO2(M) with a rectangular cross section: A new route to prepare, the phase transition and the optical switching properties

        Yifu Zhang,Meijuan Fan,Fei Niu,Weibing Wu,Chi Huang,Xinghai Liu,Houbin Li,Xin Liu 한국물리학회 2012 Current Applied Physics Vol.12 No.3

        Belt-like VO2(M) with a rectangular cross section was first synthesized by the irreversible transformation of VO2(A) at the elevated temperatures under the inert atmosphere to the best of our knowledge. The asobtained samples were characterized by a combination of techniques including XRD, SEM and TEM. The processes of converting VO2(A) to VO2(M) were briefly discussed. The as-obtained VO2(M) has belt-like morphology with a rectangular cross section with typical lengths up to several tens of micrometers,widths ranging from tens of nanometers to several micrometers, and thicknesses about 60e150 nm. The morphology and size of the VO2(M) were dependent on that of the precursor VO2(A). The phase transition properties of VO2(M) were investigated by DSC, indicating that it exhibited a strong phase transition at 67.9 ℃ in the heating cycle and 61.1 ℃ in the cooling cycle. Furthermore, the optical switching property of VO2(M) was studied by the variable-temperature infrared spectra, and it was found that the as-obtained VO2(M) could be used as the optical switch.

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        Fabrication of belt-like VO2(M)@C core-shell structured composite to improve the electrochemical properties of VO2(M)

        Yifu Zhang,Chongxue Chen,Juecheng Zhang,Ling Hu,Weibing Wu,Yalan Zhong,Yuliang Cao,Xinghai Liu,Chi Huang 한국물리학회 2013 Current Applied Physics Vol.13 No.1

        VO2(M) nanobelts encapsulated into carbon coreeshell structured composite (VO2(M)@C) was successfully synthesized by the thermal treatment with the precursor V3O7$H2O@C composite under the inert atmosphere. The as-obtained sample was characterized by XRD, EDS, EA, FT-IR, Raman, SEM and TEM measurements. The core exhibited monoclinic phase VO2(M) and the carbon coated on the surface of VO2(M) was amorphous. The average thickness of carbon was about 18.5 nm. The possible formation mechanism of VO2(M)@C was proposed as that the reaction underwent the solid state reaction by the interface reaction between V3O7 core and carbon shell. Furthermore, VO2(M) and VO2(M)@C composite were explored as the cathode materials to apply in lithium-ion batteries, indicating that the VO2(M)@C composite electrode exhibited the better electrochemical properties than that of pure VO2(M), achieving the aim of improving the electrochemical properties of VO2(M).

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        Causal relationship between smoking status, smoking frequency and bladder cancer: a Mendelian randomization study

        Pang Lei,Ding Zijun,Chai Hongqiang,Li Fei,Wu Ming,Shuang Weibing 한국유전학회 2023 Genes & Genomics Vol.45 No.2

        Background Smoking is a well-established risk factor for bladder cancer. However, it remained unclear that whether smoke status and smoke frequency increase bladder cancer. Objective We aim to explore the causal relationship between smoking status, smoking frequency and the risk of bladder cancer by Mendelian randomization. Methods Large sample size of the genome-wide association(GWAS) database of smoking status, smoking frequency and bladder cancer were obtained. Smoking status included never, previous and current whereas smoking frequency included cigarettes smoked per day, number of cigarettes currently smoked daily and pack years of smoking. Six sets of instrumental variables and 78 related single nucleotide polymorphic(SNP) loci were identified (P < 5 × 10–8. Linkage disequilibrium R2 < 0.001). The causal relationship between smoking status and bladder tumor was studied by inverse variance weighted (IVW), weighted median and MR-Egger regression. Sensitivity analysis were also performed. Results There is no causal effect from smoke status on bladder cancer risk while significantly positive relationship between smoking frequency on bladder cancer risk were found. IVW results showed that cigarettes smoked per day, number of cigarettes currently smoked daily and pack years of smoking increase bladder cancer (OR 1.001, 95% CI 1.000–1.002, P = 0.047; OR 1.003, 95% CI 1.000–1.005, P = 0.028; OR 1.004, 95% CI 1.001–1.006, P = 0.003). Sensitivity analysis showed that genetic pleiotropy did not bias the results. Conclusion The results of two sample Mendelian randomization analysis show that there is a positive causal relationship between smoking frequency and the risk of bladder cancer.

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