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Chemical reconstruction of Castor Oil Research of Environmentally Friendly Lubricants
TAO De-hua,YE bin 한국트라이볼로지학회 2002 한국트라이볼로지학회 학술대회 Vol.2002 No.10
Natural castor oil was chemically reconstructed to extend the carbon chains by means of iso-reaction so as to improve the rheological behavior, by way of increasing the viscosity index and decreasing the pour point. The rheoloaical and triboloaical characteristics of the reconstructed castor oil were comparatively investigated with those of the natural castor oil and several other vegetable oils and a mineral oil. The friction and wear test results on a four-ball machine indicate that the chemically reconstructed castor oil has considerably improved rheological and tribological properties as compared with the natural castor oil. It shows a greatly increase viscosity index and largely decreased pour point, which makes it applicable to low temperature lubrication. The chemically reconstructed castor oil even shows better tribological behavior than pentaerythritol ester or di-iso-capryl sebacate. However, it is still needed to increase the oxidation stability of the reconstructed castor oil.
YE Bin,TAO De-hua 한국트라이볼로지학회 2002 한국트라이볼로지학회 학술대회 Vol.2002 No.10
The tribolugical characteristic of several environmentally friendly lubricating base stocks was examined, and the effect of some commonly used additives on the tribological behavior of the lubricating oils was comparatively investigated on a four-ball machine. It has been found that the commercial additives including butene sulfide, wax chloride, zinc dialkyldithiophosphate and ashless P-N type agent helped to improve the friction-reducing and antiwear properties as well as the extreme pressure behavior. Non-toxic nanoscale (CF)x showed the best friction-reducing ability, though it registered relatively poor extreme pressure properties. The mechanism on friction of nano-scale material is discussed.