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        Highly efficient separation of uranium from wastewater by in situ synthesized hydroxyapatite modified coal fly ash composite aerogel

        Siqi Huang,Congcong Chen,Zhibo Zhao,Lingyi Jia,Yong Zhang 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.118 No.-

        In this work, hydroxyapatite (HAP) was in situ synthesized on coal fly ash (CFA) to prepare hydroxyapatitemodified coal fly ash composite aerogel (HCFAA). The maximum removal efficiency and capabilityof uranium(VI) on HCFAA were 97.6 % and 205.7 mg g1, respectively, which was much higher than thoseof CFA (83.6 % and 59.1 mg g1) (pH = 3.0, m/V = 1.0 g/L and T = 298 K). The desorption efficiency of uranium(VI) by HCFAA was even more than 80 % after five cycles, demonstrating that the introduction ofHAP had improved uranium(VI) removal performances. Pseudo-second-order and Langmuir models werefitted better with the experimental data, indicating the uranium(VI) removal process was a homogeneousmonolayer chemisorption. Meanwhile, the uranium(VI) removal efficiency for HCFAA in actual wastewaterwas higher to 80.6 % and uranium(VI) could even be completely separated from actual wastewaterby HCFAA during dynamic adsorption (m = 50 mg, V = 400 mL, C0 = 10 mg/L), further illustrating that theintroduction of HAP was an available method to modify CFA. Characterizations results demonstrated thaturanium(VI) was successfully immobilized on HCFAA through ion exchange, dissolution-precipitationand surface complexation. In conclusion, HCFAA was a prospective adsorbent for uranium(VI) separationin practical application.

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        Failure Envelopes of Bucket Foundations for Offshore Wind Turbinesunder Combined Loading Including Torsion

        Siqi Li,Yuan Wang,Qing-wen Li,Jing-qi Huang,Jin-hui Li 대한토목학회 2019 KSCE JOURNAL OF CIVIL ENGINEERING Vol.23 No.12

        The loading condition of bucket foundations for offshore wind turbines is very complicated and often under combined loading, but the torsion is always ignored. So, it is necessary to investigate the failure envelopes including torsion of bucket foundations. Under the premise of validating the reliability of the numerical model by comparing with other published data, failure envelopes in each loading space are obtained and the applicability of swipe test for the determination of H-T failure envelope and M-T failure envelope of bucket foundations is explored. The impacts of torsion and aspect ratio on the combined bearing capacities are studied. While revealing the law of impacts, equations are proposed to determine the respective failure envelopes and evaluate the combined bearing capacities. The V-H-M-T failure envelope can reveal the torsion effect on envelope under traditional V-H-M loading, the results show that the normalized V-H-M failure envelopes under different torsions almost coincide, torsion effect can be easily considered according to this characteristic.

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