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Zhiyuan Yang,Junjie Wang,Lu Chen,Mengjun Liang,Yulin Xu,Chentao Zou,Xiaoxia Liu,Shuijin Yang 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2017 NANO Vol.12 No.5
In this work, we developed a simple hydrothermal method toward the fabrication of TiO2/ Bi3.64Mo0.36O6.55 heterostructure, which had superior photocatalytic performance for degrading of RhB under visible light irradiation. The as-prepared samples were characterized by X-ray diffraction (XRD), field emission scanning electron microscope (FESEM), high-resolution transmission electron microscopy (HRTEM), UV-Vis diffuse reflectance spectroscopy (DRS) and photoelectrochemical measurements. The optimal composite with 15 wt.% TiO2/Bi3.64Mo0.36O6.55 (TBMO3) exhibits a much higher photocatalytic activity than that of Bi3.64Mo0.36O6.55 and P25 by degradation of RhB under visible light irradiation within 20 min. The enhanced performance of TBMO3 is predominantly attributed to the synergistic effect both in the higher surface area and the improved separation of photogenerated charge carriers between the two semiconductors. Recycling experiments indicated that TiO2/Bi3.64Mo0.36O6.55 photocatalysts had excellent cycle performance and stability. The photocatalytic mechanism of nanocomposite photocatalysts was proposed, which is confirmed by the active species trapping experiments and photoluminescence tests.
Chentao Zou,Zhiyuan Yang,Mengjun Liang,Yunpeng He,Yun Yang,Shuijin Yang 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2018 NANO Vol.13 No.11
Bi metal deposited on Bi2MoO6 composite photocatalysts have been successfully synthesized via a simple reduction method at room temperature with using NaBH4 as the reducing agent. The photocatalytic activity of the composite was evaluated by degradation of rhodamine B (RhB) and bisphenol A (BPA) solution under visible light. The rate constant of Bi/Bi2MoO6 composite to RhB is 10.8 times that of Bi2MoO6, and the degradation rate constant of BPA is 6.9 times of that of Bi2MoO6. Nitrogen absorption–desorption isotherm proved that the increase of specific surface area is one of the reasons for the improvement of photocatalytic degradation activity of Bi/Bi2MoO6 composites. The higher charge transfer efficiency of Bi/Bi2MoO6 is found through the characterization of the photocurrent and impedance, which are attributed to the surface plasmon resonance (SPR) effect produced by the introduction of the metal Bi monomer in the composite. Free radical capture experiments proved that cavitation is the main active species. Based on the above conclusions, a possible mechanism of photocatalytic degradation is proposed.
Lu Xue,Guanghua Luo,Yang Sun,Shuijin Huang,De-Jin Xu,Guang-Chun Xu,Zhao-Jun Han,Zhong-Yan Gu,Ya-Nan Zhang 한국응용곤충학회 2020 Journal of Asia-Pacific Entomology Vol.23 No.1
Insecticide mixtures are an effective strategy in pest resistance management. The synergistic chlorpyrifos and imidacloprid mixture could significantly increase toxicity against rice pest, Nilaparvata lugens, despite their high levels of resistance. However, synergism mechanisms to explain this phenomenon remain unknown. Chlorpyrifos and imidacloprid at a 1:0.5 ratio showed significant synergism on N. lugens with a combination index value of 0.18 after topical exposure. We constructed a genetic database of the genes expressed in individual and synergistic chlorpyrifos and imidacloprid treatments of N. lugens using Illumina Hiseq™ X Ten, and 17 co-downregulated genes putatively involved in synergism were detected by comparative transcriptome analyses. Expression patterns of the 17 candidate synergistic genes matched with transcriptome sequencing data by quantitative real-time PCR analyses. Feeding of dsRNAs further reduced the expression levels of 10 of these candidate synergistic genes (from 1.68 to 4.13-fold). Nymphs fed with only dsRNAs of CYP4DE1, CYP6AY1v2, CYP353D1, and CYP439A1 experienced more high mortality rates (81.45–90.34%) to improve synergism between chlorpyrifos and imidacloprid. Multiple reductive expressed P450 genes were potentially associated with synergism of a mixture of chlorpyrifos and imidacloprid, as confirmed by comparative transcriptome analyses and RNAi assays. Our findings suggested that synergistic interactions between chlorpyrifos and imidacloprid might be controlled by P450s.
Dye-Sensitized-Assisted, Enhanced Photocatalytic Activity of TiO2/Bi4V2O11
Mengjun Liang,Zhiyuan Yang,Ying Mei,Haoran Zhou,Shuijin Yang 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2018 NANO Vol.13 No.3
In this study, the TiO2/Bi4V2O11 nanocomposite photocatalysts were prepared by loading different amount of TiO2 nanoparticles onto the surface of Bi4V2O11 nanospheres via a facile hydrothermal method. Afterwards, the as-synthesized samples were characterized by high-resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), N2 adsorption–desorption isotherms, X-ray photoelectron spectroscopy (XPS), UV-Vis diffuse reflectance spectroscopy (DRS) and photocurrent techniques. The optimal TiO2/Bi4V2O11 composite with 20 wt.% TiO2 loading (TB2) exhibited the best photocatalytic activity, which could degrade almost RhB completely within 30 min under visible light irradiation. The enhanced photocatalytic activity of TiO2/Bi4V2O11 composites for RhB degradation could be mainly ascribed to the efficient charge separation over dye-induced sensitized and the increased specific surface area. Also, the photocatalytic activities of TiO2/Bi4V2O11 for CIP degradation were tested. After five consecutive recycling experiments, the photocatalytic degradation activity of TB2 could still reach 99% which indicated that the catalysts had superior stability. Based on the experimental and bandgap calculations, a possible photocatalytic mechanism of TiO2/Bi4V2O11 for RhB degradation was proposed.
Peng Yingchuan,Zhao Jun,Sun Yang,Wan Peng,Hu Yanyue,Luo Guanghua,Qin Wenjing,Huang Shuijin 한국응용곤충학회 2021 Journal of Asia-Pacific Entomology Vol.24 No.2
The ATP-binding cassette (ABC) proteins are involved in trans-cellular transport of substances at inverse con centrations. After ABC genes were discovered to be involved in multidrug resistance in humans, increased attention was paid to the role of insect ABC genes in pesticide resistance. Chilo suppressalis, the most important Lepidopteran pest in rice production, has developed resistance to the insecticide chlorantraniliprole. However, few of the ABC genes that contribute to chlorantraniliprole resistance have been studied. Here, 47 genes encoding ABC transporters were identified, including five CsABCA, seven CsABCB, ten CsABCC, two CsABCD, one CsABCE, three CsABCF, 15 CsABCG, and four CsABCH genes. The expression profiles of these transporter genes were determined in three chlorantraniliprole-resistant strains: R1, R2, and HR, with a resistance ratio of 38.8, 110.4, and 249.6, respectively. CsABCA1, -D2, and -H2 were up-regulated in all resistant strains, and the trend in the transcript levels of all 47 CsABC genes fitted a descending curve from R1 to HR. Unexpectedly, CsABCF1, -G11 and -G12 were significantly down-regulated in HR. These results provide new insights into the roles of ABC transporters in chlorantraniliprole resistance in C. suppressalis.