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        Optimization of feed and extractant concentration for the liquid–liquid extraction of volatile fatty acids from synthetic solution and landfill leachate

        Sameena Begum,Vijayalakshmi Arelli,Gangagni Rao Anupoju,Sridhar S,Suresh K. Bhargava,Nicky Eshtiaghi 한국공업화학회 2020 Journal of Industrial and Engineering Chemistry Vol.90 No.-

        Liquid–liquid extraction of volatile fatty acids (VFA) from landfill leachate (LL) as well as syntheticsolution (SS) whose concentration varied from 0.2 to 1 mol/L was investigated. The impact of extractantand feed VFA concentration on extraction efficiency (EE), distribution ratio (KD) and loading ratio (z) withthe help of statistical analysis and process optimization using response surface methodology ispresented. Physical extraction of VFA from SS using seven different diluents was performed to choose thebest diluent. Reactive extraction of VFA was investigated with 10–50% (v/v) trioctylamine (TOA) andtributylphosphate (TBP) as extractants in 1-Octanol. Reactive extraction of VFA results disclosedenhancement of EE due to the synergistic chemical interactions between extractant and diluent. Majorityof the acid extractant complexes formed were 1:1 with TBP while 1:1, 2:1 and 3:1 with TOA as verified byz > 0.5 The optimal extractant concentration for TOA and TBP was found to be 37.8% and 39.09% at a feedconcentration of 0.67 mol/L and 0.81 mol/L for SS respectively to achieve maximum EE of 91% while it was29.3% and 36.2% at 0.2 mol/L for LL to achieve EE of 52% and 57% correspondingly.

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        Assessment of bank erosion and channel shifting of Padma River in Bangladesh using RS and GIS techniques

        Sultana Jahan Ophra,Sameena Begum,Raihanul Islam,Md. Nazrul Islam 대한공간정보학회 2018 Spatial Information Research Vol.26 No.6

        Bangladesh is a riverine country. Every year it faces many natural hazards due to river. Bangladesh is mainly formed by alluvial deposits. It faces riverbank erosion frequently due to regular shifting of river channels. This research work provides an overview of the trend of riverbank erosion of Padma River of Munshiganj, Madaripur and Shariatpur district. It also shows the land cover change due to riverbank erosion. The riverbank erosion was calculated by using remote sensing and geographic information systems (GIS) techniques. Only secondary data have been used to reach the research goals. Various computer software such as Erdas Imagine, Arc GIS, Google Earth, Environment for Visualizing Images etc. have been used to process and analyze raw data. In this study, using seven selected images of Landsat TM and OLI acquired from 1988 to 2017, the riverbank migration patterns and land dynamics of Padma resulted from accretion/ erosion processes for 29 years were investigated. The migration rates are based on the differences in 1988–1993, 1993–1998, 1998–2003, 2003–2008, 2008–2013 and 2013–2017. The average erosion and accretion rates are 1472.056 and 1610.152 ha/year of Padma, respectively. This study shows Padma got meandered and braided from almost straight channel in the time span.

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