RISS 학술연구정보서비스

검색
다국어 입력

http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.

변환된 중국어를 복사하여 사용하시면 됩니다.

예시)
  • 中文 을 입력하시려면 zhongwen을 입력하시고 space를누르시면됩니다.
  • 北京 을 입력하시려면 beijing을 입력하시고 space를 누르시면 됩니다.
닫기
    인기검색어 순위 펼치기

    RISS 인기검색어

      검색결과 좁혀 보기

      선택해제

      오늘 본 자료

      • 오늘 본 자료가 없습니다.
      더보기
      • 무료
      • 기관 내 무료
      • 유료
      • KCI등재

        Dielectric properties and EMI shielding efficiency of polyaniline and ethylene 1-octene based semi-conducting composites

        Sambhu Bhadra,Nikhil K. Singha,Dipak Khastgir 한국물리학회 2009 Current Applied Physics Vol.9 No.3

        The preparation of polyaniline (PAni) was carried out by the oxidative emulsion polymerization of aniline and the semi-conducting composites were prepared by mixing it with a polyolefinic thermoplastic elastomer ethylene 1-octene copolymer (EN). Different electrical properties and electromagnetic interference shielding efficiency (EMI SE) of these composites were measured. The results revealed that the incorporation of PAni in EN increases the conductivity, dielectric constant, dielectric loss and EMI SE. These composites exhibit pressure dependent dielectric properties and may act as pressure sensor. There are increase in AC conductivity and decrease in dielectric constant with the increase in applied pressure on composites. A model correlation between EMI SE and AC conductivity at same frequency for the composites having maximum 40% of PAni was obtained through extrapolation and linear regression analysis, which shows that EMI SE has linear relationship with AC conductivity. Because of their semi-conductive behavior these composites can find application as antistatic materials and electromagnetic interference (EMI) shielding material. The preparation of polyaniline (PAni) was carried out by the oxidative emulsion polymerization of aniline and the semi-conducting composites were prepared by mixing it with a polyolefinic thermoplastic elastomer ethylene 1-octene copolymer (EN). Different electrical properties and electromagnetic interference shielding efficiency (EMI SE) of these composites were measured. The results revealed that the incorporation of PAni in EN increases the conductivity, dielectric constant, dielectric loss and EMI SE. These composites exhibit pressure dependent dielectric properties and may act as pressure sensor. There are increase in AC conductivity and decrease in dielectric constant with the increase in applied pressure on composites. A model correlation between EMI SE and AC conductivity at same frequency for the composites having maximum 40% of PAni was obtained through extrapolation and linear regression analysis, which shows that EMI SE has linear relationship with AC conductivity. Because of their semi-conductive behavior these composites can find application as antistatic materials and electromagnetic interference (EMI) shielding material.

      • Synthesis of higher soluble nanostructured polyaniline by vapor-phase polymerization and determination of its crystal structure

        Bhadra, Sambhu,Lee, Joong Hee Wiley Subscription Services, Inc., A Wiley Company 2009 Journal of applied polymer science Vol.114 No.1

        <P>Higher soluble nanostructured polyaniline was prepared by vapor-phase polymerization after passing aniline vapor through an aqueous acidic solution of ammonium persulfate (PANI-V). Polyaniline was also synthesized by the conventional oxidative polymerization method (PANI-C) in an aqueous medium for the comparison of its properties with PANI-V. PANI-V exhibited lower conductivity but higher hydrophilicity and higher solubility (2–3 times) in different solvents, such as tetrahydrofuran, N-methyl-2-pyrrolidone, dimethylsulfoxide, N,N-dimethyl formamide, and m-cresol at room temperature compared with that of PANI-C. The thermal stability of PANI-V was higher than that of PANI-C. In-depth investigations of the crystal structures of PANI-C and PANI-V were performed through powder X-ray diffraction analysis. The PANI-V showed a less ordered structure with a lower crystallinity and crystallite size and with a higher d-spacing and interchain separation compared with PANI-C. The unit cell volume of PANI-V was significantly higher with a greater number of atoms in the unit cell than that of PANI-C. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009</P>

      • Synthesis and Properties of New Type of Proton Conducting Polymer Membrane for High Temperature Fuel Cells

        이중희(Lee, Joong-Hee),삼부 바드라(Sambhu, Bhadra),김남훈(Kim, Nam-Hoon),이홍기(Lee, Hong-Ki),김홍건(Kim, Hong-Gun) 한국신재생에너지학회 2009 한국신재생에너지학회 학술대회논문집 Vol.2009 No.11

        Poly(benzimidazole-co-aniline) (PBIANI), a self-crosslinked, net-structured, proton conducting polymer has been synthesized for the membrane of high temperature proton exchange membrane fuel cells (HT-PEMFC) with improved proton conductivity and mechanical strength. The stress at break (26pm3MPa)and proton conductivity (167 mS cm-1)of the phosphoric acid doped PBIANI (DPBIANI)membrane is much higher than those of other doped polybenzimidazole(PBI) type membranes.

      연관 검색어 추천

      이 검색어로 많이 본 자료

      활용도 높은 자료

      해외이동버튼