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Xuan Zhang,ZhiPing Mao,Qian Wu,LinPing Zhang 한국공업화학회 2013 Journal of Industrial and Engineering Chemistry Vol.19 No.3
In this report, hexakis (4-nitrophenoxy) cyclotriphosphazene (HNCP) and ethylene–octene copolymer grafted-maleic anhydride (POE-g-MA) were blended with pure PET together. The fire retardant ability and thermal stability of PET/HNCP/POE-g-MA were investigated respectively. The results indicated that HNCP and POE-g-MA had a synergic effect on the dripping resistance of PET besides the enhancement in flame retardancy to a certain degree. LOI values of the polymers with both POE-g-MA and 10 wt%HNCP were higher than that of pure PET and no drips just containing 1 wt%POE-g-MA. The reason was that HNCP could be well dispersed in PET when POE-g-MA was added, forming a more effective char layer and preventing dripping of polymers. Indeed, the morphology of charred residue of PET/HNCP/POE-g-MA showed that a porous protective layer with a dense surface was formed. The thermogravimetric analysis revealed that addition of HNCP improved the thermal stability and the yield of char residue of the PET/POE-g-MA systems. Based on a series of experiment results, the synergistic effect of HNCP and POE-g-MA on the anti-dripping of PET was also discussed. In the PET/HNCP/POE-g-MA system, POE-g-MA played a role of compatibilizer. The improved compatibility and dispersion provided the composite with the ideal flame retardancy, thermal stability and anti-dripping property.
Promoting N2 electroreduction to ammonia by fluorine-terminating Ti3C2Tx MXene
Ding Yu,Zhang Junbo,Guan Anxiang,Wang Qihao,Li Si,Al-Enizi Abdullah M.,Qian Linping,Zhang Lijuan,Zheng Gengfeng 나노기술연구협의회 2021 Nano Convergence Vol.8 No.14
Two-dimensional MXene-based materials are potential of presenting unique catalytic performances of electrocatalytic reactions. The surface functionalization of MXene-based catalysts is attractive for developing efficient electrocatalysts toward nitrogen reduction reaction. Herein, we reported a Ti 3 C 2 T x MXene with a medium density of surface functionalized fluorine terminal groups, as an excellent N 2 reduction reaction electrocatalyst with enhanced adsorption and activation of N 2 . The Ti 3 C 2 T x MXene catalyst showed a production rate of ammonia as 2.81 × 10 –5 μmol·s −1 ·cm −2 , corresponding to a partial current density of 18.3 μA·cm −2 and a Faradic efficiency of 7.4% at − 0.7 V versus reversible hydrogen electrode in aqueous solutions at ambient conditions, substantially exceeding similar Ti 3 C 2 T x MXene catalysts but with higher or lower densities of surface fluorine terminal groups. Our work suggests the capability of developing surface functionalization toolkit for enhancing electrochemical catalytic activities of two-dimensional MXene-based materials.