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        Impact of Ammonia Producing Bacillus sp. on Corrosion of Cupronickel alloy 90:10

        S. Maruthamuthu,P. Dhandapani,S. Ponmariappan,배정효,N. Palaniswamy,Pattanathu K.S.M. Rahman 대한금속·재료학회 2009 METALS AND MATERIALS International Vol.15 No.3

        The objectives of the present investigation were to characterize ammonia-producing bacteria (Bacillus sp.) and study its impact on biodeterioration of cupronickel alloy 90:10. in a nitrogen free environment. It is well known that iron sulphate and molybdenum are good inhibitors when used in a cooling water system. The interactions between inhibitor and ammonia producing bacteria on the corrosion of cupronickel 90:10 were studied. The predominated ammonia producing bacteria Bacillus spp. (AG1-EU202683; AG2-EU202684; AG3-EU202685 and AG4-EU202686) were identified by 16S rRNA gene sequencing from the biofilm. These bacteria fixed with atmospheric nitrogen for their cell protein synthesis and converted into ammonia. Ammonia enhanced pH and ammonical solution were formed in the presence of Bacillus spp. which acted as an etchant. The presence of some anodic spots in the presence of bacteria was affected by ammonia and then underwent pitting corrosion. The present study reveals that Bacillus spp. encourage intergranular attack without any stress in the cooling water system. The objectives of the present investigation were to characterize ammonia-producing bacteria (Bacillus sp.) and study its impact on biodeterioration of cupronickel alloy 90:10. in a nitrogen free environment. It is well known that iron sulphate and molybdenum are good inhibitors when used in a cooling water system. The interactions between inhibitor and ammonia producing bacteria on the corrosion of cupronickel 90:10 were studied. The predominated ammonia producing bacteria Bacillus spp. (AG1-EU202683; AG2-EU202684; AG3-EU202685 and AG4-EU202686) were identified by 16S rRNA gene sequencing from the biofilm. These bacteria fixed with atmospheric nitrogen for their cell protein synthesis and converted into ammonia. Ammonia enhanced pH and ammonical solution were formed in the presence of Bacillus spp. which acted as an etchant. The presence of some anodic spots in the presence of bacteria was affected by ammonia and then underwent pitting corrosion. The present study reveals that Bacillus spp. encourage intergranular attack without any stress in the cooling water system.

      • KCI등재

        Recent bioreduction of hexavalent chromium in wastewater treatment: A review

        Debabrata Pradhan,Lala Behari Sukla,Matthew Sawyer,Pattanathu K.S.M. Rahman 한국공업화학회 2017 Journal of Industrial and Engineering Chemistry Vol.55 No.-

        Hexavalent chromium (Cr(VI)) in water is a proven carcinogen to different internal and external organs of the living organisms. There are different human activities incorporated to the anthropogenic sources in the environment enriching Cr(VI) of high concentration in the water system above the regulatory level. The physical, chemical and biological properties of chromium favour the dissolution in the water environment. This concerns the environmental researcher to tackle and mitigate. Chemical or biological techniques or a combination of the two have been used to remove Cr(VI) from polluted waters. Biological techniques include integrated bioremediation, such as the primary processes of direct bioreduction and biosorption, and secondary processes of microbial fuel cell, biostimulation, surface modified dry biomass and biochar adsorption, and engineered biofilm and cell free reductase. These techniques are used by a wide range of living organisms including bacteria, fungi, plants, plant leaves, plant nuts and algae. This group of living organisms transform and remove Cr(VI) from water during the cellular metabolisms, extracellular activities, physical and chemical adsorptions on the cell surface, and photosynthesis. Variation of different physical, chemical and environmental parameters affecting the efficiency of the bioremediation process have impacted on the design of bioreactors. There has been a recent development of a microbial fuel cell which use the proximity of Cr(VI) reduction as a cathode half cell for the generation of renewable energy and simulation of its’ removal from water.

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